Solvent-free methods in nanocatalysis : from catalyst design to applications / editors, Rafael Luque, Manoj B. Gawande, Esmail Doustkhah, Anandarup Goswami.

Format:

Book

Contributor:

Luque, Rafael, editor.

Gawande, Manoj B., editor.

Doustkhah, Esmail, editor.

Goswami, Anandarup, editor.

Wiley InterScience (Online service)

Language:

English

Subjects (All):

Nanostructured materials.

Catalysis.

Physical Description:

1 online resource (352 pages)

Place of Publication:

Weinheim : Wiley-VCH, [2023]

Contents:

Cover

Title Page

Copyright

Contents

Preface

Chapter 1 Introduction: Scope of the Book

1.1 Introduction: Green Chemistry, Solvent-free Synthesis, and Nanocatalysts

1.2 Topics Covered in this Book

1.3 Solvent-Free Synthesis of Nanocatalysts

1.4 Solvent and Catalyst-Free Organic Transformations

1.5 Solvent-Free Reactions Using NCs

1.5.1 Different Metal Oxides as a Catalyst/Support in Solvent-Free Reaction

1.5.1.1 Titanium Oxide

1.5.1.2 Tin Oxide

1.5.1.3 Manganese Oxide (MnOx)

1.5.1.4 Zinc Oxide

1.5.1.5 Aluminum Oxide

1.5.1.6 Iron Oxide

1.5.2 Silica-Based Materials as Catalysts/Supports in Solvent-Free Organic Reactions

1.5.3 Carbon-Based Materials as Catalysts/Supports in Solvent-Free Organic Reactions

1.5.4 Nitride-Based Materials as Catalysts/Supports in Solvent-Free Organic Reactions

1.5.5 Ionic Liquid-Based Materials as Catalysts/Supports in Solvent-Free Organic Reactions

1.6 Present Status and Future Direction

References

Chapter 2 Strategies for the Preparation of Nanocatalysts and Supports Under Solvent-Free Conditions

2.1 Introduction

2.2 Mechanochemistry

2.2.1 Ball Milling

2.2.2 Mortar and Pestle

2.3 Thermal Treatment

2.3.1 Simple Thermal Treatment

2.3.2 Thermal Decomposition

2.3.3 Microwave Heating Energy

2.4 Plasma-Assisted Methods

2.4.1 Thermal Plasma Method

2.4.2 Cold Thermal Plasma Method

2.5 Deposition Method

2.5.1 Atomic Layer Deposition (ALD) Method

2.5.2 Chemical Vapor Deposition (CVD) Method

2.6 Conclusion and Future Perspective

Acknowledgments

Chapter 3 Solvent- and Catalyst-Free Organic Transformation

3.1 Introduction

3.2 Solvent- and Catalyst-Free Organic Transformations

3.2.1 Mechanochemistry

3.2.2 Microwave Irradiation

3.2.3 Classical Heating

3.2.4 Ultrasound Irradiation.

3.3 Conclusion

Chapter 4 Metal Oxides as Catalysts/Supports in Solvent-Free Organic Reactions

4.1 Introduction

4.2 Different Metal Oxides as a Catalyst/Support in Solvent-Free Reactions

4.2.1 Titanium Dioxide-Based Catalysts

4.2.2 Tin Oxide-Based Catalysts

4.2.3 Manganese Oxide-Based Catalysts

4.2.4 Zinc Oxide-Based Catalysts

4.2.5 Aluminum Oxide-Based Catalysts

4.2.6 Iron Oxide-Based Catalysts

4.2.6.1 Fe3O4-Based Catalyst/Support

4.2.6.2 Fe2O3-Based Catalyst/Support

4.3 Conclusion

Chapter 5 Silica-Based Materials as Catalysts or Supports in Solvent-Free Organic Reactions

5.1 Solvent-Free Reactions Over Silica Gel

5.2 Silica Nanoparticles and its Applications

5.3 Zeolites and Hierarchical Zeolite Structures

5.4 Conclusion

Chapter 6 Carbon-Based Materials as Catalysts/Supports in Solvent-Free Organic Reactions

