Schiff base metal complexes : synthesis and applications / edited by Pranjit Barman and Anmol Singh.

Format:

Book

Contributor:

Barman, Pranjit, editor.

Singh, Anmol, editor.

Language:

English

Subjects (All):

Schiff bases.

Physical Description:

1 online resource (224 pages)

Place of Publication:

Weinheim, Germany : Wiley-VCH GmbH, [2023]

Summary:

Schiff Base Metal Complexes Schiff bases are compounds created from a condensed amino compounds, which frequently form complexes with metal ions. They have diverse applications in biology, catalysis, material science and industry. Understanding these compounds, their properties, and the available methods for synthesizing them is a key to unlocking industrial innovation. Schiff Base Metal Complexes provides a comprehensive overview of these compounds. It introduces the compounds and their properties before discussing their various synthesizing methods. A survey of existing and potential applications gives a complete picture and makes this a crucial guide for researchers and industry professionals looking to work with Schiff base complexes. Schiff Base Metal Complexes readers will also find: * A systematic and organized structure designed to make information instantly accessible * Detailed coverage of thermal synthesis, photochemical synthesis, and more * Challenges with different methods described in order to help readers make the correct choice for their own work Schiff Base Metal Complexes is a useful reference for organic chemists, materials scientists, and researchers or industry professionals working with organometallics.

Contents:

Cover

Title Page

Copyright

Contents

Preface

Part I Introduction

Chapter 1 Historical Background

1.1 Introduction

1.2 Theories of Coordinate Bond

1.2.1 Valence Bond Theory

1.2.2 Crystal Field Theory

1.2.3 Molecular Orbital Theory

1.2.4 Ligand Field Theory

References

Chapter 2 Classification

2.1 Ligands

2.2 Schiff Base

2.3 Types of Schiff Base

2.3.1 Salen‐type Ligands

2.3.2 Salophen‐type Ligands

2.3.3 Hydrazone‐type Ligands

2.3.4 Thiosemicarbazone/Carbazone‐type Ligands

2.3.5 Heterocyclic Schiff Bases

2.4 Different Bonding Modes of Schiff Bases

2.4.1 Monodentate

2.4.2 Bidentate

2.4.3 Tridentate

2.4.4 Tetradentate

2.4.5 Pentadentate

2.4.6 Hexadentate

Chapter 3 Different Routes of Synthesis

3.1 Formation of Schiff Bases

3.1.1 Direct Ligand Synthesis

3.1.2 Template Synthesis

3.1.3 Rearrangement of Heterocycles (Oxazoles, Thiazoles, etc.)

Chapter 4 Schiff Base Metal Complexes

Chapter 5 Effect of Different Parameters on Schiff Base and their Metal Complex

5.1 Ionic Charge

5.2 Ionic Size

5.3 Nature of Central Metal Ions

5.4 Nature of the Ligand

5.4.1 Basic Character of the Ligand

5.4.2 Size and Charge of the Ligand

5.4.3 Concentration of Ligand

5.4.4 Substitution Effect

5.4.5 Chelating Effect

5.4.6 Nature of Solvent

5.4.7 Crystal Field Effect

5.4.8 Thermodynamic and Kinetic Effect

Chapter 6 Thioether and Chiral Schiff Base

6.1 Thioether Schiff Base

6.2 Chiral Schiff Base

Part II Synthesis

Chapter 7 General Routes of Synthesis

7.1 Introduction

7.2 Mechanism of the Synthesis of Schiff Base Ligand

7.3 Problems Found in Conventional Method - Hydrolysis of C N Bond

References.

Chapter 8 Different Route of Synthesis of Schiff Base‐Metal Complexes

8.1 Introduction

8.2 Different Chemical Routes

8.2.1 Preparation of Schiff's Bases via Aerobic Oxidative Synthesis

8.2.2 Synthesis of Schiff Bases via Addition of Organometallic Reagents to Cyanides

8.2.3 Reaction of Phenol with Nitriles to Form SB

8.2.4 Reaction of Metal Amides to Ketone to Form SB

8.2.5 Reaction of Nitroso Compounds with Active Hydrogen Compounds

8.2.6 Dehydrogenation of Amines

8.2.7 Oxidation of Metal Amines to Form SB

8.2.8 Reduction of Carbon-Nitrogen Compounds

8.2.9 Synthesis of SB from Ketals

8.2.10 SB Synthesis by Using Hydrazoic Acid

8.2.11 SB Synthesis by Using Sodium Hypochlorite

8.2.12 Preparation of N‐metallo Imines

8.2.13 Preparation of N‐metallo Imines (Metal &amp

equals

B, Al, Si, Sn)

8.2.13.1 Preparation of N‐boryl and N‐aluminum Imines

8.2.13.2 Preparation of N‐silylimines via

8.2.13.3 Preparation of N‐tin Imines

8.3 Different Methods

8.3.1 Classical or Conventional Method

8.3.2 Microwave Irradiation Method

8.3.3 Water as Solvent Method

8.3.4 Grindstone Technique

8.3.5 Ultrasonic Method

8.3.6 Green Method Using Green Catalyst

Chapter 9 Synthesis and Mechanism of Schiff Base‐Metal Complexes

9.1 Introduction

9.2 Synthesis of Schiff Bases Metal Complexes

9.2.1 Synthesis of Ligand Followed by Complexation

9.2.2 One‐Step Process or Template Synthesis

9.3 Synthesis of Some of the Schiff Base Metal Complexes

Chapter 10 Synthesis and Mechanism of Chiral and Achiral Schiff Base and Their Metal Complexes

