Metal-Organic Frameworks in Analytical Chemistry / edited by Amirhassan Amiri and Masoud Mirzaei.

Format:

Book

Contributor:

Amiri, Amirhassan, editor.

Mirzaei, Masoud, 1985- editor.

Language:

English

Subjects (All):

Analytical chemistry.

Metal-organic frameworks.

Physical Description:

1 online resource (485 pages)

Edition:

First edition.

Place of Publication:

London, England : The Royal Society of Chemistry, [2023]

Summary:

This book covers multipurpose usage of MOFs in sample preparation, integration, and detection stages of analytical chemistry for researchers/scientists/engineers who are interested in developing new materials or new applications.

Contents:

Cover

Preface

Contents

Chapter 1 Metal-Organic Frameworks in Green Analytical Chemistry

1.1 Introduction

1.2 Green Synthesis

1.3 Preparation of MOFs Considering GAC Principles

1.3.1 Green Design and Synthesis of MOFs

1.4 Properties of MOFs Towards GAC

1.4.1 Toxicity Issues of MOFs

1.5 MOFs as Green Media in Analytical Chemistry

1.5.1 MOFs as Green Sorbents in Sensors

1.5.2 MOFs as Green Sorbents in Extraction Processes

1.5.3 MOFs as Green Media in Chromatography

1.5.4 MOFs in Electrophoretic Separations

1.5.5 MOFs as Sensors

1.6 Concluding Remarks

References

Chapter 2 Chemistry of Metal-Organic Frameworks

2.1 Introduction

2.2 Classification of Synthesis Methods

2.2.1 Solvothermal Synthesis

2.2.2 MW- and US-assisted Synthesis

2.2.3 EC Synthesis

2.2.4 MC Synthesis

2.2.5 Classical Synthesis Methods

2.2.6 Synthesis Methods for MOF Composites

2.3 Characterization Methods

2.4 Properties of MOFs

2.4.1 Electrochemical Properties

2.4.2 Optical Properties

2.4.3 Mechanical Properties

2.4.4 Thermal Properties

2.4.5 Magnetic Properties

2.4.6 Adsorbent Properties for Analytical Sample Preparation

2.5 Conclusion

Acknowledgements

Chapter 3 Metal-Organic Framework Nanocomposites

3.1 Introduction

3.2 Nanocomposites with Improved Physical, Mechanical, and Chemical Properties

3.3 Fabrication of MOF Nanocomposites

3.4 MOF-based Nanocomposite Solutions in Analytical Chemistry

3.5 Conclusion

Chapter 4 Cleanup and Remediation Based on MOFs

4.1 Introduction

4.2 MOF-based Engineered Materials and TheirFormats for Cleanup and Remediation of Environmental Pollutants

4.2.1 MOF-based Engineered Materials

4.2.2 Formats of MOF-based Materials Used in Environmental Remediation.

4.3 Applications of MOF-based Materials in Cleanup and Remediation of Aqueous Environments

4.3.1 Removal of Organic Contaminants from Water

4.3.2 Removal of Inorganic Contaminants from Water

4.4 Applications of MOF-based Materials in Cleanup and Remediation of Atmospheric Environments

4.4.1 Removal of Organic Contaminants from Air

4.4.2 Removal of Inorganic Contaminants from Air

4.5 Conclusions and Future Perspectives

Abbreviations

MOF Names

Chapter 5 Metal-Organic Frameworks in the Sample Preparation Stage of Analysis

5.1 Introduction

5.2 Unique Properties of MOFs as Sorbents

5.3 SPE

5.4 dSPE

5.5 MSPE

5.6 SPME

5.7 Conclusions and Perspectives

Chapter 6 Metal-Organic Frameworks in Solid Phase Extraction of Organic and Inorganic Trace Analytes from Food and Environmental Samples

6.1 Introduction

6.2 MOFs as Adsorbents for Pesticides

6.3 MOFs as Adsorbents for Toxic Metals

6.4 MOFs as Adsorbents for Drugs

6.5 MOFs as Adsorbents for Dyes

6.6 Conclusions

Chapter 7 Use of Metal-Organic Frameworks in the Separation/Identification Stage of Analysis

7.1 Introduction

7.2 Unique MOF Properties as Sorbents

7.2.1 Stability of MOFs

7.2.2 Porosity and Surface Area

7.2.3 Analyte Interaction

7.3 MOF-based Sample Preparation

7.3.1 SPE

7.3.2 MSPE

7.3.3 SPME

7.4 MOF-based Stationary Phases

7.4.1 MOFs as Stationary Phases in GC

7.4.2 MOFs as Stationary Phases in LC

7.4.3 MOFs as Stationary Phases in CEC

7.5 MOF-based Membranes

7.5.1 Gas Separation with MOF Membranes

7.5.2 Liquid Separation with MOF Membranes

7.5.3 Ion Separation with MOF Membranes

7.6 Conclusions

References.

