Sustainable and Functional Redox Chemistry / edited by Shinsuke Inagi.

Format:

Book

Contributor:

Inagi, Shinsuke, editor.

Series:

ISSO (Series)

Issn Series

Language:

English

Subjects (All):

Green chemistry.

Oxidation-reduction reaction.

Physical Description:

1 online resource (403 pages)

Edition:

First edition.

Place of Publication:

London, England : The Royal Society of Chemistry, [2022]

Summary:

This book represents a compilation of the latest advancements in functional redox chemistry and demonstrates its importance in achieving a more sustainable future. This book is an ideal companion for any postgraduate students or researchers interested in sustainability in academia and industry.

Contents:

Cover

Preface

Contents

Part 1 Sustainable Redox Reaction

Chapter 1 Redox-mediated Electrochemical Cyclization Reactions

1.1 Introduction

1.2 Radical Cyclization Reactions

1.2.1 Cyclization Reactions of Heteroatom-centered Radicals

1.2.2 Cyclization Reactions of Carbon-centered Radicals

1.3 Halide-mediated Ionic Cyclization Reactions

1.4 Conclusion

Acknowledgements

References

Chapter 2 Recent Advances in the Kolbe and Non-Kolbe Electrolysis of Carboxylic Acids

2.1 Introduction

2.2 Background of the Kolbe Electrolysis

2.3 Background of Non-Kolbe Electrolysis

2.4 Recent Advances in the Electrolysis of Carboxylic Acids

2.4.1 Kolbe Intramolecular Cyclisation

2.4.2 Hofer-Moest Synthesis of Isocyanates

2.4.3 Hofer-Moest Synthesis of Orthoesters

2.4.4 Electrochemical Methoxylation

2.4.5 Electrochemical Decarboxylation of Malonic Acid Derivatives

2.5 Recent Advances in the Electrolysis of Carboxylic Acid Derivatives

2.5.1 Electrochemical Deprotection of Aromatic Esters

2.5.2 Electrochemical Deoxygenation of Diphenylphosphinates

2.6 Future Perspectives

2.7 Conclusion

Abbreviations

Chapter 3 Novel Electrolytic Processes

3.1 Introduction

3.2 Parallel Batch Systems Used for Electroorganic Synthesis

3.2.1 Parallel Batch Systems Using the Cation Pool Method

3.2.2 Parallel Batch Processes for Electrosynthesis

3.3 Combinatorial Flow System for Electroorganic Chemistry

3.3.1 Flow Electrochemistry

3.3.2 PEM Reactor

3.4 Bipolar Electrochemical System

3.5 Conclusion

Chapter 4 A Sugar Machine

4.1 Introduction

4.2 Electrochemical Generation of Glycosylation Intermediates

4.2.1 Generation of Glycosyl Triflate Intermediates

4.2.2 Generation of Glycosyl Sulfonium Ion Intermediates.

4.3 Development of a Method for AutomatedElectrochemical Solution-phase Synthesis of Oligosaccharides

4.3.1 Proof of Principle of One-pot Iterative Glycosylation

4.3.2 Demonstration of Automated Electrochemical Assembly of Oligosaccharides

4.4 Synthesis of Biologically Active Oligosaccharides

4.4.1 Synthesis of TMG-chitotriomycin

4.4.2 Synthesis of Myc-LCOs

4.5 Synthesis of 1,2-trans Glycosidic Linkages of Hexoses via Automated Electrochemical Assembly

4.6 Synthesis of Cyclic Oligosaccharides via Automated Electrochemical Assembly

4.7 Conclusion

Part 2 Sustainable Redox Catalysis

Chapter 5 Vanadium( V)-induced Oxidative Cross-coupling of Enolate Species

5.1 Introduction

5.2 Oxovanadium( V)-induced Intermolecular SelectiveOxidative Cross-coupling between Boron and Silyl Enolates

5.3 Oxidative Cross-coupling between Various Boron and Silyl Enolates

5.4 Oxovanadium( V)-catalyzed Oxidative Cross-couplingbetween Boron and Silyl Enolates under O2 as a Terminal Oxidant

5.5 Conclusion

Chapter 6 Mediated Electron Transfer in Electrosynthesis: Concepts,Applications, and Recent Influences from Photoredox Catalysis

Robert Francke and Michal Ma´ jek 6.1 Introduction

6.2 Concepts and Applications

6.2.1 Direct and Indirect Electrosynthesis

6.2.2 The Catalytic Current

6.2.3 Redox Catalysis and Chemical Catalysis

6.2.4 In-cell-and Ex-cell-mediated Transformations

6.3 Approaches Toward Facilitating Mediator Recycling

6.3.1 Ionically Tagged Mediators

6.3.2 Polymediators

6.3.3 Mediator-modified Electrodes

6.4 Mediators in Photoelectrochemical Synthesis

6.4.1 Transformations at Photoelectrodes

6.4.2 Sequential Activation of Substrates by Electro-and Photochemistry.

6.4.3 Enhancing Mediator Reactivity with Light

6.5 Conclusions

Chapter 7 Synergy of Electrochemistry and Asymmetric Catalysis

7.1 Introduction

7.2 Substrates as the Redox Entities in Electrochemical Asymmetric Catalysis

7.3 Catalysts as Redox Entities in Electrochemical Asymmetric Catalysis

7.4 Both Substrates and Catalysts as the Redox Entities in Electrochemical Asymmetric Catalysis

7.5 Conclusion

Chapter 8 Alternative Approaches for Scalable Artificial Photosynthesis via Sustainable Redox Processes

