Chalcogen Chemistry : Fundamentals and Applications / edited by Vito Lippolis [and three others].

Format:

Book

Author/Creator:

Vito Lippolis

Contributor:

Lippolis, Vito, editor.

Language:

English

Subjects (All):

Chemistry, Inorganic.

Physical Description:

1 online resource (752 pages)

Edition:

First edition.

Place of Publication:

London, England : The Royal Society of Chemistry, [2023]

Summary:

Covering organic and inorganic synthesis, structural properties, coordination chemistry and computational modelling, all key classes of chalcogen compounds are illustrated.

Contents:

Intro

Copyright

p5_230206

p9_230206

Contents: Contents

Chapter 1: Carbonyl Chalcogenide Cluster-based Polymers

1.1 Introduction

1.2 Group 6 Carbonyl Chalcogenide Coordination Polymers

1.3 Group 7 Carbonyl Chalcogenide Coordination Polymers

1.3.1 Te-Mn Cluster-based Carbonyl Polymers

1.3.2 S-Re Rectangular Carbonyl Polymers

1.4 Group 8 Metal Carbonyl Chalcogenide Coordination Polymers

1.4.1 S-Fe Cluster-based Carbonyl Polymers

1.4.2 EFe3 &amp

lpar

E=Te, Se, S&amp

rpar

Cluster-based Carbonyl Polymers

1.4.3 Mixed Group 15 and 16 Fe Carbonyl Supramolecules

1.4.4 Ru Telluride Carbonyl Polymer

1.5 Potential Applications

1.5.1 Semiconducting Behaviors

1.5.2 Photodegradation

1.5.3 Magnetic Properties

1.5.4 Catalysis

1.5.5 Adsorption/Desorption Properties

1.6 Concluding Remarks

Acknowledgments

References

Chapter 2: Chalcogenocarbonyl and Chalcogenonitrosyl Metal Complexes

2.1 Introduction

2.2 Chalcogenocarbonyl &amp

CE&amp

Complexes

2.3 New Thiocarbonyl &amp

CS&amp

Complexes Reported after 2008

2.4 Selenocarbonyl &amp

CSe&amp

2.4.1 Complexes Featuring Terminal Coordinated CSe

2.4.1.1 Synthesis

2.4.1.2 Reactions of Complexes Featuring Terminal Coordinated CSe

2.4.1.3 List of Complexes Featuring Terminal Coordinated CSe and Characterized by X-ray Diffraction Studies

2.4.2 Complexes Featuring Bridging Coordinated CSe

2.4.2.1 Complexes Featuring Symmetric Bridging CSe

_s_h_o_w_33_.

Outline placeholder

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2.4.2.2 Complexes Featuring End-on/Side-on Bridging CSe

2.4.2.3 Complexes Featuring Bridging End-on/End-on CSe

2.4.2.4 Complexes Featuring Bridging ç3- and ç4-CSe

_s_h_o_w_37_

2.4.2.5 List of Complexes Featuring Bridging CSe

2.5 Tellurocarbonyl &amp

CTe&amp

2.5.1 Complexes Featuring Terminal Coordinated CTe

2.5.1.1 Synthesis

2.5.1.2 Reactions of Complexes Featuring Terminal Coordinated CTe

2.5.2 Complexes Featuring Bridging Coordinated CTe

2.5.3 List of all CTe Complexes

2.6 Comparison of a Series of CE &amp

E=O, S, Se, Te&amp

2.7 Chalcogenonitrosyl &amp

NE&amp

_s_h_o_w_42_

_s_h_o_w_44_

2.8 Thionitrosyl &amp

NS&amp

2.8.1 Synthesis

2.8.2 Reactions

2.8.3 List of NS Complexes Characterized by an X-ray Diffraction Study

2.9 Selenonitrosyl &amp

NSe&amp

2.9.1 Synthesis

_s_h_o_w_49_

2.9.2 Reactivity

2.9.3 List of NSe Complexes Characterized by an X-ray Diffraction Study

2.10 Telluronitrosyl &amp

NTe&amp

2.11 Comparison of Chalcogenonitrosyl &amp

NE

E=O, S, Se&amp

Chapter 3: Metal-Chalcogenolates: Synthesis and Applications in Material Chemistry

3.1 Introduction

3.2 Synthesis of Chalcogenolate Complexes

3.2.1 Reactions Involving Chalcogen Insertion into the Metal-Carbon Bond

3.2.2 Oxidative Addition Reactions of Diorganodichalcogenides.

3.2.2 Oxidative Addition Reactions of Diorganodichalcogenides

3.2.3 Reactions with Nucleophilic Organochalcogenolate Reagents

3.2.4 Chalcogenolysis/Protonolysis Reactions

3.3 Structural Aspects of Metal Chalcogenolates

3.4 Applications of Metal Chalcogenolates to Materials Chemistry

3.4.1 Precursors for Main Group Metal Chalcogenides

3.4.1.1 Group 13 Chalcogenides

3.4.1.2 Group 14 Chalcogenides

3.4.1.3 Group 15 Chalcogenides

3.4.2 Precursors for Transition Metal Chalcogenides

3.4.2.1 Precursors for Group 12 Chalcogenide Materials

3.4.3 Precursors for Lanthanide Chalcogenides

3.4.4 Precursors for Ternary Chalcogenide Materials

Chapter 4: Chalcogenones and Pincer Ligands: Coordination Chemistry and Interaction with Transition and Heavy Main Group Elements

