Kinetic and thermodynamic stability of cerium (IV) complexes with a series of aliphatic organic compounds / Olga Voskresenskaya.

Format:

Book

Author/Creator:

Voskresenskaia, O. O. (Olga Olegovna)

Series:

Chemistry research and applications series.

Chemistry Research and Applications

Language:

English

Subjects (All):

Complex compounds.

Cerium compounds--Stability.

Cerium compounds.

Aliphatic compounds.

Physical Description:

1 online resource (185 p.)

Place of Publication:

New York : Nova Publishers, c2013.

Language Note:

English

Summary:

An approach to the investigation of the thermodynamic and kinetic stability of variable-valence metal complexes has been developed. Concepts of the generalized inverse problems of quantitative instrumental analysis and the complex formation equilibria are introduced. The procedure for this investigation is regarded as a sequential procedure for solving these two inverse problems. The classical methods for investigating the complex formations in solution are analyzed in terms of these in-verse problems. Their generalizations are given to determine together with the formation constants also redo

Contents:

""KINETIC AND THERMODYNAMIC STABILITY OF CERIUM(IV) COMPLEXES WITH A SERIES OF ALIPHATIC ORGANIC COMPOUNDS""; ""KINETIC AND THERMODYNAMIC STABILITY OF CERIUM(IV) COMPLEXES WITH A SERIES OF ALIPHATIC ORGANIC COMPOUNDS""; ""LIBRARY OF CONGRESS CATALOGING-IN-PUBLICATION DATA""; ""CONTENTS""; ""PREFACE""; ""ABSTRACT""; ""Chapter 1: INTRODUCTION""; ""1. Applications of Tetravalent Cerium Compounds""; ""2. Investigations of Interaction between Cerium(IV) and Organic Ligands""; ""3. Generalized Methods for Investigating Complexes Stability in Terms of Inverse and Direct Problems""; ""References""

""Chapter 2: METHODS FOR INVESTIGATION OF THERMODYNAMIC AND KINETIC STABILITY OF CERIUM(IV) COMPLEXES""""1. Classical Methods for Investigating the Complex Formation""; ""2. Possibility of Kinetic Modifications for Classical Thermodynamic Methods""; ""3. Benesi�Hildebrand�Ardon Method and Its Modifications""; ""4. Thermodynamic Methods for Studying Thermodynamic and Kinetic Stability of Complexes with Cations in an Unstable OS""; ""5. Kinetic Methods for Solving Inverse Problem of Complex Formation""

""6. Further Generalizations of the Methods for Investigating the Thermodynamic and Kinetic Stability of Complexes with Cations in an Unstable OS""""References""; ""Chapter 3: INVESTIGATING STABILITY OF CERIUM(IV) COMPLEXES WITH SOME ALIPHATIC ORGANIC COMPOUNDS""; ""1. Experiment and Calculations""; ""2. Thermodynamic and Kinetic Stability of Cerium(IV) Complexes with Some Dicarboxylic Acids""; ""3. Formation and Intracomplex Redox Decomposition of Cerium(IV) Complexes With a Series of Oxycarboxylic Acids""

""4. Thermodynamic and Kinetic Stability of Cerium(IV) Complexes with Some Polyatomic Alcohols""""References""; ""Chapter 4: A COMPARATIVE STUDY OF THE INVESTIGATED SYSTEMS""; ""1. Spectroscopic Evidence for Existence of Intermediate Complexes""; ""2. Stoichiometry""; ""3. Stability Constants of the Complexes""; ""4. Intracomplex Redox Decomposition Rate Constants and Activation Energies""; ""5. Correlation between Thermodynamic and Kinetic Stability of the Complexes""; ""6. Reaction Order, Rate Law and Mechanism""; ""7. Detailed Mechanism for Systems with Two Intermediates""

""8. Some Computational Aspects""""9. Conclusion""; ""References""; ""INDEX""

Notes:

Description based upon print version of record.

Description based on online resource; title from title page (ebrary, viewed August 24, 2013).

Includes bibliographical references at the end of each chapters and index.

ISBN:

1-62618-958-7

OCLC:

855534386