Conjugated microporous polymers / Atsushi Nagai.

Format:

Book

Author/Creator:

Nagai, Atsuchi, author.

Language:

English

Subjects (All):

Polymers.

Porous materials.

polymers.

filter (materials).

Physical Description:

x, 228 pages : illustrations (black and white, and colour) ; 23 cm

Place of Publication:

Singapore : Jenny Stanford Publishing, [2025]

Summary:

Conjugated microporous polymers (CMPs) with various structures and properties have been synthesized, and it is possible to design the molecular structure of the conjugated skeleton and nanopores. Research on CMPs in clean energy technologies is important for the improvement of CMP-based materials and their applications in energy and environmental engineering. CMPs show great potential for solving energy and environmental problems such as gas adsorption, photocatalysis, solar energy conversion, and electrical energy storage and conversion.This book summarizes the progress in the synthesis and design of CMPs and their applications in clean energy technologies such as hydrogen generation and storage, carbon dioxide adsorption and conversion, rechargeable batteries, supercapacitors, and photocatalytic H2 production. It describes the design, synthesis, and recent developments of conjugated microporous polymers with emphasis on the possible applications of these materials. The book is a useful resource for students and researchers involved in the development of porous materials.

Contents:

Cover

Half Title

Title Page

Copyright Page

Table of Contents

Preface

Chapter 1: Porous Organic Materials

1.1: Porous Materials

1.2: Porous Organic Polymers

1.2.1: Hyper-Crosslinking Polymers

1.2.2: Covalent Triazine Frameworks

1.2.3: Covalent Organic Frameworks

1.2.4: Conjugated Microporous Polymers

Chapter 2: Synthetic and Structural Studies of CMPs

2.1: Design and Synthesis

2.1.1: Design Principles

2.2: Synthesis Routes

2.2.1: Sonogashira-Hagihara Coupling

2.2.2: Suzuki-Miyaura Coupling

2.2.3: Yamamoto Coupling

2.2.4: Heck Coupling

2.2.5: Cyclotrimerization Reactions

2.2.6: Phenazine Ring Fusion

2.2.7: Schiff-Base Condensation

2.2.8: Heterocycle Linkages

2.2.9: Alkyne Metathesis

2.2.10: Oxidative Coupling

2.2.11: Buchwald-Hartwig Amination

2.2.12: Electropolymerization

2.2.13: Hypercrosslinking Linear Conjugation

2.2.14: Post-Synthesis Modification

2.3: Control Over Porous Structure

2.3.1: Control by Tuning Monomer Structure and Ratio

2.3.2: Control by Tuning Reaction Conditions

2.3.3: Control by Post-Modification Approach

2.4: Perspectives and Challenges

Chapter 3: Surface Area and the Theory of Porous Materials

3.1: Introduction

3.2: Gas Sorption Theory

3.2.1: Langmuir Model

3.2.2: Brunauer-Emmett-Teller Theory

3.2.3: Isotherm Shapes

3.2.4: Adsorption Hysteresis

Chapter 4: Gas Storage of CMPs

4.1: Natural Equilibrium

4.2: Greenhouse Gas Emissions

4.2.1: Carbon Dioxide Capture

4.2.2: Hydrogen Gas Storage

4.2.3: CMPs for Photocatalytic Hydrogen Evolution

4.2.4: Methane Gas Storage

Chapter 5: Heterogeneous CMP's Catalyst Applications

5.1: Introduction

5.2: Conjugated Microporous Polymers for Heterogeneous Catalysis

5.2.1: Heterogeneous Transition-Metal Catalysis

5.2.2: Heterogeneous Ir-Catalyzed Reductive Amination

5.2.3: CMPs for Heterogeneous Fe-Catalyzed Oxidation of a Sulfide and Epoxidation of Olefins

5.2.4: Heterogeneous Ru-Catalyzed Asymmetric Hydrogenation

5.2.5: CMPs for Heterogeneous Ag-Catalyzed Heterocyclization

5.2.6: Heterogeneous Cu-Catalyzed Hydrosilylation of Terminal Alkynes and CO2

5.2.7: Heterogeneous Pd-Catalyzed Carbon-Carbon Bonding Coupling Reactions

5.3: Heterogenous Organocatalysis

5.4: CMPs for Heterogeneous Photocatalytic Applications

5.5: Conclusion and Perspective

Chapter 6: CMP's Energy Storage Applications

6.1: Introduction

6.2: CMPs as Electrode for LIBs

6.2.1: Comparison of Covalent Organic Frameworks and CMPs

6.2.2: CMPs as Cathode Materials for LIBs

6.2.3: CMPs as Anode Materials for LIBs

6.3: CMPs as Electrode for SIBs

6.3.1: CMPs as Cathode Materials for SIBs

6.3.2: CMPs as Anode Materials for SIBs

6.4: CMPs for Supercapacitors

6.5: Conclusion and Future Outlook

Chapter 7: CMP's Semiconductor Applications

Notes:

Includes bibliographical references and index.

Other Format:

ebook version :

ISBN:

9789815129663

981512966X

OCLC:

1496486416

Publisher Number:

90104344760