Catalytic Reactions in Hydrogen Energy Production : Physicochemical Fundamentals.

Format:

Book

Author/Creator:

Li, Bolin.

Language:

English

Subjects (All):

Hydrogen as fuel.

Catalysis.

Physical Description:

1 online resource (744 pages)

Edition:

1st ed.

Place of Publication:

Chantilly : Elsevier Science & Technology, 2025.

Summary:

Catalytic Reactions in Hydrogen Energy Production: Physicochemical Fundamentals elucidates the activation mechanism of molecular chemical bonds, the construction law of catalytic site orientation and the catalytic mechanism in the catalytic reaction processes involved in hydrogen energy production (including electrocatalysis, photocatalysis and.

Contents:

Front Cover

Catalytic Reactions in Hydrogen Energy Production

Copyright

Contents

I - Hydrogen energy and electrocatalysis

1 - Introduction to hydrogen energy and electrocatalysis

1.1 Introduction

1.2 Fundamental principles of electrocatalysis

1.3 Relationship between hydrogen energy and electrocatalysis

1.4 Summary

Acknowledgments

References

2 - Basic principle of hydrogen production by electrolysis of water

2.1 Introduction

2.2 Basic principle of cathode hydrogen evolution

2.3 Basic principle of anodic oxygen evolution

2.3.1 Adsorption evolution mechanism (AEM)

2.3.2 Lattice oxygen mechanism (LOM)

2.3.3 Oxide path mechanism (OPM)

2.4 Basic principle of full water electrolysis

2.5 Summary

3 - Performance evaluation of hydrogen production by electrolysis of water

3.1 Introduction

3.2 Thermodynamics and kinetics

3.2.1 Thermodynamics

3.2.1.1 Basic theories and equations

3.2.1.2 Thermodynamic basis of HER

3.2.1.3 Thermodynamic basis of OER

3.2.2 Kinetics

3.2.2.1 Kinetic basis of electrode reaction

3.2.2.2 Kinetic loss in electrolyzer

3.3 Overpotential principle and test

3.3.1 Overpotential principle

3.3.2 Overpotential test

3.3.2.1 Cyclic voltammetry (CV)

3.3.2.2 Linear sweep voltammetry (LSV)

3.4 Tafel curve principle and test

3.4.1 Tafel curve principle

3.4.2 Tafel curve test

3.5 Stability principle and test

3.6 Faraday efficiency (FE)

3.7 Turnover frequency (TOF)

3.8 Electrochemical impedance curve (EIS)

3.9 Electric double layer capacitance (Cdl)

3.10 Test system and three-electrode cell

3.11 Summary

4 - Catalytic materials for electrolysis of water to hydrogen production

4.1 Introduction.

4.2 Cathode hydrogen evolution catalytic materials

4.2.1 Precious metal HER catalyst

4.2.2 Non-precious metal HER catalyst

4.3 Anodic oxygen evolution catalytic material

4.3.1 Basic design principles of OER electrocatalysts

4.3.2 Basic categories and active sites of OER electrocatalysts

4.3.3 Typical research cases of OER electrocatalysts

4.3.3.1 Ni3S2 electrocatalysts

4.3.3.2 LDHs electrocatalysts

4.3.3.3 NiCo2O4 electrocatalysts

4.3.3.4 Heteroatom doping electrocatalysts

4.4 Bifunctional catalytic materials

4.5 Summary

5 - Design of catalytic materials for electrolysis of water

5.1 Introduction

5.2 Nanoscale design

5.2.1 Low dimensional nanomaterials

5.2.2 High-curvature nanomaterials

5.2.3 High-porosity nanomaterials

5.3 Composite interface design

5.4 Doping modification control

5.5 Vacancy defect engineering

5.6 Atomic structure design

5.7 Electronic structure regulation

5.7.1 Charge transfer effect

5.7.2 d-band center theory

5.7.3 Electron metal-support interaction (EMSI)

5.8 Summary

6 - The coupling design of water electrolysis and other systems

6.1 Introduction

6.2 Coupling design of electrolytic water and organic matter oxidation

6.3 Coupling design of electrolytic water and gas reduction

6.4 Design of solar powered water electrolysis system

6.5 Design of wind powered water electrolysis system

6.6 Design of hydraulically driven electrolytic water system

6.7 Summary

7 - Design of other electrolytic hydrogen production system

7.1 Introduction

7.2 Hydrogen production by electrolysis of sodium borohydride solution

7.3 Hydrogen production by electrolysis of ammonia solution

7.4 Hydrogen production by electrolysis of seawater.

7.5 Summary

8 - Results and prospects of hydrogen energy and electrocatalysis

8.1 Introduction

8.2 Results for hydrogen energy and electrocatalysis

8.3 Prospects for hydrogen energy and electrocatalysis

8.4 Summary

II - Hydrogen energy and photocatalysis

9 - Introduction of hydrogen energy and photocatalysis

9.1 Introduction

9.2 Research progress of photocatalysis

9.3 Relationship between hydrogen energy and photocatalysis

9.4 Summary

10 - The basic principle of photocatalysis for water splitting

10.1 Introduction

10.2 Basic principles of photocatalysis

