Metal-organic framework composites. Volume I / edited by Anish Khan [and four others].

Format:

Book

Contributor:

Khan, Anish, editor.

Series:

Materials research foundations ; Volume 53.

Materials research foundations ; Volume 53

Language:

English

Subjects (All):

Metallic composites.

Nanocomposites (Materials).

Organometallic compounds.

Physical Description:

1 online resource (278 pages).

Edition:

1st ed.

Place of Publication:

Millersville, PA : Materials Research Forum LLC, [2019]

Summary:

The present book covers design, synthesis and preparation of various MOFs, as well as the resulting product characteristics: homogenous morphology, small size dispersion, high thermal stability and desired surface area. Keywords: Metal-Organic Frameworks (MOFs), Composites Based on MOFs, Energy Storage, Catalysts, Environmental Sensors, Environment Safety, Industrial Wastewater Treatment, Enzyme Encapsulation, Composite Characterization, Electrochemical Sensors, Metallizing Polymer Fibers, Electroless Coatings, Radio Frequency (RF) Ion Sputtering, High Velocity Oxygen Fuel (HVOF), Thermal Spray Processes, Metal-polymer Composites, Green Applications, Clean Energy, Water Adsorption, Water Harvesting, High Performance Polymer Fibre-Metal Matrix Composites, Layered Rare Earth Hydroxides, Nanocarbon Synthesis, Polyoxometalate-Based MOFs Composites.

Contents:

Intro

front-matter

Table of Contents

Preface

1

Metal-Organic-Frameworks (MOFs) for Industrial Wastewater Treatment

1. Introduction

1.1 Background of MOFs

2. Structure and types of Metal-Organic-Frameworks

3. Fabrication/preparation of Metal-Organic-Frameworks

3.1 Conventional synthesis

3.2 Alternative synthesis

3.2.1 Microwave synthesis

3.2.2 Electrochemical synthesis

3.2.3 Mechanochemical synthesis

3.2.4 Sonochemical synthesis

4. Application of MOFs for wastewater treatment

4.1 Effect of MOFs on water pollutants

Conclusion

References

2

Metal-Organic Frameworks and their Composites for the Development of Electrochemical Sensors for Environmental Applications

2. Synthesis of MOFs and MOF composites

3. Sensors based on MOF for environmental applications

4. Electrochemical sensor based on MOF for environmental applications

4.1 Heavy metal ion detection

4.1.1 Detection of lead ion (Pb2+)

4.1.2 Detection of copper ion (Cu2+)

4.2 Sensing of inorganic ions

4.2.1 Detection of Nitrite ion (NO2-)

4.3 Sensing of organic compounds

3

Metal-Organic Frameworks for Wastewater Treatment

2. Treatment of inorganic pollutants in wastewater by MOFs

2.1 Cations

2.2 Anions

3. Treatment of organic pollutants in wastewater by MOFs

3.1 Organic dyes

3.2 Drugs

3.3 Other harmful organisms

Conclusions and perspectives

4

Metal-Organic-Framework (MOFs) and Environmental Application

1.1 Outline

1.2 Background on MOFs

2. Problems associated with wastewater treatment

2.1 Diverse categories of contaminants

2.1.1 Microbe-derived contaminants

2.1.2 Common water pollution index

2.1.3 Emerging pollutants.

2.1.4 Toxicity and symptoms of WWT (Waste Water Treatment) poisoning

3. Treatment methods in WWT

3.1 Activated sludge treatment (AST)

3.2 Advanced wastewater treatment

3.3 Miscellaneous treatments

3.3.1 Activated carbon (AC)

3.3.2 Ion-exchange

4. MOF performance in diverse WWT applications

4.1 MOFs in adsorption applications for WWT

4.2 MOFs in separation applications for WWT

4.3 MOFs in sensing applications for WWT

4.4 MOFs in miscellaneous WWT applications

5. Perspectives on the use of MOFs in WWT

5

High Performance Polymer Fibre-Metal Matrix Composites of Metal-Organic Frameworks - Metallization, Processing, Properties and Applications

2. Materials

2.1 Poly-benzobisoxazole (PBO)

2.2 Aluminium

3. Metallization of HPP

4. Electroless coating

5. Pre-treatment of PBO fibres

6. Copper coating of PBO fibres

7. TGA characterization

8. HVOF thermal spray coating

9. HVOF thermal spray high performance polymer reinforced MMCs

Conclusions

Limitations and further research

Acknowledgement

6

Condensation of WO42- Polyhedra Units on Layered Rare Earth Hydroxides Nanosheets: Hierarchical Channels and Heavy Metal Adsorption

2. Experimental

2.1 Materials and methods

2.2 Methods

2.3 Characterization of the Sorbent materials

2.4 Adsorption experiment

2.5 Kinetic studies

3. Results and discussion

Acknowledgements

7

Designing Metal-Organic Frameworks for Clean Energy Applications

2. MOFs for clean energy applications

2.1 MOFs for fuel cells

2.2 MOFs for solar cell

2.3 MOFs for lithium-ion batteries

Conclusion and future perspective

8

Metal-Organic Frameworks for Water Adsorption.

1. Introduction

2. Water adsorption isotherm of MOFs

3. Water adsorption mechanisms

4. Water harvesting processes

5. Criteria for MOFs

6. Factors affecting adsorption of MOFs

Conclusions and outlooks

9

Flexibility in Metal-Organic Frameworks: A Fundamental Understanding

1. Introduction about MOFs and its structure

2. Origin of MOFs flexibility

2.1. Flexibility of functionalized linkers

2.1.1 Carboxylate linkers

2.2. Flexibility of the metal nodes

3. General aspects of framework flexibility

3.1 Breathing, swelling and linker rotation

3.2 Thermoresponsivity

3.3 Mechanical properties, elasticity

3.4 Photoresponsive

4. How to control MOFs flexibility

4.1 Metal ion

4.2 Ligand (functional group)

4.2.1 Secondary building block unit (SBU)

4.2.2 Linker substitution

4.2.3 Introduction of bulky side chains at the flexible edge of the MOF

4.2.4 Linker rotation

4.3 Post-synthetic modification (crystal size)

5. Characterization of Flexibility in MOFs

6. Applications

Abbreviation

10

Metal-Organic Frameworks as Host for Encapsulation of Enzymes

2. Encapsulation of enzymes in MOFs

2.1 In situ enzyme encapsulation within the MOFs

2.2 Post-synthetic enzyme encapsulation within the MOFs

2.2.1 Pore encapsulation

3. Advantages of enzyme encapsulation

3.1 Recyclability

3.2 Catalytic activity

3.3 Stability

4. Summary and outlook

Abbreviations

11

MOF-Derived Nanocarbons: Synthesis, Properties, and Applications

2. General methods for preparation of MOF-derived nanocarbons

3. Structural peculiarities

4. Influence of pyrolysis conditions and initial MOF structure on the final structure of nanocarbons

5. Bimetallic MOF-derived carbons.

6. Role of N-doping

7. Main applications of MOF-derived nanocarbons

Conclusions and further outlook

12

Polyoxometalate-Based Metal-Organic Framework Composites

2. Application of POM-based MOF in electrocatalysts

3. Application of POM-based MOF in photocatalysis

4. Application of POM-based MOF in lithium storage

5. Application of POM-based MOF in adsorption

Concluding Remarks

Reference

back-matter

Keyword Index

About the Editors.

Notes:

Description based on print version record.

Description based on publisher supplied metadata and other sources.

ISBN:

1-64490-029-7

OCLC:

1108570558