Biobased adhesives : sources, characteristics, and applications / edited by K. L. Mittal and Manfred Dunky.

Format:

Book

Contributor:

Mittal, K. L., editor.

Dunky, Manfred, editor.

Series:

Adhesion and Adhesives: Fundamental and Applied Aspects Series

Language:

English

Subjects (All):

Adhesives.

Physical Description:

1 online resource (762 pages)

Place of Publication:

Hoboken, NJ : John Wiley & Sons, Inc., [2023]

Summary:

Biobased Adhesives Unique and comprehensive book edited by acknowledged leaders on biobased adhesives that will replace petroleum-based adhesives. This book contains 23 chapters covering the various ramifications of biobased adhesives. The chapters are written by world-class scientists and technologists actively involved in the arena of biobased adhesives. The book is divided into three parts: Part 1: Fundamental Aspects; Part 2: Classes of Biobased Adhesives; and Part 3: Applications of Biobased Adhesives. Topics covered include: an introduction to biobased adhesives; adhesion theories and adhesion and surface issues with biobased adhesives; chemistry of adhesives; biorefinery products as biobased raw materials for adhesives; naturally aldehyde-based thermosetting resins; natural crosslinkers; curing and adhesive bond strength development in biobased adhesives; mimicking nature; bio-inspired adhesives; protein adhesives; carbohydrates as adhesives; natural polymer-based adhesives; epoxy adhesives from natural materials; biobased polyurethane adhesives; nanocellulose-modified adhesives; debondable, recyclable, and biodegradable biobased adhesives; 5-Hydroxymethylfurfural-based adhesives; adhesive precursors from tree-derived naval stores; and applications in various diverse arenas such as wood bonding, controlled drug delivery, and wearable bioelectronics. Audience This book will interest materials scientists, adhesionists, polymer chemists, marine biologists, food and agriculture scientists, and environmentalists. R&D personnel in a slew of wide-ranging industries such as aviation, shipbuilding, railway, automotive, packaging, construction, wood bonding, and composites should find this book a repository of current and much-needed information.

Contents:

Cover

Title Page

Copyright Page

Contents

Preface

Part 1: Fundamental Aspects

Chapter 1 Introduction to Naturally-Based (Bio-) Adhesives

1.1 Introduction

1.2 Overview and Challenges For Adhesives Based on Natural Resources

1.2.1 Combined Use of Synthetic and Naturally-Based Adhesives

1.2.2 Overview on Adhesives Based on Natural Resources

1.2.3 Requirements, Limitations, and Opportunities for Wood Adhesives Based on Natural Resources

1.3 Biorefinery and Platform Chemicals

1.4 Lignin as Raw Material for Platform Chemicals

1.5 5-Hydroxymethylfurfural (5-HMF) as Platform Chemical

1.6 Mimicking Nature

1.7 Special Topics and Latest Developments

1.8 Prospects

1.9 Summary

General Literature on Biobased Adhesives

List of Abbreviations

References

Chapter 2 Adhesion Theories in Naturally-Based Bonding: Adhesion and Surface Issues with Naturally-Based Adhesives

2.1 Introduction

2.2 Adhesion Theories

2.2.1 Mechanical Interlocking

2.2.2 Electrostatic Mechanism

2.2.3 Adsorption (Thermodynamic) or Wetting Mechanism

2.2.4 Diffusion Mechanism

2.2.5 Chemical (Covalent) Bonding Mechanism

2.2.5.1 Hydrogen Bonding

2.2.6 Acid-Base Theory

2.2.7 Weak Boundary Layers

2.2.8 Stickiness or Tackiness

2.3 Protein Adhesives

2.3.1 Animal-Sourced Proteins

2.3.2 Plant Proteins

2.4 Carbohydrate-Based Adhesives

2.5 Plant or Wood-Based Extractives

2.5.1 Rubber

2.5.2 Resins

2.5.2.1 Rosin

2.5.2.2 Terpene Resins

2.5.2.3 Tannins

2.5.2.4 Gums

2.6 Fats or Oils

2.6.1 Tung Oil

2.6.2 Linseed Oil

2.6.3 Soybean Oil

2.6.4 Castor Oil

2.6.5 Miscellaneous Oils

2.7 Summary

Acknowledgements

Chapter 3 The Chemistry of Bioadhesives

3.1 Introduction

3.2 Carbohydrate Bioadhesives.

3.3 Protein Bioadhesives

3.4 Lignin-Based Bioadhesives

3.5 Tannin-Based Bioadhesives

3.5.1 Hydrolysable Tannins

3.5.1.1 Gallo-Tannins

3.5.1.2 Ellagi-Tannins

3.5.2 Condensed Polyflavonoid Tannins

3.5.3 Reactions of Condensed Flavonoid Tannins

3.6 Other Bio-Adhesives for Wood Composites

3.7 Summary

Chapter 4 Biorefinery Products as Naturally-Based Key Raw Materials for Adhesives

