Streamlining Free Radical Green Chemistry / V. Tamara Perchyonok, Ioannis Lykakis, Al Postigo.

Format:

Book

Author/Creator:

Perchyonok, V. Tamara, author.

Lykakis, Ioannis, author.

Postigo, Al, author.

Language:

English

Subjects (All):

Free radicals (Chemistry).

Physical Description:

1 online resource (xxiv, 779 pages)

Place of Publication:

Cambridge : Royal Society of Chemistry, 2023.

Summary:

"This practical and concise guide showcases the sustainable methods offered by green free radical chemistry and summarizes the fundamental science involved. It discusses the pros and cons of free radical chemistry in aqueous systems for synthetic applications. All transformation steps are covered including initiation, propagation, and termination. Useful background knowledge is combined with examples, including industrial scale processes for pharmaceuticals and fine chemicals.".

Contents:

Chapter 1 Development of free radical green chemistry and technology: journey through times, solvents, causes, effects and assessments

chapter 2 Classical synthetic free radical transformations in alternative media: supercritical CO2, ionic liquids and fluorous media

chapter 3 Solvent-free carbon-carbon bond formations in ball mills and in the solid state

chapter 4 Microwaves in synthesis: how do microwaves promote the reaction in conventional and alternative media?

chapter 5 Asymmetric free-radical reductions mediated by chiral stannanes, germanes, and silanes

chapter 6 Organic radical reductions in water: water as a hydrogen atom source

chapter 7 Tin-free radical reactions mediated by organoboron compounds

chapter 8 Thiols as efficient hydrogen atom donors in free radical transformations in aqueous media

chapter 9 Advances in the use of phosphorus-centered radicals in organic synthesis in conventional flasks: advantages, reasons and applications

chapter 10 Metal-based homogeneous catalysis and free radical synthesis: advantages, developments and scope

chapter 11 Radicals and transition-metal catalysis: a complementary solution to increase reactivity and selectivity in organic chemistry

chapter 12 Reagent control in transition-metal-initiated radical reactions

chapter 13 Enantioselective radical reactions and organocatalysis. Chapter 14 The sunny side of chemistry: green synthesis by solar light

chapter 15 Sonochemistry: ultrasound application in radical synthesis

chapter 16 Black-light-initiated free radical reactions for synthetic applications, micro-reactors and modified nucleoside synthesis

chapter 17 Photo-catalysis and metal-oxygen-anion cluster decatungstate in organic chemistry: a manifold concept for green chemistry

chapter 18 Radical domino reactions: intermolecular telescopic reactions

chapter 19 Telescopic reactions and free radical synthesis: focus on radical and radical-ionic multicomponent processes

chapter 20 Radical-radical-radical telescopic reactions: from rules through reasons to applications

chapter 21 Applications of conventional free radicals and advances in total synthesis: from the bench to the future through the vinyl radical

chapter 22 Streamlining organic free redical synthesis through modern molecular technology: from polymer-supported synthesis to microreactors and beyond

chapter 23 Radical reactions and b-cyclodextrin as a molecular ferrari: is there a hidden advantage of speed, power and class? from fundamental reactions to potential applications

chapter 24 Artificial enzymes and free radicals: the chemist's perspective

chapter 25 Applications of conventional free radicals and advances in total synthesis: from the bench to nature through SmI2 radicals as an efficient trigger for radical cascades, a journey from orsay to the 21st century

chapter 26 Innovative reactions mediated by zirconocene: advantages and scope

chapter 27 Applications of conventional free radicals and advances in total synthesis: radical cascades in bio-inspired terpene synthesis.

Notes:

Description based on publisher supplied metadata and other sources.

ISBN:

1-83916-905-2