10.1 Introduction

10.2 Synthesis of Chiral and Achiral SB Ligand

10.3 Synthesis of Chiral SB Metal Complexes

10.4 Chiral Schiff Bases of Titanium, Zirconium, and Vanadium.

10.5 Chiral Schiff Bases of Main Group Metals

10.5.1 Manganese and Chromium Schiff Bases

10.5.2 Iron and Ruthenium Schiff Base Complexes

10.5.3 Cobalt, Nickel, Copper, and Zinc Schiff Base Complexes

10.5.4 Lanthanide Metal Schiff Bases

10.5.5 Silicon and Tin Metal Schiff Bases

Chapter 11 Synthesis and Mechanism of Thioether: Schiff Base and Their Metal Complexes

11.1 Introduction

11.2 Chemical Synthesis Procedures

11.2.1 Procedure for the Synthesis of Thioether‐Containing Schiff Base

Chapter 12 Computational Chemistry

12.1 Introduction

12.2 Application of DFT in the Field of Schiff Base and Their Metal Complexes

Part III Application

Chapter 13 General Applications of Schiff Bases and Their Metal Complexes

13.1 Catalyst

13.2 Biological and Medicinal Importance

13.2.1 Antibacterial Activity

13.2.2 Anticancer and Anti‐inflammatory Agent

13.2.3 Antifungal Activity

13.2.4 As a Drug in a Number of Diseases

13.3 Coatings

13.4 Analytical Chemistry

13.5 Dyes

13.6 Semi‐conducting Materials

13.7 Solar System

13.8 Photocatalyst

13.9 Polymer Chemistry

13.10 Agrochemical Industry

Chapter 14 Application in Pharmacological Field

14.1 Introduction

14.2 Antimicrobial Activity

14.2.1 Schiff Bases Against Gram‐Positive Bacteria

14.2.2 Schiff Bases Against Gram‐Negative Bacteria

14.3 Antifungal Activity of Schiff Bases

14.4 Anticancer Activity of Schiff Bases and Their Metal Complexes

14.4.1 In Vitro Activity

14.4.2 In Vivo Activity

14.5 Antidyslipidemic and Antioxidant Activity

14.6 Anthelmintic Activity

14.7 Antitubercular Activity

14.8 Antidepressant Activity

14.9 Anticonvulsant Activity

14.10 Antioxidant Activity

14.11 Antiviral Activity.

14.12 Anti‐inflammatory and Analgesic Activities

Chapter 15 Application as Catalyst

15.1 Introduction

15.2 Coupling Reaction

15.3 Polymerization Reaction

15.4 Oxidation Reaction

15.5 Epoxidation Reaction

15.6 Ring‐Opening Epoxidation Reaction

15.7 Cyclopropanation Reaction

15.8 Hydrosilylation Reaction

15.9 Hydrogenation Reaction

15.10 Aldol Reaction

15.11 Michael Addition Reaction

15.12 Annulation Reaction

15.13 Diels-Alder Reaction

15.14 Click Reaction

15.15 Mannich Reaction

15.16 Ene Reaction

15.17 Summary

Chapter 16 Application as Drug‐Delivery System

Chapter 17 Chemosensors/Bioimaging Applications

17.1 Introduction

17.1.1 Chemosensing

17.1.1.1 Explosives Sensing

17.1.1.2 Oxygen Sensing

17.1.1.3 High pH Sensing

17.1.1.4 Other Porphyrinoid‐based Chemosensors and Chemodosimeters

17.1.1.5 Metal Sensing

17.2 Chemosensors

17.2.1 Fluorescence ON‐OFF

17.2.1.1 Tiny Molecules Chemosensors

17.2.1.2 Supramolecular Chemosensors

17.2.1.3 QDs‐based Chemosensors

17.2.1.4 Fluorescent Nanomaterial‐based Chemosensors

17.2.2 OFF‐ON Chemosensors

17.2.2.1 Rhodamine‐based Sensors

17.2.2.2 Coumarin‐based Sensors

17.2.2.3 BODIPY‐based Sensors

17.2.3 Ratiometric Fluorescent Chemosensors

17.2.3.1 Pyrene‐based Chemosensors

17.2.3.2 Fluorophore Hybridization Chemosensors

17.2.3.3 Dual‐emission Fluorescent Nanoparticles

17.2.4 Rhodamine‐based Sensors

17.2.4.1 Fluorescent Bioimaging of CK in HeLa cells

17.2.4.2 Mice Bioimaging Experiments

17.2.5 Fluorescent Chemosensor for AcO− Detection

17.2.6 CN− and Al3+ Chemosensor for Bioimaging

17.3 Conclusion

Chapter 18 Application in Industrial Field

18.1 Introduction

18.2 Current Status in India

18.3 Conclusion

Index

EULA.

Notes:

Description based on print version record.

Includes bibliographical references and index.

Other Format:

Print version: Barman, Pranjit Schiff Base Metal Complexes

ISBN:

9783527839476

352783947X

9783527839452

3527839453

OCLC:

1379475524