Sustainable catalysis, without metals or other endangered elements. Part 2 / edited by Michael North, Green Chemistry Centre of Excellence, University of York, York, UK.

Format:

Book

Author/Creator:

Michael North

Contributor:

North, Michael, editor.

Series:

RSC green chemistry series ; 41.

RSC Green Chemistry, 1757-7039 ; 41

Language:

English

Subjects (All):

Catalysis.

Physical Description:

1 online resource (473 p.)

Place of Publication:

Cambridge, England : Royal Society of Chemistry, 2016.

Language Note:

English

Summary:

Focussing on catalysis without metals or other endangered elements, this book is an important reference for researchers working in catalysis and green chemistry.

Contents:

Cover; Contents; Preface; References; Part 2; Chapter 14 Nonquaternised Cinchona Alkaloid Derivatives as Asymmetric Organocatalysts for Carbon-Carbon Bond-forming Reactions ; 14.1 Introduction; 14.2 Catalytic Asymmetric 1,4-Addition Reactions; 14.3 Catalytic Asymmetric 1,2-Addition Reactions; 14.4 Catalytic Asymmetric Cycloaddition Reactions; 14.5 Concluding Remarks; References; Chapter 15 Nonquaternised Cinchona Alkaloid Derivatives as Asymmetric Organocatalysts for Carbon-Heteroatom Bond-forming Reactions ; 15.1 Introduction; 15.2 Hydrophosphonylation; 15.3 Epoxidation and Hydroperoxidation

15.4 Aziridination15.5 Lactone and Lactam Formation; 15.6 Epoxide and Aziridine Ring Opening; 15.7 Anhydride Ring Opening; 15.8 Amination; 15.8.1 Amination by Substitution; 15.8.2 Aza-Michael Addition; 15.9 Hydroxylation; 15.9.1 Carbonyl α-Hydroxylation ; 15.9.2 Oxa-Michael Addition; 15.10 Sulfenylation; 15.10.1 α-Sulfenylation ; 15.10.2 Sulfa-Michael Addition; 15.11 Halogenation; References; Chapter 16 Cinchona Alkaloid Derivatives as Asymmetric Phase-transfer Catalysts ; 16.1 N-Quaternised Cinchona Alkaloid Ammonium Salts; 16.2 Asymmetric Phase-transfer Catalysis (PTC)

16.2.1 Monoalkylation of Schiff Bases Derived from Glycine16.2.2 Dialkylation of Schiff Bases Derived from Glycine; 16.2.3 Other Alkylations with Cinchona-derived PTC Catalysts; 16.2.4 Conjugate Additions with Cinchona-derived PTC Catalysts; 16.2.5 Aldol Reactions with Cinchona-derived PTC Catalysts; 16.2.6 Mannich Reactions with Cinchona-derived PTC Catalysts; 16.2.7 Darzens Reaction with Cinchona-derived PTC Catalysts; 16.2.8 Epoxidation of Enones with Cinchona-derived PTC Catalysts; 16.2.9 Other Reactions with Cinchona-derived PTC Catalysts; 16.3 Conclusions; References

Chapter 17 Binaphthyl-derived Cyclic Amines and Their Salts as Asymmetric Organocatalysts 17.1 Introduction; 17.2 Design of Chiral Amine Catalysts; 17.2.1 Aldol Reactions; 17.2.2 Mannich Reactions; 17.2.3 Conjugate Additions; 17.2.4 C-O and C-N Bond Formations; 17.2.5 Halogenations; 17.3 Design of Chiral Phase-transfer Catalysts; 17.3.1 Alkylations; 17.3.2 Conjugate Additions; 17.3.3 Aldol and Mannich Reactions; 17.3.4 Strecker Reactions; 17.3.5 Oxidations; 17.4 Conclusions; References; Chapter 18 Imidazolidinones as Asymmetric Organocatalysts ; 18.1 Introduction

18.1.1 Enamine Catalysis: Nucleophilicity of Imidazolidinone-derived Enamines: The Aldol Reaction18.1.2 Alkylation Reactions with Imidazolidinone Enamines; 18.2 α-Addition of Heteroatoms Catalysed by Imidazolidinone Organocatalysts ; 18.3 Iminium Activation with Imidazolidinones Organocatalysts; 18.3.1 Diels-Alder and [2+3] Dipolar-type Reactions with Imidazolidinone Catalysts; 18.3.2 Friedel-Crafts-type Reactions: Pyrroles, Indoles and N,N Dialkyl-substituted Anilines; 18.3.3 Mukaiyama-Michael Reaction Promoted by Imidazolidinone Organocatalysts

18.3.4 Enantioselective Organocatalytic Hydride Reduction

Notes:

Description based upon print version of record.

Includes bibliographical references at the end of each chapters and index.

Description based on online resource; title from PDF title page (ebrary, viewed December 11, 2015).

ISBN:

9781523102006

1523102004

9781782626435

1782626433