Transition metals - an overview / edited by Veronica J. Avila.

Format:

Book

Contributor:

Avila, Veronica J., editor.

Series:

Earth Sciences in the 21st Century Series

Language:

English

Subjects (All):

Geology.

Physical Description:

1 online resource (142 pages)

Edition:

1st ed.

Place of Publication:

New York, New York : Nova Science Publishers, Incorporated, [2023]

Summary:

"This book contains five selected chapters which provide an overview of transition metals. Chapter One explores transition metal based cathode materials for lithium-ion cells. Chapter Two reviews recent advances on the functionalization of 4-quinolone derivatives via transition metal catalysis. Chapter Three examines the screened exchange interaction in bulk at the interface of transition metals. Chapter Four summarizes the synthesis, characterization, and use of the copper(II)-1,4-bis-(3-hexafluoroacetylacetonate)benzene framework. Chapter Five reviews iron(III) nitrate as a catalyst in acid-catalyzed reactions"-- Provided by publisher.

Contents:

Intro

Contents

Preface

Chapter 1

Transition Metal Based Cathode Materials for Lithium-Ion Cells

Abstract

1. Introduction

2. Cathode Materials

2.1. Role of Transition Metals in Cathode Materials

2.2. Types of Cathode Materials

2.2.1. Layered Cathode Materials

2.2.1.1. Lithium Cobalt Oxide (LiCoO2)

2.2.1.1.1. Alternative Cathodes for LiCoO2

2.2.1.2. Lithium Nickel Manganese Cobalt Oxide (NMC) Cathode Materials

2.2.1.3. Lithium-Rich Cathode Materials

2.2.2. Olivine Cathodes

2.2.3. Spinel Cathodes

2.2.4. Inverse Spinel

2.3. Strategies to Enhance Electrochemical Performance of Cathode Materials

2.3.1. Surface Modification

2.3.1.1. Oxides

2.3.1.2. Fluorides

2.3.1.3. Phosphates

2.3.2 Elemental Doping

Conclusion

Acknowledgments

References

Chapter 2

Recent Advances on the Functionalization of 4-Quinolone Derivatives Via Transition Metal Catalysis

2. Functionalization

2.1. Cross-Coupling Reactions

2.1.1. Suzuki Coupling and Cyanation

2.1.2. Suzuki Coupling

2.1.3. Carbonylative Suzuki Coupling

2.1.4. Sonogashira Coupling

2.1.5. Suzuki, Sonogashira and Aminocarbonylation

2.1.6. Heck Coupling

2.1.7. C-N Coupling

2.2. Decarboxylative Cross (C-C) Coupling

2.3. Decarboxylative ipso-Nitration

2.4. Decarboxylative Thioetherification

2.5. C-H Functionalization

2.5.1. Alkenylation

2.5.2. Alkynylation

2.5.3. Amidation

2.5.4. Arylation

2.6. Miscellaneous Reactions

2.6.1. -CF2 insertion

2.6.2. Annulation

2.7. Asymmetric Synthesis

2.8. Oxidative Carbonylation

Chapter 3

Screened Exchange Interactions at the Interface of Transition Metals

2. Theories of Electric Field Screening.

2.1. Thomas-Fermi Theory for a Many-Electrons System

2.2. Lindhard Dielectric Function

2.3. Friedel Theory for an Interacting Electron System

3. Screened Exchange Interactions in the Bulk of Transition Metal

3.1. Screened Hund Exchange

3.2. Screened − Exchange Interaction

4. Exchange in Magnetic Interface of Transition Metals

4.1. Interlayer RKKY Interaction

4.2. Intralayer Dzyaloshinskii-Moriya Interaction

Appendix: Charge and Spin Susceptibility of Interacting Electrons

Charge Susceptibility

Spin Susceptibility

Biographical Sketch

Chapter 4

Synthesis, Characterisation and Use of the Copper(II)-1,4-Bis- (3-Hexafluoroacetylacetonate)

Benzene Framework

Introduction

Experimental Section

General Information

Synthesis of L

Synthesis of ML

Results and Discussion

Solubility of ML

PXRD of ML

FESEM of ML

EDS of ML

AFM of ML

Thermal Stability of ML

Electrochemical Sensing of Caffeine by ML

Chapter 5

Iron(III) Nitrate As a Catalyst in Acid-Catalyzed Reactions

Catalysis

Esterification Reactions

Ketalization Reactions

Catalytic Runs

Effect of Lewis Acid Catalyst in the Esterification Reaction of β-Citronellol with HOAc

Metal Nitrate Catalyzed Glycerol Condensation Reactions with Ketone

Index

Blank Page

Blank Page.

Notes:

Includes index.

Description based on print version record.

Other Format:

Print version: Avila, Veronica J. Transition Metals - an Overview

ISBN:

9798886977004

OCLC:

1376194703