Electrooxidation Behaviour of Pt/Carbon Electrocatalyst for Phosphoric Acid Fuel Cells (PAFC) Institute CNR-TAE

Format:

Conference/Event

Author/Creator:

Passalacqua, E., author.

Conference Name:

27th Intersociety Energy Conversion Engineering Conference (1992) (1992-08-03 : San Diego, California, United States)

Language:

English

Physical Description:

1 online resource

Place of Publication:

Warrendale, PA SAE International 1992

Summary:

The electrooxidation of carbon black, which contains Pt electrocatalyst particles, was investigated in concentrated phosphoric acid at 0.6 to 1.0V. At the high potentials, anodic dissolution of Pt is rapid, and consequently no metal is present to catalyze the corrosion of carbon at 160 °C in 98% H3PO4. On the other hand, at 0.6V anodic dissolution of Pt is negligible, and hence it is present to catalyze the corrosion of carbon. In fact, the measurements indicate that the corrosion rate is noticeable higher than that of carbon black without Pt. These results suggest the Pt particles with surface Pt-0 may serve as an intermediary which facilitates the corrosion of carbon

Notes:

Vendor supplied data

Publisher Number:

929294

Access Restriction:

Restricted for use by site license