Advanced Catalysts Based on Metal-Organic Frameworks. (Part 2) / edited by Junkuo Gao and Reza Abazari.

Format:

Book

Contributor:

Gao, Junkuo, editor.

Abazari, Reza, editor.

Language:

English

Subjects (All):

Catalysts.

Metal-organic frameworks.

Physical Description:

1 online resource (278 pages)

Edition:

First edition.

Place of Publication:

Singapore : Bentham Science Publishers Pte. Ltd., 2023.

Summary:

Advanced Catalysts Based on Metal-organic Frameworks is a comprehensive introduction to advanced catalysts based on MOFs. It covers basic information about MOF catalysts with industrial and environmental applications. The detailed chapters update readers on current applications and strategies to apply MOF-based catalysts in industrial processes geared for sustainability initiatives such as renewable energy, pollution control and combating carbon emissions. Key Features of Part 2 - 7 structured, easy to read chapters that comprehensively cover specific applications of MOF catalysts- In-depth explanation of photocatalytic reactions for multifunctional electrocatalysis, water splitting and CO2 Capture- Notes on MOF materials used in modern processes- Explanation of MOFs in advanced oxidation reactions- Introduction to Electrochemical biosensors- Updated references for advanced readers The is an essential reference for chemical engineers, scientists in the manufacturing and sustainability industry and post-graduate scholars working on MOFs and chemical catalysis.

Contents:

Cover

Title

Copyright

End User License Agreement

Content

Preface

List of Contributors

Metal-organic Frameworks and their Derived Structures for Photocatalytic Water Splitting

Reza Abazari1,2,*, Soheila Sanati2 and Junkuo Gao1,*

1. INTRODUCTION

2. MECHANISM AND PRINCIPLES OF PHOTOCATALYTIC WATER SPLITTING

3.1. Pristine MOFs as Photocatalysts for Splitting of Water

3.2. Composites Based on MOFs for Photocatalytic Splitting of Water

3.3. MOF-derived Photocatalysts

CONCLUDING REMARKS

LIST OF ABBREVIATIONS

CONSENT FOR PUBLICATION

CONFLICT OF INTEREST

ACKNOWLEDGEMENTS

REFERENCES

Metal-organic Frameworks and MOF-based Materials for Photocatalytic CO2 Reduction

Kayode Adesina Adegoke1,*, Nobanathi Wendy Maxakato1,*, Rhoda Oyeladun Adegoke2 and Olugbenga Solomon Bello2,3,*

2. FUNDAMENTAL PRINCIPLES OF PHOTOCATALYSIS

3. PROCESS OF PHOTOCATALYTIC CONVERSION OF CO2

4. THERMODYNAMICS ASPECTS OF CO2 PHOTOREDUCTION

5. MECHANISM AND KINETICS BEHIND THE PHOTOCATALYTIC CO2R

6.2. MOFs and MOF-based Composite Materials for CO2 Reduction

6.3. MOFs and MOF-based Derivatives for CO2 Reduction

Electrocatalytic Meralorganic Frameworks and OER Based on Metal-organic Frameworks and their Structure

Yingchong Huang1,#, Shuxuan Liu1,#, Tuyuan Zhu1,#, Chunyan Zhou1, Zhanguo Jiang1,* and Xuehui Gao1,*

2. MECHANISM OF WATER SPLITTING

2.1. Mechanism of HER

2.2. Mechanism of OER

3. EVALUATION PARAMETERS OF ELECTROCHEMICAL HYDROLYSIS

3.1. Overpotential (η)

3.2. Tafel Slope and Exchange Current Density

3.3. Turnover Frequency (TOF)

3.4. Electrochemical Active Surface Area

3.5. Faraday Efficiency.

5.2. Catalysts Encapsulated in MOFs

5.3. Catalysts Epitaxially Coordinated with MOFs

5.4. Composite of MOFs as Electrocatalyst for Overall Water Splitting

6. MOF-DERIVED MATERIALS FOR OER AND HER

6.1. Carbon Materials

6.2. Single Atom Catalysts

6.3. Metal/Metallic Compounds

6.3.1. Metal and Alloy

6.3.2. Metal Chalcogenides

6.3.3. Other Metal Compounds

6.4. MOF-derived Materials for Overall Water Splitting

CONCLUSIONS AND PROSPECTS

Recent Progress in Metal-Organic Frameworks and their Derivatives as Advanced Electrocatalysts for Oxygen Reduction Reactions