6.1 Introduction

6.2 Solvent-Free Catalysis Using Carbon-Based Materials

6.2.1 Activated Carbons (ACs)

6.2.1.1 Acetylation Reactions

6.2.1.2 Oxidation of Cyclohexane

6.2.2 Carbon-Based Solid Acid (CBSA) Catalysts

6.2.2.1 Cross-Aldol Condensation of Ketones with Aromatic Aldehydes

6.2.2.2 Substituted Imidazoles

6.2.2.3 Amidoalkyl Naphthols

6.2.2.4 Reductive Amination of Aldehydes and Ketones

6.2.2.5 Xanthenes and Dibenzoxanthenes

6.2.2.6 Dihydropyrimidinone Compounds (Biginelli Reaction)

6.2.2.7 Acylation, Acetalization, Thioacetalization of Aldehydes

6.2.3 Carbon Nanotubes (CNTs)

6.2.3.1 Esterification of Alcohols

6.2.3.2 Benzyl Alcohol Oxidation

6.2.3.3 Phenol Derivatives Antioxidants

6.2.3.4 Acrylonitrile Derivatives

6.2.4 Graphene Oxide (GO)

6.2.4.1 Alkylaminophenols Derivatives

6.2.4.2 N-Arylation Reactions

6.2.4.3 Oxidation of Benzylic Alcohols.

6.2.4.4 Aldol and Konevenagel Condensation Reaction

6.2.4.5 Oxidation of Cyclohexene

6.2.4.6 Oxidation of Hydrazide and Pyrazole Derivatives

6.2.5 Porous Carbon Materials

6.2.5.1 Oxidation of Alcohol and Hydrocarbons

6.2.5.2 Coupling of Amines

6.3 Summary and Future Perspectives

Chapter 7 Nitride-Based Nanostructures for Solvent-Free Catalysis

7.1 Carbon Nitride

7.1.1 Introduction

7.1.2 Synthesis of Carbon Nitride

7.1.3 Modification of Carbon Nitrides

7.1.4 Solvent-Free Catalysis with Carbon Nitrides

7.2 Boron Nitride

7.2.1 Introduction

7.2.2 Synthesis and Modification of Boron Nitride

7.3 Molybdenum Nitride

7.3.1 Introduction

7.3.2 Synthesis of Molybdenum Nitride

7.3.3 Solvent-Free Catalytic Application of Molybdenum Nitride

7.4 Aluminum Nitride

7.4.1 Introduction

7.4.2 Synthesis of Aluminum Nitride

7.4.2.1 Solvent-Free Synthesis

7.4.3 Solvent-Free Application of Aluminum Nitride

7.5 Conclusion

Chapter 8 Supported Ionic Liquids for Solvent-Free Catalysis

8.1 Introduction

8.2 Supported Ionic Liquids

8.3 Building Blocks of SILs

8.3.1 Ionic Segment

8.3.2 Solid-Support Segment

8.3.2.1 Silica Gels

8.3.2.2 Ordered Mesoporous Silicas

8.3.2.3 Carbon Nanotubes (CNTs)

8.3.2.4 Silica-Coated Magnetic Nanoparticles (SMNPs)

8.4 SIL Catalytic Systems

8.5 Supported IL Solvent-Free Catalysis

8.6 Solvent-Free Hydrogenation of Olefins

8.7 Solvent-Free Heck Reaction

8.8 Solvent-Free Multicomponent Reactions

8.8.1 Synthesis of Pyran-Based Heterocycles

8.8.2 Synthesis of 1,4-Dihydropyridine (Hantzsch Reaction)

8.8.3 Synthesis of 3,4-Dihydropyrimidine-2(1H)-One/Thiones (Biginelli Reaction)

8.8.4 Synthesis of 1-Amidoalkyl Naphthol

8.8.5 Miscellaneous Solvent-Free Multicomponent Reactions.

8.9 Solvent-Free Condensation Reactions

8.9.1 Solvent-Free Friedl̃nder Condensation

8.9.2 Solvent-Free Knoevenagel Condensation

8.9.3 Esterification

8.10 Solvent-Free CO2 Conversion Reactions

8.11 Solvent-Free Oxidation Reactions

8.12 Miscellaneous Solvent-Free Organic Reactions

8.13 Conclusion

Chapter 9 Present Status and Future Outlook

9.1 Summary

9.2 Future Outlook

Index

EULA.

Notes:

Includes bibliographical references and index.

Electronic reproduction. Hoboken, N.J. Available via World Wide Web.

Description based on online resource; title from digital title page (viewed on April 27, 2023).

Other Format:

Print version: Luque, Rafael Solvent-Free Methods in Nanocatalysis

ISBN:

9783527831463

3527831460

9783527831456

3527831452

Publisher Number:

90102556373

Access Restriction:

Restricted for use by site license.