4.1 Biorefinery Systems

4.1.1 History of Biomaterials

4.1.2 Classification of Biorefinery Systems

4.1.3 Biorefinery Processes

4.1.3.1 Hydrothermal Processes

4.1.3.2 Thermochemical Processes

4.1.3.3 Chemical Processes

4.1.3.4 Biochemical Processes

4.1.3.5 Bacterial Processes

4.1.4 Renewable Materials for Biorefinery

4.1.4.1 Carbohydrates

4.1.4.2 Lignin

4.1.4.3 Triglycerides

4.1.4.4 Mixed Organic Residues

4.2 Biobased Materials

4.2.1 Biobased Monomers

4.2.2 Synthesis Methods

4.2.2.1 L-3,4-Dihydroxyphenylalanine

4.2.2.2 2-Pyrone-4,6-dicarboxylic acid

4.3 Biobased Materials Suitable for Adhesives

4.3.1 Additives

4.3.2 Wood Adhesives

4.3.3 Lignin-Based Adhesives

4.3.4 Biorefinery Process of Kash

4.3.5 Lignin-Phenol Adhesives

4.3.5.1 Enzymatic Hydrolysis of Lignin

4.3.5.2 Biorefinery Residues

4.3.5.3 Phenol Replacement by Lignins

4.3.6 Lignin-Epoxy Adhesives

4.3.7 Lignosulfonates

4.3.8 Tannins

4.3.9 Protein-Based Adhesives

4.4 Synthesis Methods for Biobased Adhesives

4.4.1 Methylolated Wood-Derived Bio-Oil

4.4.2 Biosynthesis of Lignin

4.4.3 Soy-Based Adhesives

4.4.4 Bisphenol A-Glycidyl Methacrylate Replacement

4.5 Modification of Lignin for Better Performance

4.5.1 Functionalization with Aromatic Compounds

4.5.1.1 Functionalization of Lignin

4.5.1.2 Phenolation of Lignin.

4.5.2 Organosolv Lignin-Based Materials

4.6 Pressure-Sensitive Adhesives

4.6.1 Lignin as Filler

4.6.2 Biobased Acrylic Compounds

4.6.3 UV-Tunable Pressure-Sensitive Adhesives

4.7 Summary

Chapter 5 Natural Aldehyde-Based Thermosetting Resins

5.1 Introduction

5.2 Aliphatic Aldehydes

5.2.1 Acetaldehyde

5.2.2 Glyoxal

5.2.2.1 Glyoxalation of Lignin

5.2.2.2 Glyoxylic Acid and Glyoxal

5.2.2.3 Glyoxal and Glutaraldehyde

5.2.2.4 Glyoxal and 5-Hydroxymethylfurfural (5-HMF)

5.2.3 Dimethoxy-Ethanal (Dimethoxy-Acetaldehyde, DME)

5.2.4 Propanal (Propionaldehyde)

5.2.5 Butyraldehyde

5.2.6 Isobutyraldehyde (Isobutanal)

5.2.7 Succinaldehyde (Butandial)

5.2.8 Glutar(di)aldehyde (GA) (Pentandial)

5.3 Aldehydes Based on Cyclic Structures

5.3.1 Furfural (Furfurylaldehyde)

5.3.2 Furfuryl Alcohol (FA)

5.3.3 5-Hydroxymethylfurfural (5-HMF) (see also Chapters 1 and 17)

5.3.4 2,5-Diformylfuran (2,5-Furan-Dicarbaldehyde)

5.3.5 Aromatic Aldehyde Precursors

5.3.6 Polymers with Pendent Aldehyde Groups

5.4 Summary

Chapter 6 Natural Crosslinkers for Naturally-Based Adhesives

6.1 Introduction

6.2 Crosslinking Reactions

6.2.1 Proteins

6.2.2 Tannins

6.2.3 Carbohydrates

6.2.4 Lignins

6.3 Aliphatic Aldehydes as Crosslinkers

6.3.1 Formaldehyde

6.3.2 Higher Aldehydes

6.3.3 Glyoxal

6.3.4 Glutaraldehyde

6.3.5 Higher Aliphatic Aldehydes

6.4 Cyclic and Aromatic Aldehydes as Crosslinkers

6.4.1 Furfural

6.4.2 5-Hydroxymethylfurfural (5-HMF)

