Lead Accumulation on Automotive Catalysts Ford Motor Company

Format:

Conference/Event

Author/Creator:

Hammerle, R. H., author.

Conference Name:

SAE International Congress & Exposition (1983-02-28 : Detroit, Michigan, United States)

Language:

English

Physical Description:

1 online resource

Place of Publication:

Warrendale, PA SAE International 1983

Summary:

Engine dynamometer and laboratory flow reactor studies of automotive catalyst deactivation caused by the use of leaded fuel indicate that there are two different deactivation mechanisms: one, which dominates between 700 and 800 C, is the poisoning of the active platinum sites by lead oxide, or perhaps lead, and the other, which occurs below 550 C, is a build up of a gas diffusion barrier of lead sulfate. Both deactivation mechanisms can be temporarily reversed. Poisoning is reversed when the platinum is freed of lead oxide by lead sulfate formation below 650 C; and the barrier formed below 550 C can be made more permeable by thermal sintering of the lead sulfate at 600 to 700 C or its decomposition to lead oxide at 700 to 800 C. However, further exposure of the catalyst will again render it inactive via the mechanism predominating in that temperature region

Notes:

Vendor supplied data

Publisher Number:

830270

Access Restriction:

Restricted for use by site license