Asymmetric functionalization of C-H bonds / edited by Shu-Li You.

Format:

Book

Author/Creator:

Shu-Li You

Contributor:

You, Shu-Li, editor.

Series:

RSC catalysis series ; 25.

RSC Catalysis Series, 1757-6725 ; 25

Language:

English

Subjects (All):

Carbon compounds.

Hydrogen bonding.

Catalysis.

Physical Description:

1 online resource (431 p.)

Place of Publication:

Cambridge, England : Royal Society of Chemistry, 2015.

Language Note:

English

Summary:

Written by a leading expert, this book provides the first comprehensive review of the rapidly developing field of asymmetric C-H direct functionalization reactions.

Contents:

Cover ; Asymmetric Functionalization of C-H Bonds ; Foreword; Preface; Contents; Chapter 1 - Asymmetric CeH Bond Insertion Reactions; 1.1 C- H Bond Insertion by Metal Carbenoids ; 1.1.1 Introduction; 1.1.2 C-H Bond Insertion by Rh Carbenoids ; 1.1.2.1 Insertion into Unactivated C(sp3)-H Bonds ; 1.1.2.2 Insertion into Allylic C(sp3)-H Bonds; 1.1.2.3 Insertion into Benzylic C(sp3)-H Bonds ; 1.1.2.4 Insertion into C(sp3)-H Bonds α to a Heteroatom ; 1.1.2.5 Insertion into C(sp2)-H Bonds ; 1.1.2.6 Rh-Catalyzed Combined C-H Bond Functionalization/Cope Rearrangement

1.1.3 C-H Bond Insertion by Cu Carbenoids 1.1.4 C-H Bond Insertion by Ir Carbenoids ; 1.1.5 C-H Bond Insertion by Ru Carbenoids ; 1.1.6 C-H Bond Insertion by Fe Carbenoids ; 1.1.7 Lewis Acid Catalyzed C-H Bond Insertion by Carbenoids ; 1.2 C-H Bond Insertion by Metal Nitrenoids ; 1.2.1 Introduction; 1.2.2 Rh-Catalyzed Reactions; 1.2.3 Mn- and Ru-Catalyzed Reactions; 1.2.4 Cu-Catalyzed Reactions; 1.2.5 Ir-Catalyzed Reactions; 1.2.6 Enzyme-Catalyzed Reactions; 1.3 C-H Bond Insertion by Metal Oxo Species ; 1.3.1 Introduction; 1.3.2 Fe-Catalyzed Reactions; 1.3.3 Mn-Catalyzed Reactions

1.3.4 Ru-Catalyzed Reactions1.4 Conclusion and Perspectives; References; Chapter 2 - Asymmetric Cross-Dehydrogenative Coupling (CDC) Reactions; 2.1 Introduction; 2.2 Asymmetric CDC Reactions of C(sp3)-H Bonds Adjacent to Nitrogen ; 2.3 Asymmetric CDC Reactions of Ethers; 2.4 Asymmetric CDC Reactions of Aldehydes via Organo-SOMO Catalysis; 2.5 Asymmetric CDC Reaction of Benzylic C-H Bonds ; 2.6 Asymmetric CDC Reactions between C(sp2)-H Bond and C(sp3)-H Bond ; 2.7 Conclusion and Outlook; References; Chapter 3 - Asymmetric Oxidative Biaryl Coupling Reactions; 3.1 Introduction

3.2 Early Contributions3.3 Cu-Catalyzed Reactions; 3.4 V-Catalyzed Reactions; 3.5 Other Transition Metal-Catalyzed Reactions; 3.6 Organocatalytic Reactions; 3.7 Application in the Synthesis of Chiral Conjugate Oligomers and Polymers; 3.8 Application in the Synthesis of Natural Products; 3.9 Summary and Perspectives; References; Chapter 4 - Asymmetric [1,5]-Hydride Transfer Reactions; 4.1 Introduction; 4.2 Asymmetric [1,5]-Hydride Transfer Catalyzed by Lewis Acid; 4.3 Asymmetric [1,5]-Hydride Transfer Catalyzed by Organocatalyst

4.4 Asymmetric [1,5]-Hydride Transfer Catalyzed by a Binary Catalytic System4.5 Summary and Outlook; References; Chapter 5 - Asymmetric Functionalization of C-H Bonds via a Transient Carbon-Metal (C-M) Species ; 5.1 Introduction; 5.2 Pd-Catalyzed Reaction; 5.2.1 Mechanistic Consideration; 5.2.2 Pd-Catalyzed Diastereoselective C-H Bond Functionalization Reactions by Chiral Auxiliaries ; 5.2.3 Pd-Catalyzed Enantioselective C-H Bond Functionalization Reactions ; 5.2.3.1 PdII/Pd0 Catalytic Cycle; 5.2.3.2 PdII/PdIV Catalytic Cycle; 5.2.3.3 Pd0/PdII Catalytic Cycle; 5.3 Rh-Catalyzed Reactions

5.3.1 Mechanistic Considerations

Notes:

Description based upon print version of record.

Includes bibliographical references at the end of each chapters and index.

Description based on online resource; title from PDF title page (ebrary, viewed December 9, 2015).

ISBN:

9781782621966

1782621962