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Effect of Fuel/Air Ratio Variations on Catalyst Performance and Hydrocarbon Emissions During Cold-Start and Warm-Up General Motors Research and Development Center

SAE Technical Papers (1906-current) Available online

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Format:
Conference/Event
Author/Creator:
Drake, Michael C., author.
Conference Name:
1996 SAE International Fall Fuels and Lubricants Meeting and Exhibition (1996-10-14 : San Antonio, Texas, United States)
Language:
English
Physical Description:
1 online resource
Place of Publication:
Warrendale, PA SAE International 1996
Summary:
Effects of fuel/air equivalence ratio variations (Φ = 1.0±0.02) on engine-out and catalyst-out hydrocarbon (HC) mass and speciated emissions were measured under simulated cold-start conditions in order to suggest ways to optimize the engine-controls-catalyst system for minimum HC mass emissions and specific reactivity. A single-cylinder engine (installed in a temperature-controlled room and using commercial-grade gasoline) is run under controlled steady-state conditions (at 24 °C or -7 °C) which simulate cold starting. Speciated and total hydrocarbon emissions are measured from engine-out exhaust samples and from samples taken after an oven-temperature-controlled catalyst (either a fresh platinum/rhodium production catalyst, a 50,000 mile vehicle-aged catalyst, or a ceramic brick with standard washcoat containing no noble metal). Changes in engine fuel/air equivalence ratio (Φ = 1.0±0.02) have a small effect on engine-out HC mass emissions (± 10 %) and specific reactivity (0 - 2%). However, changing Φ from 1.02 (slightly rich) to 0.98 (slightly lean) has a large effect on catalyst performance - decreasing post-catalyst ozone forming potential values by a factor of 36 for a fresh catalyst and a factor of 6 for an aged catalyst
Notes:
Vendor supplied data
Publisher Number:
962075
Access Restriction:
Restricted for use by site license

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