Advances in multi-photon processes and spectroscopy Volume 11 / edited by S. H. Lin, A. A. Villaeys, Y. Fujimura.

Format:

Book

Contributor:

Lin, S. H. (Sheng Hsien), 1937-

Villaeys, A. A.

Fujimura, Y. (Yuichi)

Series:

Advances in Multi-Photon Processes and Spectroscopy

Advances in Multi-Photon Processes and Spectroscopy ; v.11

Language:

English

Subjects (All):

Raman effect, Resonance.

Multiphoton processes.

Physical Description:

1 online resource (217 p.)

Edition:

11th ed.

Other Title:

Multi-photon processes and spectroscopy

Place of Publication:

Singapore ; River Edge, NJ : World Scientific, c1998.

Language Note:

English

Summary:

In view of the rapid growth in both experimental and theoretical studies of multiphoton processes and multiphoton spectroscopy of atoms, ions and molecules in chemistry, physics, biology, materials science, etc., it is desirable to publish an advanced series of books containing review papers that can be read not only by active researchers in these areas, but also by those who are not experts in the field but intend to enter it. The present series attempts to serve this purpose. Each review article is written in a self-contained manner by experts in the area, so that the reader can grasp the knowledge in the area without too much preparation.

Contents:

Contents; Preface; PART ONE Resonance Raman Intensities: The Roundabout Way to; Resonance Raman Intensities: The Roundabout Way to Franck-Condon Analysis; 1. Introduction; 2. Symmetric triatomic molecules and ions; 2.A. Carbon disulfide; 2.A.i.. Emission polarization and rotational lineshapes in vapor; 2.A.ii. Electronic dephasing in solution; 2.B. Sulfur dioxide; 2.C. Triiodide ion; 3. Other small photodissociative molecules; 3.A. Alkyl iodides; 3.B. Nitromethane; 4. Small linear polyenes; 4.A. Trans-hexatriene; 4.B. Cis-hexatriene; 4.C. Butadiene; 5. Stilbene; 5.A. Trans-stilbene

5.B. Cis-stilbene6. Charge transfer systems; 6.A. Hexamethylbenzene/tetracyanoethylene complex; 6.B. Covalent charge-transfer molecules; 7. Azulene; 8. Conclusions; 9. Acknowledgments; 10. References; PART TWO Van der Waals Complexes and Small Molecular Clusters: A Tool to Understand and Control Chemical Reactions; Van der Waals Complexes and Small Molecular Clusters: A Tool to Understand and Control Chemical Reactions; Introduction; Experimental principle; REACTION IN VAN DER WAALS COMPLEXES.; I. Preparation of the complex; i) The entrance channel:; ii) The final states.

iii) The intermediate state of reaction.The van der Waals technique as a probe for a harpoon type chemical reaction; Two-photon excitation.; VUV excitation of the Xe-Cl2 complex: symmetry selection on the exit channel; Charge transfer mechanism in a T shaped Xe-Cl2 complex; Femto second investigation of the Xe-Cl2 reactive complex (73).; REACTION IN IONIC COMPLEXES; Ionic nucleophilic substitution reaction in halogenated benzene-NH3 complexes; Results; SIZE EFFECT IN NUCLEOPHILIC SUBSTITUTION; Conclusions; REFERENCES; PART THREE Photofragmentation of Weakly Bound Complexes

Photofragmentation of Weakly Bound Complexes1 Introduction; 2 One-atom cage effect; 3 Complex induced electronic predissociation; 3.1 Golden rule wave packet treatment of electronic predissociation; 4 Discussion and conclusions; References; PART FOUR Off-Resonant Fifth and Seventh Order Time-Domain Nonlinear Spectroscopy on Vibrational Dephasing in Liquids; Off-Resonant Fifth and Seventh Order Time-Domain Nonlinear Spectroscopy on Vibrational Dephasing in Liquids; Abstract; 1. Introduction; 2. Vibrational Dephasing; 2.1. Introduction; 2.2. Stochastic Theory for Vibrational Lineshape

Homogeneous and Inhomogeneous Broadening3. Basic Theory of Nonlinear Spectroscopy; 3.1. Quantum Electrodynamics and Nonlinear Spectroscopy; 3.2. Nonlinear Response Function; 3.3. Third Order Nonlinear Response Function; 4. Coherent Anti-Stokes Raman Scattering (Third Order); 5. Raman Echo (Seventh Order); 5.1. Introduction; 5.2. Time Profile of the Raman Echo Signal; 5.3. Examples of the Raman Echo and IR Photon Echo Signals; 6. One- and Two-Dimensional Overtone Vibrational Dephasing (Fifth Order); 6.1. Introduction; 6.2. Time Profiles of the Overtone Signals

6.3. One-Dimensional Overtone Dephasing

Notes:

Description based upon print version of record.

Includes bibliographical references.

ISBN:

9789812798435

9812798439

OCLC:

922951797