Compendium of Terminology in Analytical Chemistry / edited by D. Brynn Hibbert.

Format:

Book

Author/Creator:

D Brynn Hibbert

Contributor:

Hibbert, D. B. (D. Brynn), 1951- editor.

Language:

English

Subjects (All):

Analytical chemistry.

Physical Description:

1 online resource (xxiv, 666 pages) : illustrations

Edition:

Fourth edition.

Place of Publication:

London, England : The Royal Society of Chemistry, [2023]

Summary:

How do you describe an analytical method, measure the purity of the new chemical that you have just synthesized, or report the proper units of measurement? For analytical chemists, the principal tool of the trade, or source of terms, is this book - the so-called Orange Book. First published in 1978, this latest edition takes into account the explosion of new analytical procedures and, at the same time, the diversity of techniques and the quality and performance characteristics of the procedures that are the focus of interest. The scope of analytical chemistry has widened, new types of instrumental techniques have emerged and automation has taken over. Answers can now be shared, not only on the chemical composition and structure of the sample, but also changes in composition and structure in space and time. New chapters on chemometrics, bio-analytical methods of analysis, and sample treatment and preparation have been added. The terminology of metrology and quality assurance is now up to date with the latest ISO and JCGM standards. This new volume will be an indispensable reference resource for the coming decade, revising and updating accepted terminology, and providing the official language of analytical chemistry.

Contents:

