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Functional analytical techniques in pharmaceutical chemistry / Malik Saadullah, editor.

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Format:
Book
Contributor:
Saadullah, Malik, editor.
Series:
Analytical Chemistry and Microchemistry
Language:
English
Subjects (All):
Pharmaceutical chemistry.
Physical Description:
1 online resource (312 pages)
Edition:
First edition.
Place of Publication:
New York : Nova Science Publishers, Inc., [2022]
Summary:
"Pharmaceutical Chemistry is a scientific discipline in the chemical and pharmaceutical field involved in the design and development of pharmaceutical drugs and their analytical techniques. Analytical chemistry is a branch of pharmaceutical chemistry that specializes in the analysis of various substances. It involves the separation, identification, and the quantification of matter by using classical and modern methods involving the use of scientific instruments. This book is an attempt to expose the analytical techniques used in pharmaceutical chemistry, so that one can possess command in analytical techniques"-- Provided by publisher.
Contents:
Intro
Contents
Preface
Acknowledgment
Chapter 1
Background
Abstract
Introduction
Importance of Analytical Chemistry
Fundamental Research
Product Development
Product Quality Control
Maintaining of Pollutants
Assay
Medical and Clinical Studies
Analytical Issues and Their Solutions
Selection of Method
Sampling
Preliminary Sample Treatment
Separations
Method Validation
Assessment of Findings
Types of Analytical Methods
Accuracy
Analyte
Blank
Calibration
Concentration
Constituent
Detection Limit
Determination
Equivalent
Estimation
Interference
Masking
Matrix
Method
Variability
Primary Standard
Procedure
Reagent
Sample
Sensitivity
Standardization
Standard
Standard Addition
Technique
Validation of Methods
Conclusion
Conflict of Interest
Consent For Publication
References
Chapter 2
Separation Methods and Quality Control
Types of Extraction
Liquid-Liquid Extraction
Types of Liquid-Liquid Extraction (LLE)
Dispersive Liquid-Liquid Microextraction (DLLME)
Direct Organic Extraction
Extraction Without Chemical Change
Ion Exchange Mechanism
Ion Pair Extraction
Advantages of LLE
Disadvantages of LLE
Solid-Liquid Extraction
Types of Solid Phase Extraction (SPE)
Normal Phase SPE
A Solid Phase Extraction Involves Basic Five Steps
Reverse Phase SPE
Ion Exchange SPE
Anion Exchange SPE
Cation Exchange SPE
Solid Phase Microextraction
Supercritical Fluid Extraction
Process of Super Critical Extraction
Factors Affecting Extraction Efficiency
Quality Control Separation
Chromatographic Fingerprinting
Thin Layer Chromatography
Advantages of TLC
Disadvantages of TLC.
High-Performance Thin Layer Chromatography (HPTLC)
Microemulsion-Thin Layer Chromatography (ME-TLC)
Densitometric-Thin Layer Chromatography (Densitometric TLC)
Two-Dimensional Thin Layer Chromatography
Graft Thin Layer Chromatography
HPLC: High Performance Liquid Chromatography
Disadvantages of HPLC
Ultra-High Performance Liquid Chromatography UHPLC
Hydrophilic Interaction Liquid Chromatography
Gas Chromatography
Miniaturized Separation Techniques
Separation Techniques Isocratic versus Gradient Elution
Consent for Publication
Chapter 3
Physical Methods of Analysis
Solubility Determination
Basic Concepts of Solubility
Classification of Solutions
Mechanism of Solubility (Dispersibility)
Factors Affecting the Solubility (Dispersibility)
Solubility Test Methods
Shake Flask Technique
Miniaturized Shake Flask Method
Small Scale Shake-Flask Method
Equilibrium 96-Well Microtiter Plate Methods
Column Elution Method
Solubility Enhancement Techniques
Applications
Molecular Weight Determination
Osmometric Method
Membrane Osmometers
Cryoscopic Method
Ebullioscopic Method
Mass Spectrometry
Viscosity Determination
Factors Affecting Viscosity
Types of Viscometer
Ostwald Viscometer
Falling Ball Viscometer
Cup-Bob Viscometer
Cone and Plate Viscometer
Surface Tension Determination
Factors Affecting the Surface Tension
Methods for Determining Surface Tension
Static Surface Tension Measurement Methods for Liquids
Dynamic Surface Tension Measurement Methods for Liquids
Surface Tension Measurement Methods for Solids
Standard Contact Angle Measurement Methods for Various Materials
X-Ray Diffractometry.