6.4.3 Non-Volatile Aldehydes from Carbohydrates

6.5 Crosslinkers Prepared from Biomass

6.5.1 Furfuryl Alcohol

6.5.2 Extracts as Crosslinkers

6.5.3 Glycerol Diglycidyl Ether (GDE), Glycerol Polyglycidyl Ether (GPE), and Ethylene Glycol Diglycidyl Ether (EGDE).

6.5.4 Triglycidylamine (TGA)

6.5.5 Diethylene-Triamine (DETA)

6.5.6 Citric Acid

6.6 Synthetic Crosslinkers

6.6.1 Polyamidoamine-Epichlorohydrin (PAE) Resins

6.6.2 Epoxy Resins

6.6.3 Polyethylenimine (PEI)

6.6.4 Polyamidoamine (PADA)

Chapter 7 Curing and Adhesive Bond Strength Development in Naturally-Based Adhesives

7.1 Introduction

7.2 Curing Monitoring Techniques

7.2.1 Gel Time Test

7.2.2 Differential Scanning Calorimetry (DSC)

7.2.3 Thermogravimetric Analysis (TGA)

7.2.4 Dielectric Analysis (DEA)

7.3 Bond Strength Development Monitoring Techniques

7.3.1 Dynamic Mechanical Analysis (DMA)

7.3.2 Thermomechanical Analysis (TMA)

7.3.3 Automated Bonding Evaluation System (ABES)

7.3.4 Tensile-Shear Strength

7.4 Curing Mechanisms in Naturally-Based Adhesives

7.4.1 Tannin-Based Adhesives

7.4.2 Lignin-Based Adhesives

7.4.3 Soy-Based Adhesives

7.4.4 Sucrose-Based Adhesives

7.4.5 Starch-Based Adhesives

7.4.6 Liquefied Wood (LW)-Based Adhesives

7.5 Summary

Chapter 8 Mimicking Nature: Bio-Inspired Adhesives

8.1 Introduction

8.2 Improvement of Adhesive Performance

8.3 Underwater Adhesives (Wet Application Adhesives)

8.4 Detechable Bonding and Self-Healing Polymers

8.5 Medical Applications

8.6 Summary

Part 2: Classes of Biobased Adhesives

Chapter 9 Protein Adhesives - Composition, Structure and Performance

9.1 Introduction

9.2 Composition of Proteins

9.3 Types, Sources, Processing, and Properties of Proteins

9.3.1 Collagen (Animal)

9.3.2 Globular (Plant)

9.3.3 Globular (Milk)

9.3.4 Globular (Egg)

9.3.5 Globular (Blood)

9.3.6 Other Protein Sources.

9.4 Conclusion (Future of Protein Adhesives) and Summary

Chapter 10 Carbohydrates (Polysaccharides) as Adhesives

10.1 Introduction

10.2 Cellulose Derivatives

10.3 Starch-Based Adhesives

10.4 Dextrin

10.5 Natural Gums

10.6 Chitosan

10.7 Summary and Prospects

Chapter 11 Natural Polymer-Based Adhesives

11.1 Introduction

11.2 Natural Rubber (NR)-Based Adhesives

11.2.1 Introduction to NR-Based Adhesives

11.2.2 NR-Based Wood Adhesives

11.2.3 NR-Based Pressure-Sensitive Adhesives

11.2.4 NR-Based Adhesives in Leather, Rubber, Textile and Metal Bonding Applications

11.3 Poly(lactic acid) (PLA)-Based Wood Adhesives

11.3.1 Introduction to PLA-Based Adhesives

11.3.2 PLA-Based Wood Adhesives

11.3.3 PLA-Based Hot-Melt Adhesives

11.3.4 PLA-Based Adhesives for Metal Bonding

11.4 Chitosan-Based Adhesives

11.4.1 Introduction to Chitosan-Based Adhesives

11.4.2 Chitosan-Based Wood Adhesives

11.5 Summary

Chapter 12 Epoxy Adhesives from Natural Materials

12.1 Introduction and Morphology

12.2 Basic Properties of Epoxies

12.3 Epoxy Synthesis

12.4 Epoxy Curing

12.4.1 One-Component Epoxies

12.4.2 Two-Component Epoxies

12.5 Aromatic Epoxies

12.5.1 Aromatic Bis-Phenol Epoxies

12.5.2 Aromatic Novolac Epoxies

12.5.3 Biobased Aromatic Epoxies from Polyphenols, Tannins, Cardanol, and Lignin

12.5.4 Aromatic Epoxies from Lignin and Woody Biomass

12.6 Aliphatic Epoxies

12.6.1 Aliphatic Epoxies from Vegetable Oils

12.6.2 Aliphatic Epoxies from Sugars

12.6.3 Aliphatic Epoxies from Terpenoids

12.6.4 Other Aliphatic Epoxies

12.7 Hardeners

12.7.1 Amines

12.7.1.1 Aliphatic Amines

12.7.1.2 Biobased Aliphatic Amines.

12.7.1.3 Aromatic Amines.

Notes:

Description based on print version record.

Includes bibliographical references and index.

Other Format:

Print version: Mittal, K. L. Biobased Adhesives

ISBN:

9781394175406

139417540X

9781394175390

1394175396

OCLC:

1376931821