Organophosphorus chemistry. Volume 45, A review of the literature published between January 2014 and January 2015 / editors, D.W. Allen, Sheffield Hallam University, Sheffield, UK, J.C. Tebby, Staffordshire University, Stoke-on-Trent, UK, D. Loakes, Laboratory of Molecular Biology, Cambridge, UK ; authors, Piotr Bałczewski, Polish Academy of Sciences, Łódź, Poland and Jan Długosz University in Częstochowa, Poland [and fifteen others].

Format:

Book

Author/Creator:

David W Allen

Bałczewski, Piotr, author.

Contributor:

Allen, D. W., editor.

Tebby, J. C., editor.

Loakes, D., editor.

Series:

Specialist periodical report.

A specialist periodical report, 0306-0713

Language:

English

Subjects (All):

Organophosphorus compounds.

Physical Description:

1 online resource (504 p.)

Other Title:

Review of the literature published between January 2014 and January 2015

Place of Publication:

Cambridge, UK : Royal Society of Chemistry, [2016]

Summary:

Coverage in this annual review of the literature presents a comprehensive and critical survey of the vast field of study involving organophosphorus compounds including a special chapter on the recent developments in green synthetic approaches in organophosphorus chemistry to reflect the current interests in the area.

Contents:

Cover; Contents; Preface; Phosphines and related C-P bonded compounds; 1 Introduction; 2 Phosphines; 2.1 Preparation; 2.1.1 From halogenophosphines and organometallic reagents; 2.1.2 From metallated phosphines; 2.1.3 By the addition of P-H to unsaturated compounds; 2.1.4 By the reduction of phosphine oxides and related compounds; 2.1.5 Miscellaneous methods of preparing phosphines; 2.2 Reactions; 2.2.1 Nucleophilic attack at carbon; 2.2.2 Nucleophilic attack at halogen; 2.2.3 Nucleophilic attack at other atoms; 2.2.4 Miscellaneous reactions; 3 pπ-Bonded phosphorus compounds

4 Phosphirenes, phospholes and phosphininesReferences; Tervalent phosphorus acid derivatives; 1 Introduction; 2 Halogenophosphorus compounds; 3 Tervalent phosphorus amides; 3.1 Aminophosphines; 3.2 Phosphoramidites; 3.3 Phosphorodiamidites; 4 Tervalent phosphorus esters; 4.1 Phosphonites; 4.2 Phosphinites; 4.3 Phosphites; 4.4 Mixed ligands; References; Phosphine chalcogenides; References; Phosphonium salts and P-ylides; 1 Introduction; 2 Phosphonium salts; 2.1 Synthesis and characterisation; 2.2 Applications in synthesis; 2.3 Medical and biological applications; 2.4 Miscellaneous applications

3 Phosphonium-based ionic liquids (PILs)3.1 Preparation and characterisation; 3.2 Applications in synthesis; 3.3 Extraction and separation technologies based on PILs; 3.4 Electrochemical applications; 3.5 Miscellaneous applications; 4 P-ylides (phosphoranes); 4.1 Preparation, structural properties and mechanistic investigations; 4.2 Applications in synthesis; 4.3 Coordination chemistry; References; Nucleotides and nucleic acids: mononucleotides; 1 Introduction; 2 Nucleoside mono-, di- and triphosphates; 2.1 Synthesis; 2.2 Biochemical findings; 3 Nucleoside phosphonates; 4 Nucleotide prodrugs

4.1 Phosphoramidate prodrugs bearing an amino acid ester residue4.2 Other phosphoramidate and non-amidate prodrugs; 5 Analogues of mRNA caps; 6 Fluorescently labelled probes; References; Quinquevalent phosphorus acids; 1 Introduction; 2 Phosphoric acids and their derivatives; 2.1 Synthesis of phosphoric acids and their derivatives; 2.2 Reactions of phosphoric acids and their derivatives; 2.3 Biological application of phosphoric acids and their derivatives; 2.4 Miscellaneous applications; 2.5 Phosphoric acids and their derivatives as catalysts; 2.5.1 Spirodicycloalkylphenyl derivatives

2.5.2 Binaphthyl and (1,2,3,4-tetrahydronaphthyl) derivatives2.5.2.1 Bi(1,2,3,4-tetrahydronaphthyl) derivatives; 2.5.2.2 Binaphthyl derivatives; 3 Phosphonic acids and their derivatives; 3.1 Synthesis of phosphonic acids and their derivatives; 3.2 Reaction of phosphonic acids and their derivatives; 3.3 Biological application of phosphonic acids and their derivatives; 3.4 Miscellaneous applications; 4 Phosphinic acids and their derivatives; 4.1 Synthesis of phosphinic acids and their derivatives; 4.2 Reactions of phosphinic acids and their derivatives

4.3 Biological applications of phosphinic acids and their derivatives

Notes:

Description based upon print version of record.

Includes bibliographical references.

Description based on online resource; title from PDF title page (ebrary, viewed April 12, 2016).

ISBN:

9781782626930

178262693X