Jingsha Li1 and Chunxian Guo1,2,3,*

2. FUNDAMENTAL PRINCIPLES FOR OXYGEN REDUCTION REACTION (ORR)

3.2. MOFs-derived Heteroatom-doped Metal-free Carbon-based Materials

3.3. MOFs-derived Transition Metal and Nitrogen Co-doped Carbon Materials (M-Nx-C)

3.3.1. Fe-Nx-C Catalysts

3.3.2. Co-Nx-C Catalysts

3.3.3. Bimetallic-based MM'-Nx-C Catalysts

3.4. MOFs-derived Carbon-supported Single-Atom Catalysts (SACs)

3.4.1. Noble Metal SACs

3.4.2. Non-noble Metal SACs

4. SUMMARY AND PERSPECTIVE

MOFs and their Derived Structures for Multifunctional Electrocatalysis

Vera V. Khrizanforova1,* and Yulia H. Budnikova1

2. ORR/OER/ HER MECHANISMS

3. ELECTROCATALYSTS FOR OER/HER AND OVERALL WATER SPLITTING

4. OXYGEN ELECTROCATALYSTS

5. TRIFUNCTIONAL HER/OER/ORR ELECTROCATALYSTS

CONCLUSION

REFERENCES.

Metal-Organic Frameworks and their Derived Structures as Catalysts for Electrochemical Sensors

Jesús Antonio Cruz-Navarro1,*, Luis Humberto Mendoza-Huizar1, Verónica Salazar-Pereda1, Jose Ángel Cobos-Murcia1, Fabiola Hernandez-García1,* and Giaan A. Álvarez-Romero1,*

2. ELECTROANALYTICAL APPLICATIONS OF MOF COMPOSITES

2.1. Fabrication of Electrochemical Sensors Based on MOF Composites: An Overview

2.2. The Key Role of the Metal Centers on Redox Reaction Induced by MOFs Composites

2.3. Electrochemical Sensors Based on Pristine MOFs and MOFs Composites

2.4. MOF Modified Electrochemical Sensors for Biomedical Application

2.4.1. Detection of Glucose

2.4.2. Detection of Hydrogen Peroxide

2.4.3. Detection of Other Biomolecules

2.5. Environmental Applications: Electrochemical Sensing of Molecules with Biological Importance

2.5.1. Detection of Heavy Metals

2.5.2. Detection of Aromatic Compounds

Metal-organic Frameworks and MOF-based Materials for Electrocatalytic CO2 Reduction

Kayode Adesina Adegoke1,*, Solomon Oluwaseun Akinnawo2,3, Olugbenga Solomon Bello2,4,* and Nobanathi Wendy Maxakato1,*

2. MAJOR SIGNIFICANT ADVANTAGES OF ELECTROCHEMICAL APPROACH OVER OTHER METHODS OF CO2 CONVERSION

3. BASIC CONCEPT OF ELECTROCATALYTIC REDUCTION OF CO2

4. DESIGN OF MOF-BASED MATERIALS FOR THE ELECTROCATALYTIC REDUCTION OF CO2

6.1. Copper-based MOF Electrocatalysts

6.2. Iron-based MOF Electrocatalysts

6.3. Zinc-based MOF Electrocatalysts

6.4. Cobalt-Based MOF Electrocatalysts

6.5. Precious Metal-Based MOF Electrocatalysts

7.1. MOF-Derived Heteroatom-Doped Carbon Electrocatalysts.

7.2. MOF-Derived Isolated Atomic Metal Electrocatalysts

Subject Index

Back Cover.

Notes:

Description based on publisher supplied metadata and other sources.

Description based on print version record.

Includes bibliographical references.

ISBN:

9789815136029

981513602X

OCLC:

1394120248