Electrochemical Energy Storage Technologies Beyond Li-Ion Batteries : Fundamentals, Materials, Devices / Guanjie He, editor.

Format:

Book

Contributor:

He, Guanjie, editor.

Language:

English

Subjects (All):

Energy storage.

Energy storage--Equipment and supplies.

Physical Description:

1 online resource (611 pages)

Edition:

First edition.

Place of Publication:

Cambridge, MA : Elsevier Inc., [2025]

Summary:

Electrochemical Energy Storage Technologies Beyond Li-ion Batteries focuses on an overview of the current research directions to enable the commercial translation of electrochemical energy storage technologies.First, the principles of energy storage mechanisms and device design considerations are introduced.

Contents:

Intro

Electrochemical Energy Storage Technologies Beyond Li-ion Batteries: Fundamentals, Materials, Devices

Copyright

Contents

Contributors

Preface

Part 1: Fundamentals of electrochemical energy storage technologies

Chapter 1: Fundamental electrochemical energy storage mechanisms

1. Overview

2. Electron transfer and mass transport

3. Electrochemistry of electrolyte

3.1. Aqueous electrolyte

3.2. Organic electrolytes

3.3. Ionic liquids

3.4. Solid/quasisolid electrolytes

3.5. Solid polymer electrolytes

3.6. Gel polymer electrolytes

4. Electrochemistry of electrode

5. Interface

References

Chapter 2: Configurations of electrochemical energy storage devices

2. Device configuration design principles

2.1. Type of alkali metal ion battery

2.2. Cylindrical battery

2.3. Pouch cells

2.4. Square aluminum shell battery

2.5. Design principle of alkali metal ion battery

2.6. Negative/positive capacity ratio

2.7. Compaction density

2.8. Material and specification of separator

2.9. Amount of electrolyte added

2.10. Safety management principles

3. Redox flow batteries (RFBs)

3.1. All-vanadium RFBs

3.2. Zinc-based RFBs

3.3. Zinc-air RFBs

3.4. Zinc-iron RFBs

4. The function of separators

4.1. The action mechanism of separator in batteries

4.2. The main parameters influence separators performances

4.3. Polyolefin-based separator and functional membrane

4.4. Separators beyond polyolefins with extra active functions

4.5. Separators for sodium-ion battery

4.6. Synthesis of separators for sodium-ion battery

4.7. Modification of sodium-ion battery separators

Chapter 3: Material characterization and electrochemical test techniques

1. Introduction.

2. Basic characterization and electrochemical test techniques

2.1. X-ray diffraction

2.2. X-ray absorption spectroscopy

2.3. X-ray photoelectron spectroscopy

2.4. Scanning electron microscopy

2.5. Transmission electron microscopy

2.6. Fourier transform infrared spectroscopy

2.7. Raman spectroscopy

2.8. Electrochemical impedance spectroscopy

2.9. Cyclic voltammetry

3. Advanced characterization and electrochemical test techniques

3.1. Neutron powder diffraction

3.2. Neutron total scattering

3.3. Neutron reflection

3.4. Neutron imaging

3.5. Electrochemical quartz crystal microbalance

4. Conclusion

Chapter 4: Selected quantum chemical studies on the surfaces and interfaces of carbon materials for applications in&amp

s

1. Introduction

1.1. Architecture of lithium-ion batteries

1.2. Reactions in LIBs

1.3. Other group I elements as alternatives to Li

2. A brief introduction to density functional theory (DFT)

2.1. Hohenberg-Kohn theorems

2.2. Kohn-Sham equations

2.3. Exchange and correlation functional

3. The interaction of Li, Na, and K with carbon materials

3.1. Interaction with PAHs

3.2. Graphite intercalation compounds

3.3. Graphene with defects and doped graphene

3.4. Graphite oxides and graphene oxides

4. Concluding remarks and perspectives

Acknowledgment

Part 2: Non-lithium-ion rocking chair batteries: Candidate materials and device design considerations

