Ionic Liquids : Eco-Friendly Substitutes for Surface and Interface Applications / edited by Chandrabhan Verma.

Format:

Book

Author/Creator:

Verma, Chandrabhan, Author.

Contributor:

Verma, Chandrabhan, editor.

Language:

English

Subjects (All):

Ionic solutions.

Physical Description:

1 online resource (427 pages)

Edition:

First edition.

Place of Publication:

Singapore : Bentham Science Publishers Pte. Ltd., 2023.

Summary:

Ionic Liquids: Eco-friendly Substitutes for Surface and Interface Applications explores the growing interest in utilizing ionic liquids as sustainable alternatives for various industrial and biological applications. With their unique properties and environmentally friendly nature, ionic liquids have emerged as promising substitutes for toxic and volatile solvents, offering significant advantages in surface and interface chemistry. This book is divided into two parts: Part 1 covers the basics of ionic liquids, their surface/interface properties, and interactions with metallic surfaces. Part 2 focuses on the wide range of surface and interface applications of ionic liquids, including wastewater treatment, corrosion protection, catalysis, separation processes, medical devices, and sensing applications. Key Features: A complete book fully dedicated to the surface and interface chemistry of ionic liquids with seventeen chapters Covers fundamentals, recent progress, and applications in surface/interface chemistry Presents up-to-date research and interdisciplinary insights Includes relevant references and resources for further exploration This is a valuable reference for scientists and engineers who want to learn about ionic liquids' chemistry and applications.

Contents:

Cover

Title

Copyright

End User License Agreement

Contents

Foreword 1

Foreword 2

Preface

List of Contributors

Ionic Liquids: Fundamental Properties and Classifications

Tejas M. Dhameliya1,*, Bhavya J. Shah1 and Khushi M. Patel1

1. INTRODUCTION

2. PROPERTIES OF ILS

3. CLASSIFICATION OF ILS

4. APPLICATIONS OF ILS

4.1. Energy Storage or Productions

4.2. Organic Transformations

4.3. Environmental Applications

4.4. Enzymatic Transformations

4.5. Extractions

4.6. Pharmaceutical Applications

CONCLUDING REMARKS

ABBREVIATIONS

ACKNOWLEDGEMENT

REFERENCES

Eco-friendly Nature of Ionic Liquids

Himani1, Anirudh Pratap Singh Raman1, Pallavi Jain2, Ramesh Chandra3,4, Kamlesh Kumari5, Vinod Kumar6 and Prashant Singh1,*

2. CATIONS AND ANIONS IN THE FORMATION OF ILS

2.1. Physical Properties of ILs

2.2. Application of IL Molecule Adsorbed and Confined in Silica Nanopores

2.3. ILs-based Processes for CO2 Capture

2.4. Self-assembled Hybrids Porous Polyoxometalate IL (PPOM-IL) for Exclusive Adsorption of Anion Dyes

3. MANUFACTURING INTERLAYER (ITL) SOLID-STATE METAL BATTERIES BASED ON LITHIUM

3.1. ILs with ITL of Polymer with Modified PEO-based Electrolyte (PEO-E) in Li-based Battery

3.2. Polyethyleneimine-modified Silica Nanoparticles (SiO2-PEI) for Anionic Dye Removal

4. APPLICATION OF ILS USING DIFFERENT CATIONS FOR CATHODE ITL IN TRADITIONAL POLYMER SOLAR CELLS (T-PSC)

5. DESIGNING GRAFTED PYRIDINIUM BASED ILS ON KAOLINITE

6. APPLICATION OF [C15MIM] [BR] BASED IL FOR MICELLE FORMATION

6.1. Enhancing Interfacial and Aggregation Properties of Cationic IL

6.2. Application of SAILs in Micelle Formation

7. ILS IN DRUG DELIVERY.

8. APPLICATION OF 1-ALLYL-3-METHYLIMIDAZOLIUM BROMIDE FOR ADSORPTION OF ANIONIC POLLUTANTS (NITRITE AND NITRATE)

CONCLUSION

Solid (Metal)-Liquid (Ionic Liquids) Interface: Basics and Properties

Manoj Kumar Banjare1,2,*, Kamalakanta Behera3,*, Ramesh Kumar Banjare4, Siddharth Pandey5,* and Kallol K. Ghosh2,*

