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Hydrogen Selective Catalytic Reduction of Nitrogen Oxide on Pt- and Pd-based Catalysts for Lean-Burn Automobile Applications Clean Combustion Research Center, KAUST

SAE Technical Papers (1906-current) Available online

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Format:
Book
Conference/Event
Author/Creator:
Alghamdi, Nawaf M., author.
Contributor:
Anjum, Dalaver H.
Gascon, Jorge
Im, Hong G.
Kalamaras, Christos
Restrepo Cano, Juan
Sarathy, S. Mani
Conference Name:
SAE Powertrains, Fuels & Lubricants Meeting (2020-09-22 : Krakow, Poland)
Language:
English
Physical Description:
1 online resource cm
Place of Publication:
Warrendale, PA SAE International 2020
Summary:
The utilization of H2 to catalytically treat NO emissions under lean-burn conditions was studied on Pt- and Pd-containing catalysts supported on CeO2 and MgO. The catalytic performance was examined using a fixed-bed reactor whose dry effluent gas stream was analyzed by an online FTIR analyzer. The catalysts NO conversion and N2 selectivity were measured in the range of 125-300⁰C with a feed gas composition of 0.05%NO/1%H2/10%O2/N2. The CeO2-based catalysts exhibited higher NO conversion, and the most effective catalyst was Pd/CeO2, with an NO conversion of 67% and an N2 selectivity of 70% near 230⁰C. The prepared solids were characterized using different techniques (BET, ICP-OES, CO pulse chemisorption, STEM, EELS and EDS) to correlate the structural and morphological properties of the metallic phase and the support with the catalytic activity. Compared to MgO, CeO2 is a more effective support as it yields higher metal dispersion and better facilitates the reduction of Pt and Pd
Notes:
Vendor supplied data
Publisher Number:
2020-01-2173
Access Restriction:
Restricted for use by site license

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