Metal Complexes : Environmental and Biomedical Applications.

Format:

Book

Author/Creator:

Sahu, Rojalin.

Contributor:

Sahu, Puspanjali.

Language:

English

Physical Description:

1 online resource (0 pages)

Edition:

1st ed.

Place of Publication:

Sharjah : Bentham Science Publishers, 2024.

Summary:

Metal Complexes: Environmental and Biomedical Applications offers a comprehensive exploration of the role of metal complexes in diverse fields, including biomedicine, energy, and environmental protection. This book provides insights into the synthesis, properties, and applications of metal complexes, covering topics such as their use in therapeutics, diagnostics, energy materials, and catalysis. It also examines their antibacterial, antifungal, and sensor applications. With a systematic approach, the book is ideal for students, researchers, and professionals interested in the growing relevance of metal complexes in scientific and industrial applications. Key Features:- Overview of metal complexes and oxidation states.- Synthesis of metal complexes from N-heterocyclic carbene and Schiff base ligands.- Biomedical applications, including therapeutics and diagnostics.- Use of metal complexes in energy storage and catalysis.- Applications in antibacterial and antifungal treatments.- Metal complexes as sensors and in analytical chemistry. Readership:Undergraduate/graduate students, researchers, and professionals in biochemistry, biology, inorganic chemistry, and medicinal chemistry.

Contents:

Cover

Title

Copyright

End User License Agreement

Contents

Preface

Introduction to Metal Complexes: A Special Reference to Oxidation States

INTRODUCTION

OXIDATION STATE CONCEPT

3D TRANSITION SERIES ELEMENTS

Chromium (Cr)

Manganese (Mn)

Iron (Fe)

Cobalt (Co)

Nickel (Ni)

Copper (Cu)

Zinc (Zn)

ELEMENTS OF THE 4D SERIES

Technetium (Tc)

Ruthenium (Ru)

Rhodium (Rh)

Palladium (Pd)

Silver (Ag)

Cadmium (Cd)

ELEMENTS OF THE 5D SERIES

Rhenium (Re)

Osmium (Os)

Iridium (Ir)

Platinum (Pt)

Gold (Au)

Mercury (Hg)

CONCLUSION

REFERENCES

Synthesis of Metal Complexes from N-Heterocyclic Carbene and Schiff Base Ligands

METAL COMPLEX SYNTHESIS BY WATER-SOLUBLE POTENTIAL N-HETEROCYCLIC CARBENE (NHCS)

Metal Complex Functionalized with Ester or Carboxylate/carbonate

Metal Complexes with Sulfonate Functionalized NHCs

Metal Complex Synthesized from Ammonium /amine Functionalized NHCs

Metal Complexes from NHCs Functionalized with ether/alcohol

Metal Complexes from Water-soluble Polymer or Macrocycle Functionalized NHCs

Metal Complex Synthesis from NHCs Functionalized with Natural Product

WATER SOLUBILITY OF N-HETEROCYCLIC CARBENE-BASED METAL COMPLEXES

SCHIFF BASE AS A LIGAND

METHODS OF SCHIFF BASE COMPLEX SYNTHESIS

Direct Synthesis

In situ Method

Oxidation of Coordinated Secondary Amine

Amine Exchange Reaction

Metal Exchange Reaction

Ligand Exchange Reaction

METAL COMPLEX SYNTHESIS

Mode of Coordination of a Schiff Base Ligand

Coordination Complex Based on Bidentate Schiff Base Ligands

Tridentate Schiff Base or mixed Ligand-based Coordination Complex

Tetradentate Schiff Base Coordination Complexes

REFERENCE

Biomedical Applications of Clathrochelates

INTRODUCTION.

Application of Clathrochelates in Animal and Human Diagnostics and Therapy

APPLICATIONS OF NUCLEAR MAGNETIC RESONANCE PARAMAGNETIC PROBES AND CLATHROCHELATES IN MAGNETIC RESONANCE IMAGING

CLATHEROCHELATES BASED ON BORON AND THEIR APPLICATION

RADIOACTIVE CLATHROCHELATE COMPLEX FOR DIAGNOSTICS AND RADIOTHERAPY

RH AND TC COMPOUNDS AND OTHER RADIOEMITTER CLATHROCHELATES AND THEIR APPLICATION

CLATHROCHELATE COMPOUNDS OF 68GA AND 64CU AND THEIR APPLICATION

BIOACTIVE AND BIOMIMETIC METAL CAGES AND BIOPROBES BASED ON CLATHROCHELATES

Application of Metal Complexes in Therapeutics

APPLICATION OF METALS IN MEDICINE

CHARACTERISTICS OF METAL COMPLEXES

ANTI-CANCER AGENTS BASED ON TRANSITION METAL COMPLEXES

Platinum

Anticancer Agents other than Platinum

ANTI-INFECTIVE DRUGS OF TRANSITION METAL COMPLEXES

FREE RADICAL QUENCHER AND ANTI-INFLAMMATORY AGENTS BASED ON TRANSITION METAL

ANTIDIABETIC AGENTS BASED ON TRANSITION METALS

NEUROLOGICAL DRUGS BASED ON TRANSITION METALS

DIAGNOSTIC TOOL AND DELIVERY PROBES BASED ON TRANSITION METAL

SOME ESSENTIAL DRUGS BASED ON METAL AND THEIR CHEMISTRY

Applications of Metal Complexes in Diagnosis

METAL COMPLEXES PROPERTIES

MODES OF DIAGNOSIS

RADIOMETALS REQUIREMENTS FOR IMAGING

RADIONUCLIDES PRODUCTION

METAL-BASED RADIOPHARMACEUTICALS

Technetium

Rhenium

Gallium

Indium

Copper

Yttrium

MAGNETIC RESONANCE IMAGING AGENTS

Gadolinium

Eu(II)

Manganese

Iron complexes

POSITRON EMISSION TOMOGRAPHY IMAGING AGENTS

Zirconium

Metal Complexes used as Energy Materials

LANTHANIDE METAL COMPLEX AS ELECTROLUMINESCENT MATERIAL.

