Zinc Dialkyldithiophosphate-Dispersant Interactions: Effects on Solution Behavior and Wear The Lubrizol Corporation

Format:

Conference/Event

Author/Creator:

Kulp, M. J., author.

Conference Name:

International Fuels and Lubricants Meeting and Exposition (1992-10-19 : San Francisco, California, United States)

Language:

English

Physical Description:

1 online resource

Place of Publication:

Warrendale, PA SAE International 1992

Summary:

Interactions between a Zinc dialkyldithiophosphate (ZDP) and three different commercially available succinimide dispersants were observed through changes in solutions behavior, as determined by viscometry and Fourier Transform Infrared spectroscopy (FTIR), and four-ball tests.The viscometric response observed for two component blends of ZDP and succinimide dispersant in white oil changed as a function of the molar Zn to N ratio, indicative of specific interactions. The break in the viscometric response curve occurred at Zn:N=0.13 for all three succinimide dispersants. FTIR spectra of the same ZDP-dispersant blends were examined and similar Zn:N dependencies were observed.Four-ball tests measuring wear scar diameter, seizure load and weld load showed a dependence on the Zn to N ratio similar to that observed by viscometry. At very low Zn to N ratios wear and seizure load were decreased, while at higher ratios the seizure and weld loads were increased over that for ZDP alone. These studies show that either ZDP-dispersant complexation and/or competition between the ZDP and the dispersant for the metal surface affects wear as measured by the four-ball test

Notes:

Vendor supplied data

Publisher Number:

922282

Access Restriction:

Restricted for use by site license