Advances in multi-photon processes and spectroscopy. Volume 22 / edited by S. H. Lin, A. A. Villaeys, Y. Fujimura.

Format:

Book

Contributor:

Lin, S. H., editor.

Villaeys, A. A., editor.

Fujimura, Y., editor.

Series:

Advances in Multi-Photon Processes and Spectroscopy

Advances in Multi-Photon Processes and Spectroscopy ; v.22

Language:

English

Subjects (All):

Multiphoton processes--Research.

Multiphoton processes.

Spectrum analysis--Data processing.

Spectrum analysis.

Laser spectroscopy--Diagnostic use.

Laser spectroscopy.

Physical Description:

1 online resource (273 p.)

Place of Publication:

Singapore : World Scientific Publishing Company, 2015.

Language Note:

English

Summary:

This volume presents the recent progress and perspective in multi-photon processes and spectroscopy of atoms, ions, molecules and solids. The subjects in the series cover the experimental and theoretical investigations in the interdisciplinary research fields of natural science including chemistry, physics, bioscience and material science. Contents: Theoretical Foundations for Exploring Quantum Optimal Control of Molecules (Tak-San Ho, Herschel Rabitz and Shih-I Chu); Intramolecular Nuclear Flux Densities (I Barth, C Daniel, E Gindensperger, J Manz, J F Pérez-Torres, A Schild, C Stemmle, D Sul

Contents:

Preface; CONTENTS; 1. Theoretical Foundations for Exploring Quantum Optimal Control of Molecules; 1. Introduction; 2. Time-dependent Molecular Dynamics Equations; 3. Quantum OCT for the State-to-State Transition Probability: The Lagrange Multipliers Method; 4. Theory of QCL for the State-to-State Transition Probability; 4.1. Kinematic critical points; 4.2. Quantum control landscape; 5. A TBQCP for State-to-State Transition Probability Control; 6. Optimal Control in the Weak Field Limit: The Adiabatic NBO Representation

7. Optimal Control in the Strong Field Limit - The Adiabatic ENBO Representation8. Optimal Control in the Adiabatic TDBO Representation; 9. Monotonically Convergent Optimal Control Search Algorithms: TBQCP Method; 10. Applications of the Monotonically Convergent TBQCP Method; 10.1.Molecular photoassociation along with vibrational stabilization; 10.2. Selective bond breakage in gas-phase dihalomethanes CH2BrC ; 10.3. Field-free orientation of a OCS thermal ensemble; 10.4.Vibrational excitation of H2 molecules; 11. Summary; Acknowledgments

3. Femtosecond Structural Study of Reacting Excited-State Molecules Through Observation of Nuclear1. Introduction; 2. Nuclear Wavepacket Motions in the Excited State as Observed by Pumb-Probe Measurements; 2.1. Generation and observation of nuclear wavepacket motions; 2.2. Selection rules; 2.3. Setup for ultrafast two-color pump-probe spectroscopy; 2.4. Example: S1 trans-stilbene; 2.4.1. Time-domain signal and its comparison with frequency-domain data; 2.4.2. Quantitative estimation of relative band intensities

3. Initial Nuclear Wavepacket Motions of Reacting Excited-state Molecules as Observed by Pump-Probe Spectroscopy3.1. Photoisomerization of cis-stilbene; 3.2. Photodissociation of diphenylcyclopropenone; 3.3. Intramolecular proton transfer of 10-hydroxybenzoquinoline; 4. Structural Tracking by Time-resolved Impulsive Raman; 4.1. Time-resolved impulsive stimulated Raman spectroscopy; 4.2. Setup for TR-ISRS experiment; 4.3. TR-ISRS studies of photoisomerization of cis-stilbene; 4.3.1. TR-ISRS measurements; 4.3.2. Comparison with theoretical calculations

4.4. Conceptual advance: Observation of continuous structural change

Notes:

Description based upon print version of record.

Includes bibliographical references and index.

Description based on online resource; title from PDF title page (ebrary, viewed October 15, 2014).

ISBN:

981-4619-04-3