10.3 Basic principle of hydrogen production by photocatalytic splitting of water

10.4 Basic principle of photocatalytic total decomposition of water

10.5 Summary

11 - Performance evaluation of hydrogen production by photolysis of water

11.1 Introduction

11.2 Thermodynamics and kinetic theory

11.2.1 Photocatalytic thermodynamics

11.2.2 Photocatalytic kinetics

11.3 Principle and evaluation of co-catalysts

11.4 Photocatalytic hydrogen production system and performance test

11.5 Stability principle and test of photocatalytic hydrogen

11.6 Other principle and test

11.7 Summary

12 - Catalytic materials for photocatalysis of water splitting

12.1 Introduction

12.2 Physicochemical basis of photocatalyst

12.3 Visible light response catalytic materials

12.3.1 Basic classification and characteristics

12.3.2 Polymer carbon nitride for visible-light hydrogen production

12.3.2.1 Graphite-phase carbon nitride (g-C3N4)

12.3.2.2 Poly triazinimide (PTI)

12.3.3 Other semiconductors for visible-light hydrogen production

12.3.3.1 ZnIn2S.

12.3.3.2 Red phosphorus

12.3.3.3 MOFs

12.3.3.4 COFs

12.4 Near infrared light responsive catalytic materials

12.5 Co-catalyst materials for hydrogen and oxygen evolution

12.6 Summary

13 - Design of catalytic materials for photocatalysis of water splitting

13.1 Introduction

13.2 Nanoscale design

13.2.1 Nano size control

13.2.1.1 Size effect

13.2.1.2 Charge separation and migration

13.2.1.3 Specific surface area and reactive site

13.2.2 Nano dimension control

13.2.2.1 2D/2D combination

13.2.2.2 Combination of other dimensions

13.2.3 Nano crystal face control

13.3 Heterogeneous structure design

13.3.1 Heterojunction design principle

13.3.2 Heterojunction basic classification

13.3.3 Heterojunction interfacial electric field

13.4 Doping modification control

13.5 Vacancy defect engineering

13.6 Atomic structure design

13.7 Electronic structure regulation

13.8 Summary

14 - Results and prospects of hydrogen energy and photocatalysis

14.1 Introduction

14.2 Hydrogen energy and photocatalysis results

14.3 Hydrogen energy and prospects for photocatalysis

14.4 Summary

III - Hydrogen energy and thermocatalysis

15 - Introduction of hydrogen energy and thermocatalysis

15.1 Introduction

15.2 Research progress of thermocatalysis

15.3 Relationship between hydrogen energy and thermocatalysis

15.4 Summary

16 - Principle and catalyst of hydrogen production by water gas shift

16.1 Introduction

16.2 Basic principle of hydrogen production by water gas shift

16.3 Catalyst for water-gas-shift reaction

16.3.1 Nano catalysts

16.3.2 Cluster catalysts

16.3.3 Single atom catalysts

16.3.4 Mixed dimension catalysts.

16.4 Regulation and optimization of water-gas-shift reaction

16.4.1 Structure-activity relationship

16.4.2 Strong metal-support interaction

16.4.3 In situ characterization of catalytic mechanisms

16.5 Opportunities and challenges of water-gas shift reaction

16.5.1 Opportunities for water-gas shift reactions

16.5.2 Challenges for water-gas shift reactions

16.6 Summary

17 - Principle and catalyst of methane reforming hydrogen production

17.1 Introduction

17.2 Basic principle of hydrogen production by methane reforming

17.2.1 Basic principle of SRM

17.2.2 Basic principle of DRM

17.2.3 Basic principle of POM

17.2.4 Basic principle of CDM

17.3 Catalyst for methane reforming reaction

17.3.1 Catalyst for SRM

17.3.2 Catalyst for DRM

17.3.3 Catalyst for POM

17.3.4 Catalyst for CDM

17.4 Regulation and optimization of methane reforming reaction

17.4.1 Design of nanostructured catalysts

17.4.2 Design of single atom catalysts

17.4.3 Plasma-assisted reforming of methane

17.5 Opportunities and challenges of methane reforming reaction

17.5.1 Opportunities

17.5.1.1 Abundant raw material resources

17.5.1.2 Relatively mature technology

17.5.1.3 Driven by the growing demand for hydrogen energy

17.5.1.4 Compatibility with existing energy infrastructure

17.5.2 Challenges

17.5.2.1 The problem of carbon emissions

17.5.2.2 Less efficient

17.5.2.3 Equipment corrosion and carbon accumulation problems

17.5.2.4 Pressure of competition

17.6 Summary

18 - Principle and catalyst of methanol reforming hydrogen production

18.1 Introduction

18.2 Basic principle of hydrogen by methanol reforming

18.2.1 Methanol steam reforming (MSR)

18.2.2 Partial oxidation of methanol (POM).

18.2.3 Autothermal methanol reforming (ATMR).

Notes:

Description based on publisher supplied metadata and other sources.

Part of the metadata in this record was created by AI, based on the text of the resource.

ISBN:

0-443-29121-7

9780443291210

OCLC:

1553138891