8.1 Introduction

8.2 Nonfood Biomass Oxidation

8.2.1 Photocatalytic Nonfood Biomass Oxidation

8.2.2 Electrocatalytic and Photoelectrocatalytic Nonfood Biomass Oxidation

8.3 Synthetic Polymer Oxidation

8.3.1 Heterogeneous Photocatalytic Oxidation of Synthetic Polymers

8.3.2 Homogeneous Photocatalytic Oxidation of Synthetic Polymers

8.4 Photosynthetic and Photocatalytic Reduction by Metal Halide Perovskites

8.5 Conclusions and Outlook

Chapter 9 Bioinspired Catalyst Learned from B12-dependent Enzymes

9.1 Introduction

9.1.1 B12 (Cobalamin)-dependent Enzymes

9.1.2 Catalyst Design for B12-dependent Enzyme-inspired Reactions

9.2 Photo-driven Molecular Transformation

9.2.1 Heterogeneous Catalyst System

9.2.2 Esters and Amides Formation Coupled with Dehalogenation

9.2.3 Visible Light-driven Catalytic System

9.2.4 B12-inspired Hydrogen Production and Alkene Reduction

9.2.5 Homogeneous Catalyst System

9.2.6 Cross-coupling Reactions

9.2.7 B12-BODIPY Dyad System

9.2.8 Catalysis of B12 Without Photocatalyst

9.3 Summary and Outlook

Part 3 Functional Redox System

Chapter 10 Redox-active Molecules and Their Energy Device Application.

10.1 Introduction

10.2 Organic Active Materials for Li-ion Batteries

10.2.1 Basic Concepts

10.2.2 Capacity Increase

10.2.3 Cyclability Increase

10.2.4 Voltage Increase

10.3 Organic Active Materials for Redox Flow Batteries

10.3.1 Aqueous Electrolyte

10.3.2 Nonaqueous Electrolyte

Chapter 11 Redox-active Polymeric Materials

11.1 Introduction

11.2 Conjugated Polymers

11.2.1 Doping of Conjugated Polymers

11.2.2 Oxidative and Reductive Electropolymerization

11.2.3 Electrochemical Polymer Reaction

11.2.4 Two-and Three-dimensional Conjugated Polymers

11.3 Nonconjugated Polymers with Redox-active Units

11.3.1 Polymers with Redox-active Units in the Side Chain

11.3.2 Block Copolymers with Redox-active Units

11.3.3 Polymeric Materials Mimicking Metalloproteins

11.3.4 Redox Units at the Periphery of Dendrimers

11.3.5 Redox-active Inorganic Polymers

11.4 Conjugated Polymers with Redox-active Moieties

11.5 Conclusion

Chapter 12 Chiral Metal Electrodes for Enantioselective Analysis, Synthesis, and Separation

12.1 Background

12.2 Elaboration of Chiral Metal Electrodes

12.2.1 Adsorption of Chiral/Achiral Molecules on Metal Surfaces

12.2.2 Binding of Chiral Ligands toMetal Surfaces

12.2.3 Controlled Cutting of Bulk Metals

12.2.4 Chiral Molecular Imprinting

12.3 Applications of Chiral Metal Electrodes

12.3.1 Enantioselective Analysis

12.3.2 Asymmetric Synthesis

12.3.3 Electrochemical Separation

12.4 Conclusion and Perspectives

Chapter 13 Fluorescent Sensors for Water

13.1 Introduction

13.2 PET-based Fluorescent Sensors

13.3 PET/FRET-based Fluorescent Sensors

13.4 PET/AIEE-based Fluorescent Sensors

13.5 SFC/AIEE-based Fluorescent Sensors

13.6 ICT-based Fluorescent Sensors.

13.7 Fluorescent Sensor-doped Polymer Films

13.8 Conclusion

Chapter 14 Photoredox Chemistries of Cyclometalated Ir( III) Complexes

14.1 Photoinduced Electron Transfer of Cyclometalated Ir( III) Complex

14.2 Electronic Structures of Cyclometalated Complexes of Ir( III)

14.3 Sensory Applications of IntramolecularPhotoinduced Electron Transfer of Ir( III) Complexes

14.4 Photoredox Catalysis Based on IntermolecularPhotoinduced Electron Transfer of Ir( III) Complexes

14.5 Outlook

Chapter 15 Electrogenerated Chemiluminescence in Functional Redox Chemistry

15.1 Introduction

15.2 Fundamentals of ECL: Mechanisms of Light Generation

15.2.1 Annihilation ECL

15.2.2 Coreactant ECL

15.3 Applications of ECL in Molecular Electrochemistry

15.3.1 Novel ECL Reaction Systems

15.3.2 ECL for Imaging Applications

15.3.3 ECL of Organic Systems

15.3.4 Aggregation and Crystallization-induced Emission in ECL

15.4 Conclusions and Future Directions

Subject Index.

Notes:

Description based on publisher supplied metadata and other sources.

Description based on print version record.

Includes bibliographical references.

Other Format:

Print version: Inagi, Shinsuke Sustainable and Functional Redox Chemistry

ISBN:

9781839164828