Cover

Preface

1. History

2. Aims of the Orange Book

3. Structure of the Orange Book

4. Conventions and Layout

4.1 Principles of a Vocabulary

4.1.1 Generic Principles

4.1.2 Specific Principles

4.2 Constructing a Terminology Entry in IUPAC Publications

4.3 Presentation of Quantities and Their Values

4.4 Quotation Marks

5. Referencing and Cross Referencing

6. Primitive terms not Defined

Acknowledgments

References

Contents

Chapter 1 Fundamental and Metrological Concepts in Analytical Chemistry

1.1 Introduction

1.2 Definitions of Analytical Chemistry

1.3 Concepts used in Laboratory Practice

1.4 Concepts Related to Properties, Quantities And Units

1.5 Concepts on Measurement and Examination

1.6 Concepts Related to Measurement Error and Measurement Uncertainty

1.7 Concepts Related to Calibration

1.8 Terms, Symbols, Definitions and SI Units of Quantities and Constants

1.8.1 Quantities Answering the Question ''How Much Material?''

1.8.2 Quantities Describing the Composition of a Material

1.8.3 Examples of Quantities Applied in Various Subdisciplines of Analytical Chemistry

1.8.4 Adjectives Modifying Quantity Terms

1.8.5 Defining Constants of the International System of Units

1.8.6 SI-Derived Units with Special Terms and Symbols

1.9 Checklist for Making Measurements in Analytical Chemistry

1.10 Presentation of Quantities and Their Values

1.10.1 Quantity and Value

1.10.2 Numerical Quantity Value

1.10.3 Measurement Unit

1.10.4 Spacing

1.10.5 Measurement Result

1.10.6 Measurement Uncertainty

1.10.7 Symbol for Quantity

1.10.8 Italic and Roman Font Style

1.10.9 Tables and Diagrams

1.10.10 Equations

Chapter 2 Chemometrics

2.1 Introduction

2.2 Data, Sampling and Data Processing.

2.3 Experimental Design

2.4 Multivariate Methods and Related Concepts

2.5 Classification

2.6 Calibration and Regression

Chapter 3 Extraction for Sample Preparation

3.1 Introduction

3.2 General Terms

3.2.1 General Terms (Fundamental Processes)

3.2.2 General Terms (Process Technology)

3.3 Extraction Techniques

3.3.1 Gas-Phase Extraction

3.3.2 Liquid-Liquid Extraction

3.3.3 Extraction of Solids by a Fluid

3.3.4 Digestion Methods

3.3.5 Solid-phase Extraction

3.3.6 Solid-Phase Microextraction Techniques

3.3.7 Membrane Extraction

3.3.8 Automated and High-throughput Extraction Methods-Advanced Flow Technology

Chapter 4 Mass and Volume in Analytical Chemistry

4.1 Introduction

4.2 Foundations of Quantitative Chemical Measurements

4.2.1 The Decimal Metric System

4.2.2 SI Units for Mass, Volume and Amount of Substance

4.2.3 Mass: Kilogram

4.2.4 Volume and Time: Metre and Second

4.2.5 Amount of Substance: Mole

4.3 Measurement of Mass

4.3.1 Types of Balances

4.3.2 Calibrating Weights

4.3.3 Mass in Air and a Vacuum

4.3.4 Piezoelectric Measurement of Mass

4.4 Measurement of Volume

4.4.1 Volumetric Glassware Tolerances and Calibration

4.5 Solutions

4.5.1 Preparation of Solutions

4.5.2 Solutions Prepared by Dilution

4.5.3 Preparation of Standard Solutions

4.5.4 Stoichiometry and Equivalence in Titrations

4.6 Methods of Analysis Depending on Measurement of Mass

4.6.1 Gravimetric Analysis by Direct Weighing of the Analyte

4.6.2 Gravimetric Analysis of Precipitates

4.6.3 Gravimetric Analysis Involving Vapours

4.6.4 Thermogravimetric Analysis

4.7 Methods of Analysis Depending on Measurement of Volume

4.7.1 Kinds of Titrations

4.7.2 Requirements for a Titration

4.7.3 Direct and Back Titration.

4.7.4 Visual Indicators

4.7.4.1 General Characteristics

4.7.4.2 Acid-Base Visual Indicators

4.7.5 Complexometric Indicators

4.7.6 Redox Indicators

4.7.7 Adsorption and Precipitation Indicators

4.7.8 Instrumental Indicators

4.7.8.1 pH Meters and Ion Selective Electrodes

4.7.8.2 Measurement of Potential in Redox Titrations

4.7.9 Examples

4.7.9.1 Measurement of Alkalinity of Natural Waters

4.7.9.2 Mohr Method for Chloride

4.7.9.3 Measurement of Water Hardness

4.7.9.4 Karl Fischer Titration of Water

4.8 Quality of Results

4.8.1 Aspects of Quality

4.8.2 Uncertainty Associated with Mass Measurement

4.8.2.1 Uncertainty Components

4.8.2.2 Example

4.8.3 Uncertainty Associated with Volume Measurement

4.8.3.1 Examples

4.8.3.1.1 Example 1

4.8.3.1.2 Example 2

4.8.3.1.3 Example 3

4.8.4 Measurement Uncertainty Associated with Preparing Standard Solutions

4.8.4.1 Examples

4.8.5 Uncertainty Associated with Titration

4.8.5.1 Example

4.9 Glossary of Terms

Chapter 5 Separation in Analytical Chemistry

5.1 Introduction

5.2 Chromatography

