The lanthanides and actinides : synthesis, reactivity, properties and applications / editors, Stephen T. Liddle, David P. Mills, Louise S. Natrajan, The University of Manchester, UK.

Format:

Book

Contributor:

Liddle, Stephen T. (Stephen Taylor), editor.

Mills, David P., editor.

Natrajan, Louise S., editor.

Alumni and Friends Memorial Book Fund.

Language:

English

Subjects (All):

Rare earth metals.

Actinide elements.

Metals, Rare Earth.

Actinoid Series Elements.

Medical Subjects:

Metals, Rare Earth.

Actinoid Series Elements.

Physical Description:

xxi, 704 pages : illustrations ; 24 cm

Place of Publication:

London ; Hackensack, NJ : World Scientific Publishing Co. Pte. Ltd, [2022]

Summary:

"The Lanthanides and Actinides: Synthesis, Reactivity, Properties and Applications constitutes an introduction to and comprehensive coverage of f-block chemistry encompassing the following areas: periodicity, natural occurrence and extraction, separations, electronic structure, coordination chemistry, organometallic chemistry, small molecule activation, catalysis, organic synthesis applications, magnetism, spectroscopy, computation, materials, photonics, solar cell technology, biological imaging, and technological applications. Under these subject areas the book provides a broad but deep coverage, providing basic overviews as well as detailed chapters on specific areas. This book, targeted at academics, postgraduates and advanced undergraduates, will serve as an ideal introductory text and key reference work to the Lanthanides and Actinides"-- Provided by publisher.

Contents:

Machine generated contents note: 1.1. Introduction: The Rare-Earth Elements / Thomas Behrsing / Glen B. Deacon / Peter Junk

1.2. General Properties / Thomas Behrsing / Glen B. Deacon / Peter Junk

1.3. Discovery, Location and Abundance of Rare Earths / Thomas Behrsing / Glen B. Deacon / Peter Junk

1.4. Uses of the Rare Earths / Thomas Behrsing / Glen B. Deacon / Peter Junk

1.5. General Chemistry Properties of Rare-Earth Elements and Compounds / Thomas Behrsing / Glen B. Deacon / Peter Junk

References / Thomas Behrsing / Glen B. Deacon / Peter Junk

2.1. Discovery and Synthesis of the Actinide Elements / Robert J. Baker

2.2. Occurrence and Extraction / Robert J. Baker

2.3. Periodicity, Electronic Configuration and Oxidation States / Robert J. Baker

2.4. Structure and Bonding / Robert J. Baker

References / Robert J. Baker

3.1. Introduction / Matthew L. Marsh / Frankie D. White / Wesley M. Potter / Thomas E. Albrecht-Schoenzart

3.2. Intermetallics, Oxides and Hydroxides / Matthew L. Marsh / Frankie D. White / Wesley M. Potter / Thomas E. Albrecht-Schoenzart

3.3. Halides / Matthew L. Marsh / Frankie D. White / Wesley M. Potter / Thomas E. Albrecht-Schoenzart

3.4. Oxyanions / Matthew L. Marsh / Frankie D. White / Wesley M. Potter / Thomas E. Albrecht-Schoenzart

3.5. Summary / Matthew L. Marsh / Frankie D. White / Wesley M. Potter / Thomas E. Albrecht-Schoenzart

References / Matthew L. Marsh / Frankie D. White / Wesley M. Potter / Thomas E. Albrecht-Schoenzart

