Introduction to heterogeneous catalysis / Roel Prins, Institute for Chemical and Bioengineering, ETH Zurich, Switzerland, Anjie Wang, Dalian University of Technology, China, Xiang Li, Tianjin University of Science and Technology, China, Foteini Sapountzi, Syngaschem BV, The Netherlands.

Format:

Book

Author/Creator:

Prins, Roelof, author.

Wang, Anjie (Professor of chemistry), author.

Li, Xiang (Professor of chemistry), author.

Sapountzi, Foteini, author.

Series:

Advanced textbooks in chemistry

Language:

English

Subjects (All):

Heterogeneous catalysis--Textbooks.

Heterogeneous catalysis.

Catalysis--Textbooks.

Catalysis.

Chemistry--Textbooks.

Chemistry.

Genre:

Textbooks.

Physical Description:

xviii, 392 pages : illustrations (some color) ; 24 cm.

Edition:

Second edition.

Place of Publication:

London ; Hackensack, NJ : World Scientific Publishing Ltd., [2022]

Summary:

"Catalysis is a multidisciplinary subject. This book introduces the chemical, materials, and engineering principles of catalysis so that both MSc and PhD students with a basic but not extensive knowledge of chemistry and physics and those with a basic understanding of chemical engineering can learn more about catalysis. Examples are taken from catalytic reactions and catalysts used in the energy, petroleum, and base-chemicals industry. The second edition differs from the first edition in the way basic topics are integrated with catalytic applications. The authors introduce two new chapters: "Cleaning of Fuels by Hydrotreating" and "Electrocatalysis". Hydrotreating is a very important industrial process and offers the opportunity to discuss metal sulfide catalysts. Electrocatalysis gains more and more attention because it can be used to minimize the anthropogenic CO₂ emissions. Solar, wind, and hydroelectricity can drive water electrolysis and CO₂ electroreduction and, therefore, excess renewable electricity can be stored in chemicals. Introduction to Heterogeneous Catalysis (Second Edition) is intended for a one-semester course for master and PhD students who want to learn more about the principles of catalysis. This must-read textbook will enable students to read catalysis literature without much difficulty and presents not only the basic concepts of catalysis but integrates the chemical, materials, and engineering aspects of catalysis with industry examples"-- Provided by publisher.

Contents:

