Metal-organic framework composites. Volume II / edited by Anish Khan [and five others].

Format:

Book

Contributor:

Khan, Anish, editor.

Series:

Materials research foundations.

Materials research foundations

Language:

English

Subjects (All):

Coordination polymers.

Physical Description:

1 online resource (427 pages).

Edition:

1st ed.

Place of Publication:

Millersville, Pennsylvania : Materials Research Forum LLC, [2019]

Summary:

The book focusses on the following applications: gas capture and storage, especially molecular hydrogen storage; performance enhancement of Li-ion batteries; gas separation, nano-filtration, ionic sieving, water treatment, and catalysis, etc. Keywords: MOF Materials, Hydrogen Storage, Renewable Energy Applications, Lithium Batteries, MOF-Quantum Dots, Clean Energy, Nanoporous MOFs, Supercapacitors, Therapeutic Applications, Biosensing, Bioimaging, Phototherapy of Cancer, Gas Separation, Nano-filtration, Ionic Sieving, Water Treatment, Drug Delivery, Theranostics; Nanoparticle Photosensitizers, Photodynamic Therapy (PDT), Photothermal Therapy (PTT).

Contents:

Intro

front-matter

Table of Contents

Preface

1

Multiscale Study of Hydrogen Storage in Metal-Organic Frameworks

1. Introduction

2. DFT study of site characteristics in MOFs for hydrogen adsorption

3. Grand Canonical Monte Carlo (GCMC) for gravimetric and volumetric uptakes

Conclusion

Reference

2

Metal Organic Frameworks Based Materials for Renewable Energy Applications

2. Need for renewal energy

3. Metal organic frameworks

4. MOFs for environmental applications and renewable energy

5. Metallic organic framework based materials for hydrogen energy applications

6. Hydrogen Storage by MOFs

7. Storage of gases and separation process by MOFs

8. Metal organic frameworks based materials for conversion and storage of CO2

9. Use of MOFs for biogas

10. Storage of thermal energy using MOF materials

11. Metal organic frameworks based materials for oxygen catalysis

12. MOF based materials for rechargeable batteries and supercapacitors

13. Metal organic framework based materials in the use of dye sensitized solar cells

References

3

Metal Organic Frameworks Composites for Lithium Battery Applications

2. Applications of MOFs in lithium-ion batteries

3. Applications of MOFs in lithium sulphur batteries.

4. Summary and outlook

4

Metal-Organic-Framework-Quantum Dots (QD@MOF) Composites

1.1 Metal-organic frameworks

1.2 Quantum dots

1.3 Gold QDs (AuQDs)

2. QD polymeric materials

2.1 Integration of QDs

2.2 Methods of encapsulating QD to polymer matrices

2.3 Incorporation into premade polymers

2.4 Suspension polymerization

2.5 Encapsulation via emulsion polymerization

2.6 Encapsulation via miniemulsion polymerization

3. QD hybrid materials.

3.1 Strategies to generate QD hybrid materials

3.2 Exchanging ligand between polymer and QDs

3.3 Polymer grafting to QDs

3.4 Polymer grafting from QDs

3.5 Polymer capping into QDs

3.6 QDs growth within polymer

3.7 Challenges in biocompatible polymer/QDs

4. Applications of QD composites

4.1 Bio-imaging

4.2 Photo-thermal therapies

4.3 Opto-electric applications

4.3.1 QD LEDs

4.3.2 Polymer QD liquid crystal displays

4.3.3 QD polymer photo-voltaic devices

5. Metallic NCs

5.1 Classification of metallic NCs

5.2 Production of metallic NCs

5.2.1 Metallic NCs synthesis methods

5.3 Applications of metallic nano-particles

5.3.1 Silver NCs

5.3.2 Pbs QDs

5

Designing Metal-Organic-Framework for Clean Energy Applications

1.1 Introduction to MOF Composites &amp

Derivatives

1.2 Chemistry of MOFs

2. Applications of MOF in clean energy

2.1 Hydrogen Storage

2.2 Carbon dioxide capture

2.3 Methane storage

2.4 Electrical energy storage and conversion

2.4.1 Fuel cell

2.5 MOFs for supercapacitor applications

2.6 NH3 removal

2.7 Benzene removal

2.8 NO2 removal

2.9 Photocatalysis

6

Nanoporous Metal-Organic-Framework

1.1 Fundamental stabilities of nano MOFs

1.1.1 Chemical stability