SCHIFF BASE METAL COMPLEXES-BASED ENERGY AND ORGANIC PHOTOVOLTAIC MATERIALS

TRANSITION METAL OXALATE AND OTHER COMPLEX-BASED ENERGY STORAGE AND PHOTOINDUCED ENERGY TRANSFER MATERIALS

8-HYDROXYQUINOLINE METAL COMPLEX AS ELECTRO- LUMINESCENT MATERIALS

Metal Complexes used in Analytical Chemistry: A Special Focus on the Detection and Determination of Metal Ions

INTRODUCTION OF METAL IONS FROM VARIOUS SOURCES IN THE ENVIRONMENT

Alkaline Earth Metal

Transition Element

Metalloid

ANALYTICAL METHODS FOR THE DETECTION OF METAL IONS

Precipitation Analysis

Reagents for the Detection of Metal Ions

Gravimetry Analysis

Volumetric Analysis

Volumetric Reagents

Hexacyanoferrate (II)

Hexa-cyanoferrate (III)

Mercury(I)

Hexa-amminecobalt (III) chloride

Tetracyano(1,10-phenanthroline)ferrate(II)

Potassium Octacyanomolybdate and Octacyanotungstate

Cerate Complexes

Indicators

Solvent Extraction

DETECTION OF METALS USING DIFFERENT REAGENTS BASED ON METAL COMPLEX

Antimony

Beryllium

Cadmium

Potassium

Cobalt

Gold

Indium and Thallium

Mercury

Molybdenum

Nickel

Palladium

Rhodium

Thorium

Uranium

Alkali Metals

Other Metals

DETECTION OF IONS USING DIFFERENT REAGENTS

Acetate

Nitrate

Nitrite

Phosphates

Pyrophosphate and Triphosphate

Sulphate

MISCELLANEOUS ANALYTICAL APPLICATIONS

Metal Complexes in Catalysis

OXIDATION PROCESSES

Wacker Process

Olefins Epoxidation Reaction Mo(VI) Complex Catalyst

Olefins Epoxidation Asymmetrically in the Presence of Oxidant Hydroperoxide and Titanium Complex

Decomposition Reaction of Cyclohexyl Hydroperoxide in the Presence of Trivalent and Divalent Cobalt Complex

THE HYDROCYANATION REACTION.

METATHESIS REACTION

HYDROSILYLATION REACTION

CARBONYLATION REACTION

OLEFIN POLYMERIZATION

HYDROGENATION REACTION

DIMERIZATION, OLIGOMERIZATION AND CYCLOOLIGOMERI- ZATION

ISOMERIZATION

MAIN GROUP METAL-BASED CHIRAL SCHIFF BASES

CHROMIUM AND MANGANESE SCHIFF BASES

Antibacterial and Antifungal Applications of Metal Complexes

CHROMIUM COMPLEXES

MOLYBDENUM COMPLEXES

MANGANESE COMPLEXES

RHENIUM COMPLEXES

RUTHENIUM COMPLEXES

OSMIUM COMPLEXES

COBALT COMPLEXES

RHODIUM AND IRIDIUM COMPLEXES

NICKEL COMPLEXES

PALLADIUM AND PLATINUM COMPLEXES

COPPER COMPLEXES

GOLD COMPLEXES

ZINC COMPLEXES

CADMIUM AND MERCURY COMPLEXES

SILVER-METAL COMPLEXES

ALKALI METAL COMPLEXES

LANTHANIDES COMPLEXES

Metal Complexes as Sensors to Detect Analytes

CHEMOSENSORS BASED ON METAL COMPLEXES

MECHANISMS AND PRINCIPLES OF CHEMOSENSORS BASED ON METAL COMPLEXES FOR SENSING CATIONS

FLUORESCENCE DETECTION OF CATIONS BY CONVENTIONAL APPROACHES

Photoinduced Electron Transfer (PET) Mechanism

Photoinduced Charge Transfer (PCT) Mechanism

Transmetallation Approach for Chemosensing

Chemodosimetric Approach

CONVENTIONAL FLUORESCENT CHEMOSENSORS FOR CATIONS BASED ON CU (II) COMPLEXES

CD(II) COMPLEXES AS TRADITIONAL FLUORESCENT CHEMOSENSORS FOR CATIONS

RECOGNITION AND SENSING OF ANIONS BASED ON INTERACTION BETWEEN METAL AND LIGAND

Subject Index

Back Cover.

Notes:

Description based on publisher supplied metadata and other sources.

ISBN:

9789815238723

9815238728