4.1. Introduction / Yaofeng Chen

4.2. Coordination Numbers / Yaofeng Chen

4.3. Complexes / Yaofeng Chen

References / Yaofeng Chen

5.1. Introduction / Gregory Nocton / Marinella Mazzanti

5.2. Aqua Ions / Gregory Nocton / Marinella Mazzanti

5.3. Common Precursors / Gregory Nocton / Marinella Mazzanti

5.4. Uranyl(VI) Complexes / Gregory Nocton / Marinella Mazzanti

5.5. Actinyl(V) and Cation-Cation Interactions / Gregory Nocton / Marinella Mazzanti

5.6. Non-Actinyl Complexes of Actinides in High Oxidation State (VI and V) / Gregory Nocton / Marinella Mazzanti

5.7. Complexes of AnII, AnIII, and AnIV / Gregory Nocton / Marinella Mazzanti

5.8. Actinide Complexes Containing Multiply Bonded Atoms / Gregory Nocton / Marinella Mazzanti

5.9. Conclusions / Gregory Nocton / Marinella Mazzanti

References / Gregory Nocton / Marinella Mazzanti

6.1. Introduction / Wenliang Huang / Paula L. Diaconescu

6.2. Organometallic Chemistry of Lanthanide Ions in Unconventional Oxidation States / Wenliang Huang / Paula L. Diaconescu

6.3. Lanthanide Complexes Containing Ln-C σ-Bonds / Wenliang Huang / Paula L. Diaconescu

6.4. Lanthanide π-Complexes Containing Carbocyclic and Acyclic π-Ligands / Wenliang Huang / Paula L. Diaconescu

6.5. Lanthanide Carbene Complexes / Wenliang Huang / Paula L. Diaconescu

6.6. Summary and Outlook for the Organometallic Chemistry of Lanthanides / Wenliang Huang / Paula L. Diaconescu

References / Wenliang Huang / Paula L. Diaconescu

7.1. Introduction / David J.H. Emslie / Nicholas R. Andreychuk / Carlos A. Cruz

7.2. Anhydrous Halide, Triflate, Amido and Aryloxide Starting Materials / David J.H. Emslie / Nicholas R. Andreychuk / Carlos A. Cruz

7.3. Homoleptic Hydride, Borohydride, Aluminohydride, and Aminodiboronate Complexes and Their Lewis Base Adducts / David J.H. Emslie / Nicholas R. Andreychuk / Carlos A. Cruz

7.4. Homoleptic Acyclic Hydrocarbyl Compounds and Their Lewis Base Adducts / David J.H. Emslie / Nicholas R. Andreychuk / Carlos A. Cruz

7.5. Ligand Attachment Protocols for the Synthesis of Heteroleptic Compounds / David J.H. Emslie / Nicholas R. Andreychuk / Carlos A. Cruz

7.6. Cyclopentadienyl Actinide Complexes / David J.H. Emslie / Nicholas R. Andreychuk / Carlos A. Cruz

7.7. Organoactinide Complexes Bearing Non-Cyclopentadienyl π-Ligands / David J.H. Emslie / Nicholas R. Andreychuk / Carlos A. Cruz

7.8. Neutral and Anionic Non-Cyclopentadienyl Hydrocarbyl Complexes / David J.H. Emslie / Nicholas R. Andreychuk / Carlos A. Cruz