1.1.2 In water medium

1.1.3 In acid/base condition

1.1.4 Thermal Stability

1.1.5 Mechanical Stability

1.2 Synthesis

1.2.1 Modulated synthesis

1.2.2 Post-synthetic modification (PSM)

1.3 Applications of MOFs

1.3.1 Gas separations and storage

1.3.2 Catalysis

1.3.2.1 Lewis acid catalysis

1.3.2.2 Bronsted acid catalysis

1.3.2.3 Redox Catalysis

1.3.2.4 Photocatalysis

1.3.2.5 Electrocatalysis

1.3.3 Water treatment

1.4 Other applications.

1.4.1 Sensors

1.4.2 Supercapacitors

1.4.3 Biomedical applications

7

Metal-Organic-Framework-Based Materials for Energy Applications

1.1 Role of MOF in supercapacitor

1.2 Role of MOF in oxygen evolution reaction (OER)

2. Synthesis of Ni3(HITP)2 MOF

3. Characterization of Ni3(HITP)2 MOF

4. Ni3(HITP)2MOF as supercapacitor electrode for EDLC :

5. Two electrode measurements

6. Electrochemical impedance (EIS) measurements

7. Device performance

8. Hybrid Co3O4C nanowires electrode for OER process

9. Synthesis of hybrid Co3O4C nanowires

10. Characterization of hybrid Co3O4C nanowires

11. Hybrid Co3O4C nanowires MOF electrode for oxygen evolution reaction

8

Metal-Organic-Framework Composites as Proficient Cathodes for Supercapacitor Applications

2. MOFs: Structure, properties and strategies for SCs

3. Single-metal MOFs

4. Bimetal or doped MOFs

5. Hybrids and composites

6. Flexible or freestanding SCs

Conclusion and Perspectives

9

Metal-Organic Frameworks and their Therapeutic Applications

2. Metal-organic frameworks

2.1 Usage areas of metal-organic frameworks

2.1.1 Controlled drug release

2.1.2 Antibacterial activity of MOFs

2.1.3 Biomedicine

2.1.4 Chemical sensors

Conclusions and recommendations

10

Significance of Metal Organic Frameworks Consisting of Porous Materials

1.1 Definition of porosity

2. Inferences obtained from the wide range of relevant research articles

2.1 Introduction to porous MOFs

2.2 Zeolites - an amorphous &amp

inorganic porous material

2.3 Activated carbon - an organic porous material

2.4 Formation of pores in MOFs

2.5 Types of pores.

2.6 Characterization of porous MOFs

2.7 Checking for permanent porosity

2.8 Advantages of MOF porous materials

2.9 Porous MOFs in separation of gases

2.10 Nanoporous MOFs

11

Metal Organic Frameworks (MOF's) for Biosensing and Bioimaging Applications

2. In vitro MOF complex sensors

2.1 DNA-RNA-MOF complex sensor

2.2 Enzyme-MOF complex

2.2.1 Enzymatic-MOF complex

2.2.2 Non-enzymatic-MOF complex

2.3 Fluorescent-MOF complex

3. In-vivo MOF complex sensors

3.1 MR complex

3.2 CT complex

12

Nanoscale Metal Organic Framework for Phototherapy of Cancer

2. Nanoscience and nanotechnology

2.1 Tumor ablation and nanotechnology in cancer treatment

3. Metal organic frameworks (MOFs)

4. Photothermal therapy (PTT)

5. Photodynamic therapy (PDT)

6. Historical development of phototherapy

7. Mechanism of phototherapy

7.1 Basic elements of photodynamic therapy

7.1.1 Singlet oxygen

7.1.2 Light sources

8. Photosensitizers (PSs)

8.1 First generation photosensitizers

8.2 Second generation photosensitizers

8.3 Third generation photosensitizers

8.4 Introduction of tumor cells and intracellular localization of photosensitizer

9. Cell death in phototherapy

10. nMOFs for PDT

11. nMOFs for PTT

11.1 Surface plasmon resonance (SPR) mechanism and plasmonic photothermal treatment (PPTT) method

11.1.1 Mie theory

11.1.2 Gold nanostructures

11.1.3 Photothermal properties of different gold nanostructures

11.1.4 Gold nanospheres used in photothermal therapy

11.1.5 Gold nanocages and nanorods used in photothermal therapy

11.1.6 Bioconjugation of gold nanostructures used in photothermal therapy

11.1.7 Determination of temperature changes in gold surface.

12. Results and Perspectives

back-matter

Keyword Index

About the Editors.

Notes:

Includes index.

Description based on print version record.

Description based on publisher supplied metadata and other sources.

ISBN:

9781644900437

1644900432

OCLC:

1124599342