Machine generated contents note: 1.1. Catalysis and Catalysts

1.2. Heterogeneous and Homogeneous Catalysis

1.3. Production of Ammonia

1.3.1. Kinetics and Thermodynamics

1.3.2. Activity, Selectivity and Stability

1.3.3. H2 Production

1.3.4. Ammonia Synthesis

1.4. Relevance of Catalysis

References

Questions

2.1. Supported Catalysts

2.2. Crystal Structures

2.2.1. Crystal Lattices

2.2.2. X-ray Diffraction

2.3. Aluminas

2.3.1. Aluminium Hydroxides and Oxyhydroxides

2.3.2. Transition Aluminas

2.3.3. α-Al2O3

2.3.4. γ-Al2O3

2.3.5. Surface of γ-Al2O3

2.3.5.1. Lewis acid sites

2.3.5.2. Bronsted acid sites

2.3.5.3. Surface reconstruction

2.4. Silica

2.5. Preparation of Supported Catalysts

3.1. Physisorption

3.1.1. Adsorption on Surfaces

3.1.2. Langmuir Adsorption Isotherm

3.1.3. Multilayer Adsorption, BET

3.2. Surface Diffusion

3.3. Chemisorption

3.3.1. Chemical Bonding

3.3.2. Dissociative Chemisorption

4.1. Langmuir-Hinshelwood Model

4.1.1. Monomolecular Reaction

4.1.1.1. Surface reaction is rate-determining

4.1.1.2. Adsorption of the reactant or product is rate-determining

4.1.2. Bimolecular Reaction

4.2. Influence of Diffusion

4.3. Bifunctional Catalysis

5.1. Surface Structures

5.2. Surface Analysis

5.2.1. X-ray Photoelectron Spectroscopy

5.2.2. Auger Electron Spectroscopy

5.2.3. Surface Sensitivity

5.3. Surface Enrichment

5.4. Metal Binding

6.1. Dissociation of H2

6.2. Hydrogenation of Ethene

6.3. Synthesis of CO and H2

6.4. Hydrogenation of CO

6.4.1. CO Hydrogenation to Hydrocarbons

6.4.1.1. CO dissociation

6.4.1.2. Met hanat ion

6.4.1.3. Fischer-Tropsch reaction

6.4.2. Hydrogenation of CO and CO2 to Methanol

6.4.2.1. CO hydrogenation to methanol

6.4.2.2. CO2 hydrogenation to methanol

6.5. Hydrogenation of N2 to Ammonia

6.5.1. Fe Catalyst

6.5.2. Ru Catalyst

6.6. Volcano Curves

7.1. Solid Acid Catalysts

7.1.1. Zeolites

7.1.2. Amorphous Silica-Alumina

7.2. Reactions of Hydrocarbons

7.2.1. Reactions of Alkenes and Alkanes

7.2.2. Isomerisation of Pentane, Hexane and Butene

7.3. Alcohols from Alkenes

7.4. Alkylation of Aromatics

7.4.1. Ethylation and Propylation of Benzene

7.4.2. Methylation of Toluene

7.4.3. Isomerisation, Disproportionation, Transalkylation

7.5. Gasoline Production

7.5.1. Fluid Catalytic Cracking and Hydrocracking

7.5.2. Methanol to Hydrocarbons

7.5.3. Reforming of Hydrocarbons by Bifunctional Catalysis

8.1. Hydrotreating

8.2. Hydrotreating Catalysts

8.2.1. Metal Sulfides

8.2.1.1. Structure of sulfided Co-Mo/Al2O3 and Ni-Mo/Al2O3

8.2.1.2. Active sites

8.2.2. Metal Phosphides

8.3. Reaction Mechanisms

8.3.1. Hydrodesulfurisation

8.3.2. Hydro denitrogenation

8.3.3. Hydrodeoxygenation

8.3.4. Hydrotreating of Mixtures

8.4. Hydrotreating Processes

8.4.1. Hydrodesulfurisation of Naphtha

8.4.2. Hydrotreating of Diesel

8.4.3. Residue Hydroconversion

9.1. CO Oxidation

9.1.1. Mechanism

9.1.2. Three-way Catalysis

9.2. Production of Sulfuric and Nitric Acid

9.2.1. Sulfuric Acid

9.2.2. Nitric Acid

9.2.3. Selective Catalytic Reduction

9.3. Oxidation of Hydrocarbons

9.3.1. Oxidation by Oxygen

9.3.2. Oxidation by Hydroperoxide

9.3.3. Selective Partial Oxidation of Hydrocarbons

9.3.3.1. Oxidation of propene to acrylic acid and acrylonitrile

9.3.3.2. Oxidation of C4 and C6 molecules

9.4. Platform Chemicals

10.1. Introduction

10.2. Fundamental Aspects

10.2.1. Electrochemical Cells

10.2.2. Cell and Electrode Potentials

10.2.3. The Nernst Equation

10.2.4. Overpotential

10.2.5. Electrode Kinetics

10.3. Experimental Methods and Techniques

10.3.1. Three-Electrode Cell Configuration

10.3.2. Techniques for Electrocatalyst Evaluation

10.3.3. Linear Sweep Voltammetry and Cyclic Voltammetry

10.3.4. Electrochemical Impedance Spectroscopy

10.3.5. Rotating Disc Electrode

10.3.6. The Electrochemically Active Surface Area

10.4. Electrocatalysis for the Production of Sustainable Fuels and Chemicals

10.4.1. Development of Electrocatalysts

10.4.2. Hydrogen Evolution Reaction

10.4.3. Oxygen Evolution Reaction

10.4.4. CO2 Electroreduction

10.4.5. Other Electrochemical Processes

Questions.

Notes:

Includes bibliographical references and index.

ISBN:

9781800611504

1800611501

9781800611610

1800611617

OCLC:

1288424971

Publisher Number:

99993576905