7.9. Neutral and Anionic Hydride Complexes / David J.H. Emslie / Nicholas R. Andreychuk / Carlos A. Cruz

7.10. Cationic Alkyl and Related Complexes / David J.H. Emslie / Nicholas R. Andreychuk / Carlos A. Cruz

7.11. Carbene Complexes / David J.H. Emslie / Nicholas R. Andreychuk / Carlos A. Cruz

7.12. Cyanide, Carbonyl and Isonitrile Compounds / David J.H. Emslie / Nicholas R. Andreychuk / Carlos A. Cruz

7.13. Agostic Interactions and Metal-Alkane Coordination / David J.H. Emslie / Nicholas R. Andreychuk / Carlos A. Cruz

References / David J.H. Emslie / Nicholas R. Andreychuk / Carlos A. Cruz

8.1. Introduction and Scope of the Review / Conrad A.P. Goodwin / David P. Mills

8.2. CO Reactivity / Conrad A.P. Goodwin / David P. Mills

8.3. CO2/CS2/COS Reactivity / Conrad A.P. Goodwin / David P. Mills

8.4. CH4 Reactivity / David P. Mills / Conrad A.P. Goodwin

8.5. N2 Reactivity / Conrad A.P. Goodwin / David P. Mills

8.6. NOx Reactivity / Conrad A.P. Goodwin / David P. Mills

8.7. RN3 Reactivity / Conrad A.P. Goodwin / David P. Mills

8.8. Ce(IV) Reactivity / David P. Mills / Conrad A.P. Goodwin

8.9. Summary / David P. Mills / Conrad A.P. Goodwin

References / Conrad A.P. Goodwin / David P. Mills

9.1. Introduction and Scope of the Review / Karsten Meyer / Christopher Hoerger

9.2. Carbon Monoxide / Christopher Hoerger / Karsten Meyer

9.3. Carbon Dioxide / Christopher Hoerger / Karsten Meyer

9.4. Nitric and Nitrous Oxide / Christopher Hoerger / Karsten Meyer

9.5. Dinitrogen / Christopher Hoerger / Karsten Meyer

9.6. Water / Christopher Hoerger / Karsten Meyer

9.7. Azides / Christopher Hoerger / Karsten Meyer

References / Christopher Hoerger / Karsten Meyer

10.1. General / Rami J. Batrice / Moris S. Eisen / Guy Yardeni / Isabell S.R. Karmel

10.2. Introduction / Guy Yardeni / Isabell S.R. Karmel / Rami J. Batrice / Moris S. Eisen

10.3. Catalytic Reactions of Alkynes / Rami J. Batrice / Moris S. Eisen / Guy Yardeni / Isabell S.R. Karmel

10.4. Catalytic Synthesis of Esters from Aldehydes / Rami J. Batrice / Isabell S.R. Karmel / Guy Yardeni / Moris S. Eisen

10.5. Catalytic Addition of Protic Nucleophiles to Heterocumulenes / Rami J. Batrice / Isabell S.R. Karmel / Moris S. Eisen / Guy Yardeni

10.6. Dehydrocoupling of Silanes and Amines / Moris S. Eisen / Rami J. Batrice / Isabell S.R. Karmel / Guy Yardeni

10.7. Uranium-Catalyzed Reduction of Azides and Hydrazines / Guy Yardeni / Moris S. Eisen / Rami J. Batrice / Isabell S.R. Karmel

10.8. Other Catalytic Reactions / Guy Yardeni / Isabell S.R. Karmel / Rami J. Batrice / Moris S. Eisen

10.9. Actinide-Catalyzed Polymerization Reactions / Rami J. Batrice / Isabell S.R. Karmel / Moris S. Eisen / Guy Yardeni

10.10. Uranium-Catalyzed Electrocatalytic Production of Dihydrogen from Water and Coupling of Carbon Monoxide / Rami J. Batrice / Guy Yardeni / Isabell S.R. Karmel / Moris S. Eisen

10.11. Reductive Homologation and Functionalization of Carbon Monoxide / Guy Yardeni / Isabell S.R. Karmel / Rami J. Batrice / Moris S. Eisen

10.12. Conclusions / Guy Yardeni / Isabell S.R. Karmel / Rami J. Batrice / Moris S. Eisen

Acknowledgments / Guy Yardeni / Isabell S.R. Karmel / Rami J. Batrice / Moris S. Eisen

References / Rami J. Batrice / Isabell S.R. Karmel / Guy Yardeni / Moris S.