4.1 Introduction

4.2 Symmetric Pincer Ligands of Type &amp

lsqb

&amp

E&amp

z.dbd6

Z&amp

/X/&amp

rsqb

-5,5

4.2.1 Anionic Ligands

4.2.2 Neutral Ligands

4.3 Symmetric Pincer Ligands of Type &amp

S&amp

-6,6

4.3.1 Anionic Ligands

4.3.2 Neutral Ligands

4.4 Applications

4.4.1 Catalysis

4.4.2 Luminescence

4.4.3 Biological Activity

4.5 Concluding Remarks

Chapter 5: Chalcogen Heterocycles Containing Main Group Elements: Synthesis and Reactivity

5.1 Introduction

5.2 Group 13 Chalcogen Heterocycles

5.3 Group 14 Chalcogen Heterocycles

5.4 Group 15 Chalcogen Heterocycles

Chapter 6: Chalcogen-containing and Chalcogen-functionalized Heterocycles

6.1 Introduction.

6.2 Chalcogen-containing Heterocycles

6.3 Chalcogen-functionalized Heterocycles

Chapter 7: Chalcogen-Nitrogen Heterocyclic Radicals

7.1 Introduction

7.2 1,2,3-Benzodichalcogenazolyls

7.3 1,3,2-Benzodichalcogenazolyls

7.4 2,1,3-Benzochalcogenadiazolidyls

7.5 1,2,3-Benzodichalcogenazolidyls

7.6 Conclusions

Chapter 8: Synthesis and Applications of Organophosphorus Compounds with a P&amp

z.dbd

Se Group

8.1 Introduction

8.2 Reaction of Secondary Phosphine Selenides

8.3 2,4-Bis&amp

phenyl&amp

-1,3-diselenadiphosphetane-2,4-diselenide &amp

WoollinsÇ Reagent&amp

8.4 P&amp

Se Compounds as a Lewis Base Catalyst

8.5 P&amp

Se Compounds with a Binaphthyl Group

8.6 Conclusions

Chapter 9: Optically Active Derivatives with a Stereogenic Sulfur Center: Synthesis and Applications

9.1 Introduction

9.2 Optical Activity of Organosulfur Derivatives - Historical Overview

9.2.1 Sulfoxides

9.2.2 Sulfimides

9.2.3 Sulfonium Ylides

9.2.4 Sulfinic Esters

9.2.5 Sulfoximines

Chapter 10: Chiral Selenium and Tellurium-containing Derivatives: Synthesis and Applications

10.1 Introduction

10.2 Chiral Organoselenium Derivatives

10.2.1 Chiral Electrophilic Organoselenium Reagents

10.2.2 Chiral Nucleophilic Organoselenium Reagents

10.2.3 Chiral Selenide-based Reagents

10.2.4 Chiral Organoselenium Catalysts

10.3 Chiral Organotellurium Derivatives

10.4 Conclusions

Chapter 11: Electrophilic Chalcogen-containing Reagents

11.1 Introduction

11.2 Electrophilic Chalcogen Species

11.2.1 Halogenated Electrophilic Chalcogen Species

11.2.1.1 Monovalent Halogen Source

11.2.1.1.1 Fluorine-containing Species.

11.2.1.1.2 Bromine-containing Species

11.2.1.1.3 Iodine-containing Species

11.2.1.2 Selenium Dihalide

11.2.1.3 Hypervalent Iodine Source

11.2.1.4 N-Chalcogeno-amides

11.2.2 Lewis Acids Containing Electrophilic Sources

11.2.3 Miscellaneous Sources

11.2.3.1 Organoseleninic Acid &amp

RSeO2H&amp

11.2.3.2 Organosulfenic Acid &amp

RSOH&amp

11.2.3.3 Thiosulfonates &amp

RSSO2R&amp

11.3 Conclusions and Perspectives

Chapter 12: Nucleophilic Chalcogen-containing Reagents

12.1 Introduction

12.2 Nucleophilic Species Containing the Chalcogen-Boron Bond

12.3 Nucleophilic Species Containing the Chalcogen-Aluminium Bond

12.4 Nucleophilic Species Containing the Chalcogen-Silicon Bond

12.4.1 Reaction with Acetates and Ethers

12.4.2 Reaction with Acyl Chlorides

12.4.3 Palladium-promoted Carbothiolations

12.4.4 Ring-opening of Heterocycles by Chalcogenosilanes

12.4.5 Nucleophilic Substitution on Halogenated Compounds

12.4.6 Aromatic Nucleophilic Substitution with Organothiosilanes

12.4.7 Reaction with Carbonyl-containing Compounds

12.4.8 Reaction with Allenes and Alkynes

12.5 Species Containing the Chalcogen-Tin Bond

12.5.1 Stannyl Sulfides and Selenides in Stille-like and Related Metal-catalyzed Cross-coupling Reactions

12.5.2 Other Nucleophilic Processes Involving Stannyl Sulfides and Selenides

Chapter 13: The Chemistry of Selenium-catalyzed Redox Processes

13.1 Introduction

13.2 Oxidative Additions and Cyclizations of Alkenes

13.2.1 Oxidative Halogenations.

13.2.2 Oxidative Additions and Cyclizations Mediated by Electrophilic Fluorinating Agents.

Notes:

Includes bibliographical references.

Description based on publisher supplied metadata and other sources.

Description based on print version record.

Other Format:

Print version: Lippolis, Vito Chalcogen Chemistry

ISBN:

1-83916-739-4

1-83916-738-6