2. HISTORY OF IONIC LIQUIDS

3. IONIC LIQUIDS

4. CLASSIFICATION OF IONIC LIQUIDS

4.1. Neutral Anions and Cations

4.2. Acidic Anions and Cations

4.3. Basic Anions and Cations

4.4. Amphoteric Anions

5. THE STRUCTURE OF IONIC LIQUID [C4MIM]PF6/RUTILE (110) INTERFACE

6. INTERFACE BETWEEN THE IL AND THE ELECTRODE

7. IONIC FLUID MONOLAYER TRAPPED BETWEEN GRAPHITE BARRIERS CHANGES FROM LIQUID TO SOLID PHASE

8. INTERFACE IL-HOPG

9. THE EFFECT OF SOLUTES ON THE INTERFACIAL STRUCTURE OF THE IL-ELECTRODE

10. SOLID INTERFACE (IL) NEAR-SURFACE

11. WATER'S IMPACT

12. EFFECT OF ROUGHNESS

13. TYPICAL PROPERTIES AND APPLICATIONS OF IONIC LIQUIDS-SOLID INTERFACE

Surfactants and Colloidal Properties of Ionic Liquids

Mansoor Ul Hassan Shah1, Masooma Nazar2, Syed Nasir Shah3, Hayat Khan1 and Muhammad Moniruzzaman2,4,*

2. SIGNIFICANCE PROPERTIES OF SURFACE-ACTIVE IONIC LIQUID (SAILS)

3. MICRO-EMULSION FORMATION BY EMPLOYING ILBS

4. AGGREGATION BEHAVIOR OF SAILS

4.1. Aggregation Properties of the Mixture of the Surfactants

5. APPLICATION OF ILBS FOR ENVIRONMENTAL REMEDIATION

6. COLLOIDAL PROPERTIES OF ILS

7. COLLOIDAL STABILITY OF ILS

7.1. Electrostatic Stabilization

7.2. Solvation Force in ILs

7.3. Steric Repulsion in Ils

7.4. Colloidal Stability of Dispersed Ils

8. POLY (ILS) COLLOIDAL SYSTEM

8.1. Micro/Nanoparticles in PIL

8.2. Micro/Nanogels PIL.

CONCLUDING REMARKS AND FUTURE PERSPECTIVES

ACKNOWLEDGEMENTS

Adsorption of Ionic Liquids on The Metal Surface: Co-ordination Chemistry Of Ionic Liquids

Dr. Shriniwas Gurjar1, Sonia Ratnani2,*, Sushil Kumar Sharma3 and Shobhana Sharma4

2. MECHANISM OF ADSORPTION OF IONIC LIQUIDS ON THE METAL SURFACE: COORDINATION CHEMISTRY OF IONIC LIQUIDS

2.1. Reaction at the Anodic Site (in the Absence of ILs)

2.2. Reaction at the Anodic Site (in the Presence of ILs)

2.3. Reaction at the Cathode Site (in the Absence of ILs)

2.4. Reaction at the Cathode Site (in the Presence of ILs)

3. FACTORS INFLUENCING THE ADSORPTION OF IONIC LIQUIDS WITH INVESTIGATED STUDIES

3.1. Structure of the Ionic Liquids

3.1.1. Cation Variant

3.1.2. Anion Variant

3.1.3. Number and Chain Length of the Alkyl Group

3.1.4. Nature of Functional Group

3.2. Temperature

3.3. Effect of Inhibitor Concentration

3.4. Effect of Immersion Time

Interactions of Ionic Liquids With Metal Surface: Effect of Cations And Anions

Omar Dagdag1,*, Rajesh Haldhar2, Seong-Cheol Kim2, Elyor Berdimurodov3,*, Chandrabhan Verma4, Ekemini D. Akpan1 and Eno E. Ebenso1,*

1.1. ILs: Property and Application

1.2. Mechanism of Corrosion Inhibition Using ILs

2. INTERACTIONS OF ILS WITH METAL SURFACE: EFFECT OF CATIONS AND ANIONS

2.1. Interaction Between IL and Fe(001) in MD Simulation

2.2. Interaction between ILs and Fe(001) in DFT analysis

2.3. Interaction Between ILs and Au(111) in Quantum Chemical Analysis

ACKNOWLEDGMENT

Self-Assembled Nanostructures within Ionic Liquids-based Media.