Principle
Bragg's Law
Thomson Scattering
Application of X-Ray Diffraction
X-Ray Fluorescence Analysis (XFA)
Working
Applications of X-Ray Fluorescence Analysis
Polarimetry
Features Affecting Optical Activity
Important Tools CD and ORD
Refractometry
Principle
Factors Affecting the Refractive Index
Particle Size Analysis
Methods Used for the Analysis of Particle Size
Microscopy
Sieving
Sedimentation Methods
Zone Sensing Method
Light Scattering Method
Chapter 4
Classical Methods of Analysis
Acid and Base
pH
Buffer Solutions
pH Measurement Methods
Application of Indicator for pH Measuring
Flaws
Method for Hydrogen-Electrode
Quinhydron-Electrode Method
Method of Antimony-Electrode
Method of Glass-Electrode
Semiconductor Sensor Methods
Oxidation Reduction Reactions
Titration
Nonaqueous Acid-Base Titrations
Chelatometry or Complexometric Titration
Argentometric Titrations
Mohr Method, Chromate Ion
Volhard Method, Iron (III) Ion
Fajans Method, Adsorption Indicator
Redox Titrations
Titration Involving Potassium Permanganate (KMnO4)
Safety Precautions
Reagents
Iodine Redox Titrations
Titrations Require Iodine
Iodimetry
Iodometry
Ascorbic Acid Analysis by Iodimetry
Hydrogen Peroxide Analysis by Iodometry
Titration of Ceric Sulfate
Scope of Application
Gravimetric Methods
Precipitation Gravimetry
Electrogravimetry
Miscellaneous Types of Analysis
Recommended Procedure
Fats and Fatty Oils Analysis
Acid Value (AV)
Saponification
Procedure.
Iodine Value (IV)
Method I (Hanus Method)
Method II
KI Solution
Hydroxyl Value
Ester Value (EV)
Acetyle Value
Analysis of Alkaloids
Classification Established upon the Biogenesis
Protoalkaloids
Pseudoalkaloids
True Alkaloids
Classification Established upon the Ring Structure
Tropane Alkaloid
Pyrrolizidine Alkaloids
Piperidine Alkaloids
Quinolines Alkaloid
Isoquinoline Alkaloids
Indole Alkaloids
Steroidal Alkaloids
Imidazole Alkaloid
Purine Alkaloids
Pyrrolidine Alkaloids
Tests of Alkaloids
General Precipitative Reagents
Colour Tests
Analysis of Volatile Oil
Chapter 5
Electrochemical Methods of Analysis
Electrochemical Cell
Notation to Describe the Electrochemical Cell
Galvanic or Voltaic Cell
Galvanic Cell Characterized by Following Features
Electrolytic Cell or Electrolysis
Electrolytic Cells Are Characterized by the Following Features
Reversible Cell
Standard Hydrogen Electrode (SHE)
Standard Electrode Potential
Ohmic Drop (IR)
Electrochemical Cell Construction and Working
Different Cell Design
Surface Area
Stirring
Electrode
Types of Electrochemical Methods
Constant Current Electrolysis
Factors Affecting the Deposition
Constant Potential Electrolysis
Application of Electrogravimetry
Coulometry
Principle and Theory
Types of Coulometry
Coulometry at Constant Potential
Controlled-Current Coulometry
Applications of CPC and CCC
Coulometric Titration
Conductometry
Voltammetry
Types of Voltammetry Methods
Hydrodynamic Voltammetry
Pulse Voltammetry
Stripping Voltammetry.
Cyclic Voltammetry
Principle Methods Involved in Voltammetry
Polarography
Types of Polarography
Apparatus and the Methods
Electrodes
Limitations of Polarography
Advantages
Amperometry
Potentiometry
Typical Arrangement for a Potentiometric Sensor
Limitation
Types of Working Electrodes Used in the Electrochemical Analysis (Carbon Nanocomposite-Based Electrodes)
Mercury Capillary Electrodes
Carbon Paste Electrodes (SPEs)
Glassy Carbon Electrodes (GCEs)
Carbon Ceramic Electrodes (CCEs)
Graphite Rod or Pencil Graphite Electrode (GREs)
Metallic Electrodes (MEs)
Screen-Printed Electrode
Transparent Conducting Electrodes
Rotating Disk Electrode (RED)
Rotating Ring-Disk Electrode (RRDEs)
Acknowledgement
Chapter 6
Radiochemical Methods of Analysis
What Is Radiochemistry?
What Is Radiochemical Analysis?
General Principle of Radiochemical Analysis
Drawbacks of Radiochemical Analysis
Selection of Radiochemical Analysis
Types of Radiochemical Analysis
Neutron Activation Analysis
Principle of Neutron Activation Analysis
Applications of Neutron Activation Analysis (NAA)
Isotope Dilution Analysis
Radioactive Isotopes Dilution or Direct Dilution of Isotope
Inactive Isotopes Dilution or Reverse Dilution of Isotopes
Inactive Isotopes of Multiple Dilution or Double Dilution of Isotope
Application of Isotope Dilution Method
Tracer Method
Principle of the Tracer Method
Applications of the Tracer Method
Radioactive Decay
Radioactive Decay Law
Types of Radioactive Decay
Alpha Decay
Beta Decay
Negative Beta Decay.
Positive Beta Decay.
Notes:
Includes bibliographical references and index.
Description based on publisher supplied metadata and other sources.
Description based on print version record.
Other Format:
Print version: Saadullah, Malik Functional Analytical Techniques in Pharmaceutical Chemistry
ISBN:
9798886972887
OCLC:
1347028215

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