Chapter 8 Use of Metal-Organic Frameworks in the Detection Stage of Analysis/Miniaturization Devices

8.1 Introduction

8.2 Unique MOF Properties for Sensor Design

8.3 MOFs in Sensors

8.3.1 Optical Sensors

8.3.2 Electrochemical Sensors

8.3.3 Biosensors

8.3.4 Electromechanical Sensors

8.3.5 Gas Sensors

8.3.6 Mass-sensitive Sensors

8.4 MOFs in a Lab- on-a-chip

8.5 Conclusions

Chapter 9 Metal-Organic Frameworks for Sensing Applications

9.1 Introduction

9.2 MOF Properties for Sensing Applications

9.3 Design and Structural Considerations for Sensitivity and Selectivity Improvement

9.3.1 Take-home Points

9.4 Stability, Reproducibility, and Reliability of MOF-based Sensors

9.4.1 Take-home Points

9.5 Current MOF-based Sensing Devices

9.5.1 Optical Transducers

9.5.2 Electrochemical Transducers

9.5.3 Mechanical Transducers

9.6 Final Remarks and Future Perspectives

Chapter 10 Sensors Based on Conductive Metal-Organic Frameworks

10.1 Introduction

10.2 Synthesis of C- MOFs

10.2.1 Hydro/Solvothermal Synthesis

10.2.2 Interface-mediated Synthesis

10.2.3 Electrochemical Synthesis

10.2.4 PSM

10.3 Electronic MOF Sensors

10.3.1 Chemical Sensors

10.3.2 Electrochemical Sensors

10.4 Conclusion

Chapter 11 Metal-Organic Framework/Enzyme Composites

11.1 Introduction

11.2 Unique Properties of MOF/Enzyme Composites

11.3 Design and Fabrication of MOF/Enzyme Composites

11.3.1 Surface Bioconjugation

11.3.2 Encapsulation

11.3.3 Infiltration

11.4 Characterization of MOF/Enzyme Composites

11.5 Biosensing

11.5.1 Biosensors Based on Enzymatic Substrates

11.5.2 Biosensors Based on MOF/ Enzyme Composites as Catalyst Systems

11.5.3 Biosensors Based on Activity Modulation.

11.6 Magnetic MOF/Enzyme Composites

11.7 Conclusion

Chapter 12 Molecularly Imprinted Metal-Organic Frameworks

12.1 Introduction

12.2 Polymerization Techniques for MI-MOFs

12.2.1 Surface Imprinting

12.2.2 Electropolymerization

12.2.3 Sol-Gel Polymerization

12.3 Applications in Sensor Fabrication

12.3.1 Fluorescence-based Sensors

12.3.2 Electrochemical Sensors

12.4 Applications in Analytical/Bioanalytical Sample Preparation

12.4.1 SPE

12.4.2 SPME Applications

12.4.3 Comparison of the Performance of Reported MI-MOFs

12.5 Conclusion

Chapter 13 Chiral Metal-Organic Frameworks

13.1 Introduction

13.2 Direct Chiralization Methods for Preparation of CMOFs

13.3 Indirect Chiralization Methods for Preparation of CMOFs

13.3.1 Using Achiral Precursors

13.3.2 Post-synthesis Modification

13.4 Spontaneous Resolution

13.5 Analytical Applications of CMOFs

13.5.1 Enantioselective Sensing

13.5.2 Enantioselective Separation

Chapter 14 Application of Metal-Organic Framework Nanocomposites

14.1 Introduction

14.2 Biological Applications

14.2.1 Drug Delivery

14.2.2 Photodynamic Therapy

14.2.3 Bioimaging

14.3 Catalysis

14.3.1 Photocatalysis

14.4 Adsorption

14.4.1 Toxic Pollution Control

14.4.2 Gas Separation

14.5 Sensing Applications

14.5.1 Electrochemical Sensing

14.5.2 Biosensing

14.5.3 Photoluminescence Sensing

14.6 Extraction and Preconcentration

14.7 Conclusion

Subject Index.

Notes:

Includes bibliographical references.

Description based on publisher supplied metadata and other sources.

Description based on print version record.

ISBN:

1-83916-748-3

1-83916-749-1

OCLC:

1428260468