5.2.1 Basic Terms and Definitions

5.2.2 Principal Methods

5.2.3 Classification According to the Shape of the Chromatographic Bed

5.2.4 Classification According to the Physical State of the Mobile Phase

5.2.5 Classification According to the Mechanism of Separation

5.2.6 Classification According to the Mode of Elution

5.2.7 Terms Related to the Chromatographic Process and the Theory of Chromatography

5.2.7.1 The Column

5.2.7.2 The Chromatogram

5.2.7.3 The Mobile Phase

5.2.7.4 Retention Parameters

5.2.8 Terms Expressing the Efficiency of Separation

5.2.9 Classification of Detectors

5.2.10 Supercritical Fluid Chromatography and Extraction

5.2.11 Counter-current Chromatography, (CCC).

5.2.12 Ion-exchange Chromatography

5.2.13 Enantioselective, (chiral) Chromatography

5.2.14 Two-dimensional Chromatography

5.2.15 Exclusion Chromatography

5.3 Electromigration Techniques

5.4 Field-flow Fractionation and Related Techniques

Chapter 6 Analytical Spectroscopy

6.1 Introduction

6.2 General Terms

6.2.1 Kinds of Spectroscopy

6.2.2 Basic Terms Relating to Electromagnetic Radiation

6.2.3 General Terms Related to Spectroscopy

6.2.4 General Terms Relating to Instrumentation in Spectroscopy

6.2.5 Fundamental Functions and Mathematical Data Treatment

6.3 NMR Spectroscopy

6.3.1 Basic NMR Terms

6.3.2 Experimental Terminology in NMR

6.3.3 Named NMR Experiments

6.4 Atomic Spectroscopy

6.4.1 Methods of Atomic Spectroscopy

6.4.2 General Terms used in Atomic Spectroscopy Techniques

6.4.3 Terms Relating to Atomic Emission Spectroscopies

6.4.4 Terms Relating to Atomic Absorption Spectroscopies, &amp

lpar

AAS&amp

rpar

6.5 Vibrational Spectroscopy

6.5.1 Introduction to Vibrational Spectroscopy

6.5.2 Methods in Vibrational Spectroscopy

6.5.3 Terms in Vibrational Spectroscopy

Chapter 7 Mass Spectrometry

7.1 Introduction

7.2 Terms in Mass Spectrometry

Chapter 8 Electroanalytical Chemistry

8.1 Introduction

8.2 Fundamental Electrochemical Terms

8.3 General Terms in Electroanalytical Chemistry

8.4 Electrode Systems

8.4.1 Classification of Electrodes by Size

8.4.2 Classification of Electrodes by Function

8.4.3 Classification of Electrodes by Chemical Composition

8.4.4 Other Electrode Systems

8.5 Electroanalytical Techniques

8.5.1 Potentiometry and Related Techniques

8.5.2 Amperometry and Related Techniques

8.5.3 Voltammetry and Related Techniques.

8.5.4 Electrochemical Pre-concentration/Stripping Methods

8.5.5 Coulometry and Related Techniques

8.5.6 Electrogravimetry and Related Techniques

8.5.7 Conductometry and Related Techniques

8.5.8 Methods Based on Measurement of Impedance

8.5.9 Combined Methods

Chapter 9 Radioanalytical Chemistry

9.1 Introduction

9.2 General Terms in Radiochemistry

9.3 Measurement of Radiation

9.4 General Terms in Radioanalytical Chemistry

9.5 Measurement using Particles

9.6 Measurement using High-Energy Photons

9.7 Measurement Using Nuclides

Chapter 10 Analytical Chemistry of Surfaces

10.1 Introduction

10.2 Surface Chemical Analytical Methods

10.2.1 Electron Spectroscopies

10.2.2 Ion Scattering Spectroscopies

10.2.3 Mass Spectrometries

10.2.4 Optical and X-Ray Spectroscopies

10.3 Terms used in Surface Chemical Analysis

10.3.1 General Terms

10.3.2 Electron Spectroscopy

10.3.3 Ion Scattering Spectroscopy

10.3.4 Mass Spectrometry

10.3.5 Optical and X-Ray Spectroscopy

Chapter 11 Thermal Analysis

11.1 Introduction

11.1.1 Historical Matters

11.2 Definition of the Field Of Thermal Analysis &amp

TA&amp

11.3 Measurement Principles

11.4 Terminology and Glossary

11.5 Symbols Used in Thermal Analysis

11.6 Reporting Experimental Data

Chapter 12 Bioanalytical Chemistry

12.1 Introduction

12.2 Bioanalytical Samples

12.3 Analysis of Biomolecules

12.3.1 General Terms

12.3.2 Enzymatic Methods

12.3.3 Immunoanalytical Methods

12.3.4 Genomics and Nucleic Acid Analysis

12.3.5 Proteomics

12.3.6 Metabolomics

12.3.7 Glycomics

12.3.8 Lipidomics

12.4 Studies of the Interactions Between Biomolecules

Chapter 13 Quality in Analytical Chemistry

13.1 Introduction.

13.2 General Concepts Related to Quality and Quality Management.

Notes:

"International Union of Pure and Applied Chemistry".

Includes bibliographical references and index.

Description based on publisher supplied metadata and other sources.

Description based on print version record.

Other Format:

Print version: Hibbert, D Brynn Compendium of Terminology in Analytical Chemistry

ISBN:

1-78801-923-7

1-78801-288-7

9781788012881