Capacitive Deionization / Xingtao Xu and Likun Pan.

Format:

Book

Author/Creator:

Xu, Xingtao, author.

Pan, Likun, author.

Series:

Research studies. Energy & environment series ; Number 32.

Energy and Environment Series ; Number 32

Language:

English

Subjects (All):

Saline water conversion.

Physical Description:

1 online resource (363 pages)

Edition:

First edition.

Place of Publication:

London, England : The Royal Society of Chemistry, [2024]

Summary:

This book showcases the fundamentals and progressive achievements of capacitive deionization over the years.

Contents:

Cover

Preface

Author Biographies

Contents

Chapter 1 Timeline of Capacitive Deionization: The Path to a New Era

1.1 Introduction

1.2 Evaluation Metrics of CDI

1.2.1 Salt Adsorption Capacity

1.2.2 Salt Adsorption Rate

1.2.3 Salt Adsorption Efficiency

1.2.4 Flow Efficiency

1.2.5 Charge Efficiency and Specific Energy Consumption

1.2.6 Cycling Performance

1.2.7 CDI Ragone Plot

1.3 Electrode Materials

1.3.1 Ion Capture Mechanisms

1.3.2 Carbon Nanomaterials

1.3.3 Faradaic Nanomaterials

1.4 Conceptual Design of Cell Architectures for CDI

1.5 Conclusion

References

Chapter 2 Carbon Nanomaterials for Capacitive Deionization: Heteroatom Doping and Its Functionalities

2.1 Introduction

2.2 Nitrogen Doping Strategies

2.2.1 In Situ Doping

2.2.2 Post- processing Approach

2.3.1 Biomass-derived NCs

2.3.2 Nitrogen-doped Carbon Nanospheres (NCSs) and Their Derivatives

2.3.3 Graphene-based NC Materials

2.3.4 Polymer-derived NCs

2.3.5 MOF/COF-derived NCs

2.4 Role of Nitrogen Dopants in the CDI Process

2.4.1 CDI Performance Via a Balance Between Pore Structure and Nitrogen Doping

2.4.2 Selective Capture of Metal Ions Via Nitrogen Coordination

2.4.3 Enhanced Performance Stability by Nitrogen Dopants

2.5 Conclusion and Perspective

Chapter 3 Carbon Nanomaterials for Capacitive Deionization: Emerging Precursors Via Pyrolysis

3.1 Introduction

3.2 Carbon Nanomaterials from Biomass Precursors

3.2.1 Biomass-derived Carbon Nanoarchitectures

3.2.2 Pore Engineering in Biomass-derived Nanocarbon

3.2.3 Synthetic Strategies for Biomass- derived Nanocarbons

3.3 Conclusion and Outlook

Chapter 4 Beyond Carbon Nanomaterials: The Rise of Faradaic Nanomaterials

4.1 Introduction

4.2 Faradaic Materials for CDI.

4.2.1 Sodium Manganese Oxide

4.2.2 PB and PBAs

4.2.3 Polyanionic Compounds

4.2.4 2D Layered Materials

4.2.5 Chloride Ion Adsorption Materials

4.2.6 Organic Materials

4.2.7 Desalination Battery

4.3 Challenges and Perspectives

Chapter 5 Defining Capacitive Deionization from the Perspective of Faradaic Nanomaterials

5.1 Introduction

5.2 Timeline for the Electrochemical Desalination and Cell Architectures

5.3 HCDI

5.3.1 TMO-based Electrodes

5.3.2 TMS- based Electrodes

5.3.3 TMC-based Electrodes

5.3.4 NASICON-based Electrodes

5.3.5 PB-based Electrodes

5.3.6 Silver/Bismuth-based Electrodes (Cl Capturing Electrode Materials)

5.3.7 Other Electrode Materials for HCDI

5.4 RCDI

5.4.1 PB-based Electrodes

5.4.2 Nafion- coated AC

5.4.3 Flow-through RCDI

5.5 Dual-ion Intercalation Electrochemical Desalination

5.5.1 NMO8Silver-based Systems

5.5.2 NMO8BiOCl-based Systems

5.5.3 NASICON8Silver-based Systems

5.6 Summary and Outlook

Chapter 6 Technological and Conceptual Evolution for Capacitive Deionization

6.1 Introduction

6.2 New Concepts for the CDI Technique

6.2.1 MCDI

6.2.2 i-CDI

6.2.3 FCDI

6.2.4 DB

6.2.5 HCDI

6.3 Conclusion

Chapter 7 Membrane Capacitive Deionization

7.1 Introduction

7.2 Operation of MCDI

7.3 Electrode Materials for MCDI

7.4 Advanced Membrane for MCDI

7.5 Application of MCDI

7.6 Challenges and Perspectives

Chapter 8 Inverted Capacitive Deionization

8.1 Introduction

8.2 Concept and Influence Factor of iCDI

8.3 Advances of iCDI

8.4 Challenges and Perspectives

Chapter 9 Flow- electrode Capacitive Deionization

9.1 Introduction

9.2 Concept and Influence Factor of FCDI

9.2.1 Concept of FCDI

9.2.2 The Factors That Influence FCDI.

9.3 FCDI Applications

9.3.1 Desalination

9.3.2 Water Softening

9.3.3 Heavy Metal Removal

9.3.4 Nutrient Removal and Recovery

9.4 Challenges and Perspectives

9.4.1 Process Optimization

9.4.2 Improving Energy Efficiency

9.4.3 Electrode Materials Engineering

Chapter 10 Hybrid Capacitive Deionization

10.1 Introduction

10.2 Classes of Hybrid CDI Devices

10.2.1 Faradaic Cathode and Faradaic Anode Type

10.2.2 Carbon Cathode and Faradaic Anode Type

10.2.3 Faradaic Cathode and Carbon Anode Types

10.3 Advances of HCDI

10.4 Challenges and Perspectives

Chapter 11 Capacitive Deionization for Selective Capture of Ions

11.1 Introduction

11.2 Challenges in Selective Adsorption

11.3 Advances in Selective Adsorption

11.4 Application for Water Softening

11.5 Perspectives

Chapter 12 Capacitive Deionization for Environmental Contamination Control

12.1 Introduction

12.2 Application of CDI Technology for Heavy Metal Ion Removal

12.3 Application of CDI Technology for Fluoride Ion Removal

12.4 Application of CDI Technology for Arsenic Ion Removal

12.5 Application of CDI Technology for the Removal of Organic Dyes

12.6 Application of CDI Technology for Inorganic Salts Removal

12.7 Challenges and Perspectives

Chapter 13 Capacitive Deionization for Rare Metal Recovery

13.1 Introduction

13.2 Technologies for Rare Metal Recovery

13.3 Application of CDI for Lithium Recovery

13.4 Application of CDI in Uranium Recovery

13.5 Application of CDI in Vanadium Recovery

13.6 Application of CDI in Indium Recovery

13.7 Challenges and Perspectives

Chapter 14 Capacitive Deionization for Industrial Applications: What Can We Expect?

14.1 Introduction

14.2 Current Scale of Industrial CDI.

14.3 Capital and Operation Cost Analysis of Industrial CDI

14.4 Solar-driven Electrochemical Deionization (SED): Can it be a Promising Option for Industrial CDI?

14.5 Challenging Issues and Possible Future Directions

Subject Index.

Notes:

Includes bibliographical references.

Description based on publisher supplied metadata and other sources.

Description based on print version record.

ISBN:

9781839165528

1839165529

9781839165535

1839165537