High resolution NMR : theory and chemical applications / Edwin D. Becker.

Format:

Book

Author/Creator:

Becker, Edwin D.

Language:

English

Subjects (All):

Nuclear magnetic resonance spectroscopy.

Nuclear spectroscopy.

Physical Description:

1 online resource (441 p.)

Edition:

3rd. ed.

Place of Publication:

San Diego, CA : Academic Press, c2000.

Language Note:

English

Summary:

High Resolution NMR provides a broad treatment of the principles and theory of nuclear magnetic resonance (NMR) as it is used in the chemical sciences. It is written at an ""intermediate"" level, with mathematics used to augment, rather than replace, clear verbal descriptions of the phenomena. The book is intended to allow a graduate student, advanced undergraduate, or researcher to understand NMR at a fundamental level, and to see illustrations of the applications of NMR to the determination of the structure of small organic molecules and macromolecules, including proteins. Emphasis

Contents:

Front Cover; High Resolution NMR: Theory and Chemical Applications; Copyright Page; Contents; Preface to the Third Edition; Chapter 1. Introduction; 1.1 Origins and Early History of NMR; 1.2 High Resolution NMR: An Overview; 1.3 Additional Reading and Resources; Chapter 2. The Theory of NMR; 2.1 Nuclear Spin and Magnetic Moment; 2.2 Theoretical Descriptions of NMR; 2.3 Steady-State Quantum Mechanical Description; 2.4 Effect of the Boltzmann Distribution; 2.5 Spin-Lattice Relaxation; 2.6 Precession of Nuclear Magnetic Moments; 2.7 Classical Mechanical Description of NMR

2.8 Magnetization in the Rotating Frame2.9 Methods of Obtaining NMR Spectra; 2.10 Dynamic Processes; 2.11 Terminology, Symbols, Units, and Conventions; 2.12 Additional Reading and Resources; 2.13 Problems; Chapter 3. Instrumentation and Techniques; 3.1 Advantages of Pulse Fourier Transform NMR; 3.2 Basic NMR Apparatus; 3.3 Requirements for High Resolution NMR; 3.4 Detection of NMR Signals; 3.5 Phase Cycling; 3.6 Fourier Transformation of the FID; 3.7 Data Acquisition; 3.8 Data Processing; 3.9 Digital Filtering; 3.10 Alternatives to Fourier Transformation; 3.11 Sensitivity and Size of Sample

3.12 Useful Solvents3.13 Additional Reading and Resources; 3.14 Problems; Chapter 4. Chemical Shifts; 4.1 The Origin of Chemical Shifts; 4.2 Theory of Chemical Shifts; 4.3 Measurement of Chemical Shifts; 4.4 Empirical Correlations of Chemical Shifts; 4.5 Some Aspects of Proton Chemical Shifts; 4.6 Nuclei Other Than Hydrogen; 4.7 Compilations of Spectral Data and Empirical Estimates of Chemical Shifts; 4.8 Isotope Effects; 4.9 Effects of Molecular Asymmetry; 4.10 Paramagnetic Species; 4.11 Additional Reading and Resources; 4.12 Problems; Chapter 5. Coupling between Pairs of Spins

5.1 Origin of Spin Coupling Interactions5.2 General Aspects of Spin-Spin Coupling; 5.3 Theory of Spin-Spin Coupling; 5.4 Correlation of Coupling Constants with Other Physical Properties; 5.5 Effect of Exchange; 5.6 Spin Decoupling and Double Resonance; 5.7 Additional Reading and Resources; 5.8 Problems; Chapter 6. Structure and Analysis of Complex Spectra; 6.1 Symmetry and Equivalence; 6.2 Notation; 6.3 Energy Levels and Transitions in an AX System; 6.4 Quantum Mechanical Treatment; 6.5 The Two-Spin System without Coupling; 6.6 Factoring the Secular Equation; 6.7 Two Coupled Spins

6.8 The AB Spectrum6.9 AX, AB, and A2 Spectra; 6.10 ""First-Order"" Spectra; 6.11 Symmetry of Spin Wave Functions; 6.12 General Procedures for Simulating Spectra; 6.13 Three-Spin Systems; 6.14 Relative Signs of Coupling Constants; 6.15 Some Consequences of Strong Coupling and Chemical Equivalence; 6.16 ""Satellites"" from Carbon-13 and Other Nuclides; 6.17 The AA'BB' and AA'XX' Systems; 6.18 Additional Reading and Resources; 6.19 Problems; Chapter 7. Spectra of Solids; 7.1 spin Interactions in Solids; 7.2 Dipolar Interactions; 7.3 ""Scalar Coupling""; 7.4 The Heteronuclear Two-Spin System

7.5 Dipolar Decoupling

Notes:

Description based upon print version of record.

Includes bibliographical references and index.

ISBN:

1-281-01971-2

9786611019716

0-08-050806-5

OCLC:

173517687