Chapter 5: Sodium-ion batteries

2. Anode materials

2.1. Intercalation anodes

2.1.1. Carbon-based materials

2.1.2. Graphite

2.1.3. HC/soft carbon

2.1.4. Graphene and rGO

2.1.5. MXenes

2.1.6. Titanium-based anodes

2.1.7. Titanium dioxide (TiO2)

2.1.8. Sodium titanate (Na2Ti3O7)

2.1.9. Lithium titanate (Li4Ti5O12).

2.1.10. Sodium hexa-titanate (Na2Ti6O13)

2.1.11. Titanium niobate (TiNb2O7)

2.1.12. Vanadium-based anodes

2.2. Conversion anodes

2.2.1. Metal oxides

2.2.2. Metal phosphides

2.2.3. Metal tellurides

2.2.4. Metal sulfides/selenides

2.3. Conversion+alloying anodes

2.4. Alloying anodes

3. Electrolytes for NIBs

4. Separators and current collectors for NIBs

5. Cathode materials

5.1. Layered oxide cathodes

5.1.1. Cationic potential concept

5.1.2. Anionic redox reactions

5.1.3. High entropy layered oxides

5.2. Polyanionic cathodes

5.2.1. Phosphate-based polyanions

5.2.2. Sulfate and mixed polyanions

5.3. PBAs

6. Conclusions

Acknowledgments

Chapter 6: Potassium-ion batteries: Mechanism, design, and perspectives

2.1. Carbon-based anodes

2.1.1. Graphite

2.1.2. Graphene

2.1.3. Nongraphite carbon

2.2. Non-carbon-based anodes

2.2.1. Intercalation-type anodes

2.2.2. Conversion-type anodes

2.2.3. Alloying-type anodes

3. Cathode materials

3.1. Layered transition metal oxides

3.1.1. AxMO2-type cathodes

3.1.2. Vanadium oxides

3.2. Prussian blue analogs

3.3. Polyanionic compounds

3.4. Organic cathode materials

4. Electrolytes

4.1. Organic liquid electrolytes

4.2. IL electrolytes

4.3. Solid-state electrolytes

4.4. Aqueous electrolytes

5. Binders

6. Conclusion and perspectives

Chapter 7: Zinc-ion batteries: Recent trends in zinc-ion batteries

2. Materials used in zinc-ion batteries

2.1. Anode

2.1.1. Zinc anode

2.1.2. Zinc corrosion behavior

2.1.3. Zinc dendrite formation hypothesis

2.1.4. Protection of the zinc anode

2.2. Cathode

2.2.1. Manganese-based oxides

2.2.2. γ-MnO2

2.2.3. α-MnO2.

2.2.4. Vanadium-based cathode materials

2.2.4.1. V2O5 cathode materials

2.2.4.2. VxOy cathode materials

2.2.4.3. MxVyOz vanadate cathode materials

2.3. Electrolytes

2.3.1. Aqueous electrolyte

2.3.2. Concentrated electrolytes

2.3.3. Gel electrolyte

2.4. Current collector

2.5. Separators

2.6. Conclusion and perspectives

Chapter 8: Rechargeable magnesium-ion batteries: From mechanism to emerging materials

2. Working mechanism and main challenges

3. Cathode

3.1. Polyanionic cathode materials

3.2. Spinel cathode materials

3.3. Transition metal oxides

3.4. Transition metal sulfides

3.5. Transition metal selenides

4. Anode

4.1. Alloy anode

4.2. Mg metal anode

4.3. Metal oxide anode

4.4. Carbon-based anode

5. Electrolyte

5.1. Mg(TFSI)2

5.2. Nonnucleophilic electrolyte

5.3. Some other electrolytes

6. Summary and outlooks

Chapter 9: Aluminum-ion batteries

1. Introduction of rechargeable aluminum-ion batteries

2. Cathode materials

2.1. AlCl4- intercalation cathode materials

2.2. Al3+ intercalation cathode materials

2.3. Conversion-type cathode materials

2.4. Summary

3. Electrolytes

3.1. Nonaqueous liquid electrolytes

3.2. Aqueous electrolytes

3.3. Gel polymer electrolytes

3.4. Summary

4. Al metal anode and related technologies

5. Other materials

5.1. Binders

5.2. Current collector

5.3. Separator

5.4. Summary

Chapter 10: Calcium-ion batteries

1. A general introduction to this technology

2. Challenges in developing modern CIBs

3. Anode materials

3.1. Metallic calcium anodes

3.2. Alloy anodes

3.3. Intercalation anodes

3.4. Organic anodes

4. Cathode

4.1. Prussian blue analogs.

4.2. Oxides

4.3. Chalcogenides

4.4. Organic materials

4.5. Other cathode materials

5. Perspectives

5.1. Advanced computation for screening electrode materials

5.2. Surface modification

5.3. Defects engineering

5.4. Designing nanostructure for fast Ca2+ diffusion

5.5. Multiion strategies

5.6. Optimization of testing conditions

Chapter 11: Materials electrochemistry for dual-ion batteries

1. Understanding of dual-ion batteries

1.1. Introduction

1.2. Fundamentals of dual-ion batteries

2. Positive electrode design

2.1. Graphite

2.1.1. Electrochemistry and fundamentals in graphite

2.1.2. Influencing factors and strategies

2.2. Other cathode candidates

3. Negative electrode design

3.1. Intercalation- and conversion-type anodes

3.2. Alloying-type anodes

3.3. Metallic and organic materials

4. Electrolyte design

4.1. Standard liquid electrolyte

4.2. Solvation effect of anions

4.3. Functional additives

4.4. High-concentration electrolytes

4.5. Quasi-solid-state and gel polymer electrolytes

5. Conclusion and perspectives

Part 3: Emerging metal-air batteries and fuel cells: Candidate materials and device design considerations

Chapter 12: Lithium-air batteries

2.1. Oxygen-selective membranes and their positive effects on Li metal anode

2.2. In situ protective layers

2.3. External anodic hydrophobic protective coatings

2.4. Lithium liquid metal as the anode

3. Air-cathode materials

3.1. Carbon-based catalyst

3.2. Transition metal oxide-based catalyst

3.3. Spinel oxide-based catalysts

3.4. Perovskite oxide catalysts

4.1. Nonaqueous electrolyte

4.2. Aqueous electrolyte

4.3. Solid-state electrolyte

5. Other components

5.1. Current collectors.

5.2. Separators.

Notes:

Includes bibliographical references and index.

Description based on publisher supplied metadata and other sources.

Description based on print version record.

ISBN:

9780443155154

0443155151

OCLC:

1477222333