Trends in polyoxometalates research / Laurent Ruhlmann and Delphine Schaming, editors.

Format:

Book

Contributor:

Ruhlmann, Laurent, 1967- editor.

Schaming, Delphine, 1983- editor.

Series:

Chemistry research and applications series.

Chemistry Research and Applications

Language:

English

Subjects (All):

Polyoxometalates.

Metallic oxides.

Physical Description:

1 online resource (456 p.)

Place of Publication:

New York, [New York] : Nova Publishers, 2015.

Language Note:

English

Summary:

The book attempts to make available the recent developments in polyoxometalate (POM) synthesis. The focus centralizes on the functionalization of POMs with covalently organic moiety (for instance, the use of exogenous ligands such as carboxylate or bisphosphonate). It also delves into the development of lanthanide POMs, or the formation of blackberry-like assemblies. Likewise, the properties (redox properties, magnetism, etc...), and its applications (homogeneous and heterogeneous catalysis, photocatalysis, photoelectrocatalysis and photovoltaic cell development, etc.) are also analyzed.This a

Contents:

TRENDS IN POLYOXOMETALATES RESEARCH; TRENDS IN POLYOXOMETALATES RESEARCH; Library of Congress Cataloging-in-Publication Data; CONTENTS; PREFACE; Chapter 1: Controllable Self-Assembly Process of Polyoxometalate Macroions Driven by Counterion Mediated Attraction; ABSTRACT; ABBREVIATIONS; 1. INTRODUCTION; 2. THE SOLUTION BEHAVIOR OF HYDROPHILIC POM MACROIONS; CONCLUSION; REFERENCES; Chapter 2: Building New Polyoxotungstates using Exogeneous Ligands: From Carboxylato to Bisphosphonato Complexes ; ABSTRACT; ABBREVIATIONS; 1. INTRODUCTION; 2. CARBOXYLATE LIGANDS; 3. BISPHOSPHONATE LIGANDS

CONCLUSIONACKNOWLEDGMENTS; REFERENCES; Chapter 3: POM-Based Chiral Hybrids via Organically Covalent Modification of Achiral Precursors ; ABSTRACT; 1. INTRODUCTION; 2. POM-BASED CHIRAL HYBRIDSVIA ORGANOIMIDIZATION; 3. POM-BASED CHIRAL HYBRIDSVIA ORGANOALKOXYLATION; 4. POM-BASED CHIRAL HYBRIDS VIA ORGANOTIN; 5. POM-BASED CHIRAL HYBRIDSVIA ORGANOSILYLATION; 6. POM-BASED CHIRAL HYBRIDSVIA ORGANOPHOSPHONYLATION; CONCLUSION; REFERENCES; Chapter 4: POM Complexes with Noble Metals - New Insights into Synthesis and Reactivity ; ABSTRACT; 1. INTRODUCTION

2. ESI-MS TECHNIQUES FOR MONITORING OF THE REACTIVITY OF NOBLE METAL SITES IN POMS3. COMPLEXES OF IR(III) AND RH(III) WITH [PW11O39]7-; 4. REACTIVITY AT THE NOBLE METAL SITE; 5. NO AND CO-FUNCTIONALIZED RU POM [27, 37]; 6. INCORPORATION OF M-M BONDS ANDPOLYNUCLEAR UNITS INTO RH AND IR POM; 7. PT(II) AND AU(III) COMPLEXES; CONCLUSION; ACKNOWLEDGMENTS; REFERENCES; Chapter 5: SYNTHESIS AND CHARACTERIZATION OF LANTHANOID CONTAINING POLYOXOTUNGSTATES NANOCLUSTER; ABSTRACT; 1. INTRODUCTION; 2. LANTHANOID CONTAINING POLYOXOTUNGSTATES NANOCLUSTERS; CONCLUSION; REFERENCES

Chapter 6: POLYOXOMETALATE-BASED SINGLE MOLECULE MAGNETSABSTRACT; ABBREVIATIONS; 1. INTRODUCTION; 2. SINGLE-MOLECULE MAGNETS BASED ON MULTINUCLEAR TRANSITION METAL MAGNETIC CORES AND POLYOXOTUNGSTATE OR POLYOXOMOLYBDATE LIGANDS; 3. HYBRID ASSEMBLIES CONTAINING CATIONIC TRANSITION METAL-BASED MAGNETIC UNITS AND POM COUNTERCATIONS; CONCLUSION; ACKNOWLEDGMENTS; REFERENCES; Chapter 7: SMALL ANGLE X-RAY SCATTERING OF GROUP V POLYOXOMETALATES; ABSTRACT; 1. INTRODUCTION; 2. SMALL ANGLE X-RAY SCATTERING; 3. SAXS STUDIES OF POM SYSTEMS; 4. SIMULATING SAXS DATA; CONCLUSION; REFERENCES

Chapter 8: POLYOXOMETALATE REACTIVITY TOWARD BIOMOLECULES AND THEIR MODEL SYSTEMSABSTRACT; 1. INTRODUCTION; 2. HYDROLYSIS OF NUCLEOTIDES AND NUCLEIC ACID MODEL SYSTEMS; 3. HYDROLYSIS OF CARBOXYESTERS; 4. CLEAVAGE OF DIPEPTIDES, OLIGOPEPTIDES AND PROTEINS; 5. HYDROLYSIS OF DI- AND POLYSACCHARIDES; CONCLUSION; REFERENCES; Chapter 9: POLYXOMETALATE-CONTAINING HYBRID DIBLOCK COPOLYMERS: SYNTHESIS MORPHOLOGY, AND APPLICATIONS; ABSTRACT; ABBREVIATIONS; 1. INTRODUCTION; 2. COIL-COIL HYBRID DIBLOCK COPOLYMERS; 3. ROD-COIL HYBRID DIBLOCK COPOLYMERS; CONCLUSION; REFERENCES

Chapter 10: POLYOXOMETALATES ASSOCIATED WITH PORPHYRINS USED AS EFFICIENT VISIBLE PHOTOSENSITIZERS

Notes:

Description based upon print version of record.

Includes bibliographical references at the end of each chapters and index.

Description based on print version record.

ISBN:

1-63482-693-0