Pillararenes / edited by Tomoki Ogoshi.

Format:

Book

Author/Creator:

Tomoki Ogoshi

Contributor:

Ogoshi, Tomoki, editor.

Royal Society of Chemistry (Great Britain), issuing body.

Series:

Monographs in supramolecular chemistry ; 18.

Monographs in Supramolecular Chemistry, 1368-8642 ; 18

Language:

English

Subjects (All):

Macrocyclic compounds.

Supramolecular chemistry.

Physical Description:

1 online resource (331 p.)

Place of Publication:

Cambridge, England : Royal Society of Chemistry, 2016.

Language Note:

English

Summary:

First reported in 2008, Pillararenes are a new class of macrocyclic hosts consisting of hydroquinone units linked at the para -position. With a composition similar to cucurbiturils and calixarenes, they combine the advantages and aspects of traditional hosts and have applications in sensing, material synthesis and biomedicine. Pillararenes starts with the historical background of macrocyclic compounds and then following chapters cover the synthesis of pillararenes, their structures, conformations and planar chirality. Dedicated chapters then cover their host-guest properties and supramolecular assemblies based on pillararenes including supramolecular polymers and mechanically interlocked molecules. Edited by the leader in the field, this is the first book to cover pillararenes and will appeal to graduate students, researchers and academics in supramolecular chemistry, organic chemistry, polymer chemistry and materials science interested in the chemistry and applications of pillararenes.

Contents:

Cover; Contents; Preface; Chapter 1 Historical Background of Macrocyclic Compounds; 1.1 Introduction; 1.2 Cyclodextrins; 1.3 Crown Ethers and Their Derivatives; 1.4 Calix[n]arenes and Their Derivatives; 1.5 Cucurbit[n]urils CB[n] and Their Derivatives; 1.6 Other Synthetic Macrocyclic Compounds; 1.7 Conclusion and Outlook; References; Chapter 2 Synthesis of Pillar[n]arenes; 2.1 Introduction; 2.2 Synthesis of Pillar[5] arenes; 2.2.1 Synthesis of Pillar[5]arene from 1,4-Dimethoxybenzene as a Monomer; 2.2.2 Synthesis of Pillar[5]arenes from 1,4-Dialkoxybenzene Monomers

2.2.3 Mechanism of the Formation of Pillar[5]arenes - Thermodynamic Control2.3 Synthesis of Pillar[6]arenes under Kinetic and Thermodynamic Control; 2.4 Synthesis of Larger Pillar[n]arene Homologs under Kinetic Control; 2.5 Conclusion and Outlook; References; Chapter 3 Functionalization of Pillararenes; 3.1 Introduction; 3.2 Per-functionalization of Pillar[n]arenes by Pre-formed Pillar[n]arenes; 3.3 Per-functionalization of Pillar[n]arenes by Cyclization of Dialkoxybenzene Derivatives with Reactive Moieties; 3.4 Mono-functionalization of Pillar[5]- and Pillar[6]arenes

3.5 Di-functionalized Pillar[5]- and Pillar[6]arenes3.6 Functionalized Pillar[5] arenes with More Than Three Diifferent Substituents; 3.7 Conclusion and Outlook; References; Chapter 4 Conformation and Planar Chirality of Pillar[n]arenes; 4.1 Introduction; 4.2 Conformation of Pillar[5]arenes; 4.2.1 Conformation of Pillar[5]arenes with Simple Alkyl Substituents; 4.2.2 Conformation of Pillar[5]arenes with One p-Conjugated Unit; 4.2.3 Conformation of Hydroxylated Pillar[5]arenes; 4.2.4 Conformation of Non-symmetrical Pillar[5]arenes; 4.3 Conformations of Pillar[6]arenes

4.3.1 Conformation of Symmetrical Per-alkylated Pillar[6]arenes4.3.2 Conformation of Per-hydroxylated Pillar[6]arene; 4.4 Conclusion and Outlook; References; Chapter 5 Host-Guest Properties of Pillar[n]arenes; 5.1 Introduction; 5.2 X-ray Crystal Structure and Electron Potential Profiles of Pillar[n]arenes; 5.3 Host-Guest Properties of Pillar[5]arenes; 5.3.1 per-Hydroxylated Pillar[5]arene; 5.3.2 per-Alkylated Pillar[5]arenes; 5.3.3 Water-soluble Pillar[5]arenes; 5.3.4 Functionalized Pillar[5]arenes; 5.4 Host-Guest Properties of Pillar[6]arenes; 5.4.1 per-Hydroxylated Pillar[6]arene

5.4.2 per-Alkylated Pillar[6]arenes5.4.3 Water-soluble Pillar[6]arenes; 5.4.4 Functionalized Pillar[6]arenes; 5.5 Host-Guest Properties of LargerPillar[n]arene Homologs (n = 7-14); 5.6 Summary and Outlook; References; Chapter 6 Assembled Structures of Pillar[n]arenes; 6.1 Introduction; 6.2 Assembled Structures of Pillar[5]arenes in Crystal States; 6.2.1 per-Alkylated Pillar[5]arenes; 6.2.2 per-Functionalized Pillar[5]arenes; 6.2.3 A1/A2 Pillar[5]arenes; 6.2.4 Pillar[5]arenes with Two and Three Benzoquinone Units; 6.2.5 Non-symmetrical Pillar[5]arenes

6.2.6 Host-Guest Complexes between Pillar[5]arenes and Guests

Notes:

Description based upon print version of record.

Includes bibliographical references at the end of each chapters and index.

Description based on online resource; title from PDF title page (ebrary, viewed December 10, 2015).

ISBN:

9781782622321

1782622322