Eisen

11.1. Introduction / Andrew Kerridge

11.2. Simulation Methodologies / Andrew Kerridge

11.3. Summary and Outlook / Andrew Kerridge

References / Andrew Kerridge

12.1. General / Joris van Slageren / Yvonne Rechkemmer

12.2. EXAFS / Joris van Slageren / Yvonne Rechkemmer

12.3. XANES / Joris van Slageren / Yvonne Rechkemmer

12.4. XMD / Joris van Slageren / Yvonne Rechkemmer

12.5. High Resolution X-ray Absorption, High-Energy-Resolution Fluorescence-Detection X-ray Absorption Spectroscopy and Resonant Inelastic X-ray Scattering Spectroscopy / Joris van Slageren / Yvonne Rechkemmer

12.6. XPS / Yvonne Rechkemmer / Joris van Slageren

References / Yvonne Rechkemmer / Joris van Slageren

13.1. Methods / Yvonne Rechkemmer / Joris van Slageren

13.2. Types of Transitions and Comparison to Lanthanide Systems / Yvonne Rechkemmer / Joris van Slageren

13.3. Actinyl Compounds and Related Systems / Yvonne Rechkemmer / Joris van Slageren

References / Joris van Slageren / Yvonne Rechkemmer

14.1. General / Joris van Slageren / Yvonne Rechkemmer

15.1. General / Joris van Slageren / Yvonne Rechkemmer

16.1. Introduction / Peter Kaden

16.2. NMR Spectroscopy of Actinide Containing Compounds / Peter Kaden

16.3. New Studies of Actinide Complexes / Peter Kaden

16.4. Conclusion and Outlook / Peter Kaden

References / Peter Kaden

17.1. Rare Earths: The Vitamins of High Technology / Jean-Claude G. Bunzli

17.2. Catalysts / Jean-Claude G. Bunzli

17.3. Pigments and Additives for Glass, Ceramic and Leather Industries / Jean-Claude G. Bunzli

17.4. Magnets / Jean-Claude G. Bunzli

17.5. Metallurgy, Alloys and Compounds / Jean-Claude G. Bunzli

17.6. Ceramics / Jean-Claude G. Bunzli

Contents note continued: 17.7. Photonics (Phosphors) / Jean-Claude G. Bunzli

17.8. Applications in Biosciences / Jean-Claude G. Bunzli

17.9. Agriculture and Feed for Livestock / Jean-Claude G. Bunzli

17.10. Energy-Related and Futuristic Applications / Jean-Claude G. Bunzli

17.11. Summary of Applications per Rare-Earth Element / Jean-Claude G. Bunzli

Further Reading / Jean-Claude G. Bunzli

References / Jean-Claude G. Bunzli

18.1. Basic Properties / Louise S. Natrajan / Mark J. Sarsfield / Jean-Claude G. Bunzli

18.2. Applications of Actinides: Summary / Jean-Claude G. Bunzli / Louise S. Natrajan / Mark J. Sarsfield

18.3. Metallurgy and Metals / Louise S. Natrajan / Jean-Claude G. Bunzli / Mark J. Sarsfield

18.4. Photonic Applications / Jean-Claude G. Bunzli / Louise S. Natrajan / Mark J. Sarsfield

18.5. Tracers for Dating / Jean-Claude G. Bunzli / Louise S. Natrajan / Mark J. Sarsfield

18.6. Semi-Conductor Properties / Louise S. Natrajan / Jean-Claude G. Bunzli / Mark J. Sarsfield

18.7. Actinides in Catalysis / Jean-Claude G. Bunzli / Louise S. Natrajan / Mark J. Sarsfield

18.8. Radioactive Sources / Jean-Claude G. Bunzli / Louise S. Natrajan / Mark J. Sarsfield

18.9. Nuclear Power Generation / Jean-Claude G. Bunzli / Louise S. Natrajan / Mark J. Sarsfield

18.10. Nuclear Weapons / Jean-Claude G. Bunzli / Louise S. Natrajan / Mark J. Sarsfield.

Notes:

Includes bibliographical references.

Local Notes:

Acquired for the Penn Libraries with assistance from the Alumni and Friends Memorial Book Fund.

ISBN:

9781800610156

1800610157

OCLC:

1251740566

Publisher Number:

99990839955