Jyoti Dhariwal1, Gaurav Choudhary1, Dipti Vaya1, Srikanta Sahu2, Manish Shandilya1, Poonam Kaswan1, Ambrish Kumar3, Shruti Trivedi3, Manoj K. Banjare4,* and Kamalakanta Behera1,5,*

2. IONIC LIQUIDS BASED MICELLES

2.1. Cationic IL-Based Surfactant

2.2. Anionic IL-Based Surfactant

2.3. Zwitterionic IL-Based Surfactant

3. EFFECT OF IL ON PROPERTIES OF SURFACTANT MICELLES

3.1. Effect of IL on the Properties of Anionic Surfactant

3.2. Effect of IL on the Properties of Non-ionic Surfactant

3.3. Effect of IL on Properties of Cationic Surfactant

3.4. Effect of IL on Properties of Zwitterionic Surfactant

4. IONIC LIQUIDS-BASED MICROEMULSIONS (MES)

5. TYPES OF IL-BASED MES

5.1. Non-Aqueous IL MEs

5.2. Aqueous IL-MEs

5.3. IL-Oil-Water MEs

6. APPLICATIONS OF IL-BASED MES

6.1. Reaction Medium for Catalysis and Synthesis

6.2. Polymerization

6.3. Nanomaterial Synthesis

6.4. Biocatalyst

6.5. Drug Delivery

6.6. Analytical Applications

Ionic Liquids: Eco-Friendly Substitutes for Surface and Interface Applications

Pradip M. Macwan1 and Pragnesh N. Dave2,*

2. WHAT ARE PHASE TRANSFER CATALYSTS (PTC)?

2.1. Types of PTC

2.2. Applications of PTC

2.3. Why Ionic Liquids Are Used as a Catalyst

2.4. What are Task-Specific Ionic Liquids (TSILs)

3. SYNTHESIS OF IONIC LIQUIDS

4. METHODS FOR THE SYNTHESIS OF IONIC LIQUIDS

4.1. Alkylation

4.2. Anion Exchange

4.3. Solvent-free Synthesis

4.4. Synthesis of Chiral

4.5. Synthesis of Ionic Liquids with a Special Performance

4.6. Microwave-Assisted Synthesis of Room-Temperature Ionic Liquid Precursor in Closed Vessel

5. CLASSIFICATION OF IONIC LIQUIDS ACCORDING TO ACIDITY/BASICITY

5.1. Neutral Anion.

5.2. Acidic Anions and Cations

5.3. Basic Cations and Anions

5.4. Anions Amphoteric

5.5. New Electrolyte for Solid-State Lithium-Ion Batteries

6. IONIC LIQUIDS ARE APPEALING AS POSSIBLE SOLVENTS FOR A VARIETY OF REASONS, INCLUDING

6.1. Benefits and Properties Of Ionic Liquids

7. PROPERTIES OF IONIC LIQUIDS

7.1. Properties of Ionic Liquids With Solvent Use

7.2. Purity of Ionic Liquids

8. IONIC LIQUIDS AS CATALYSTS

8.1. Applications of Ionic Liquids as a Catalyst In Organic Synthesis

9. VARIOUS SYNTHESES INVOLVING IONIC LIQUIDS AS THE CATALYST

9.1. Friedel-Crafts Alkylation and Acylation

9.2. Diels-Alder Reaction

9.3. Henry's Reaction

9.4. Fischer Indole Synthesis

10. BRØNSTED ACIDIC ILS (BAILS)

10.1. Esterification, Ether Formation, and Rearrangement Reaction In Bails

10.2. Esterification Reaction

10.3. Transesterification and Coupling Reactions

11. BRONSTED BASIC ILS

11.1. Michael's Addition

11.2. Knoevenagel Reaction

11.3. Henry's Reaction

11.4. Markovnikov's Addition

11.5. Mannich's Reaction

11.6. Feist-Benary Reaction

12. APPLICATIONS OF IONIC LIQUIDS IN TRANSITION-METAL-MEDIATED CATALYSES

12.1. Hydrogenation

12.2. Oxidation

12.3. Hydroformylation

12.4. Heck Reaction

12.5. Hydrodimerization

12.6. Alkoxycarbonylation

12.7. Trost-Tsuji Coupling

12.8. Suzuki-Cross Coupling Reaction

13. APPLICATION OF IONIC LIQUIDS IN BIOLOGICAL PROCESSES DEVELOPMENT

13.1. Biocatalytic Reductions Processes

13.2. Biotransformation Process

13.3. Ionic Liquids as Active Pharmaceutical Ingredients

Ionic Liquids in Wastewater Treatments

Enyioma C. Okpara1,*, Olanrewaju B. Wojuola1, Damian C. Onwudiwe2,3 and Victor Tshivhase4

2. WATER POLLUTION AND WASTEWATER TREATMENT TECHNIQUES.

2.1. Water Pollution.

Notes:

Includes bibliographical references.

Description based on publisher supplied metadata and other sources.

Description based on print version record.

ISBN:

9789815136234

9815136232

OCLC:

1394118386