Na-ion batteries / edited by Laure Monconduit, Laurence Croguennec.

Format:

Book

Contributor:

Monconduit, Laure, editor.

Croguennec, Laurence, editor.

Language:

English

Subjects (All):

Sodium ion batteries.

Physical Description:

1 online resource (375 pages) : illustrations

Place of Publication:

London, England ; Hoboken, New Jersey : ISTE Ltd. : John Wiley & Sons, Incorporated, [2020]

Summary:

This book covers both the fundamental and applied aspects of advanced Na-ion batteries (NIB) which have proven to be a potential challenger to Li-ion batteries. Both the chemistry and design of positive and negative electrode materials are examined. In NIB, the electrolyte is also a crucial part of the batteries and the recent research, showing a possible alternative to classical electrolytes - with the development of ionic liquid-based electrolytes - is also explored. Cycling performance in NIB is also strongly associated with the quality of the electrode-electrolyte interface, where electrolyte degradation takes place; thus, Na-ion Batteries details the recent achievements in furthering knowledge of this interface. Finally, as the ultimate goal is commercialization of this new electrical storage technology, the last chapters are dedicated to the industrial point of view, given by two startup companies, who developed two different NIB chemistries for complementary applications and markets.

Contents:

Cover

Half-Title Page

Title Page

Copyright Page

Contents

Introduction

I.1. Why Na-ion batteries?

I.2. From the electrodes to the electrolyte for NIBs

I.2.1. Positive electrodes

I.2.2. Negative electrodes

I.2.3. Electrolytes and the solid electrolyte interphase

I.3. Future commercialization of NIBs

I.4. References

1. Layered NaMO2 for the Positive Electrode

1.1. Research history of layered transition metal oxides as electrode materials for Na-ion batteries until 2009

1.2. Crystal structures of layered materials

1.2.1. Crystal structures of synthesizable NaxMO2

1.2.2. Structural changes of O3-NaMO2 by Na extraction

1.2.3. Structural changes of P2-NaxMO2 by Na extraction

1.3. O3-type layered materials

1.3.1. NaMO2 (M = Sc, Ti, V, Cr, Mn, Fe, Co, Ni)

1.3.2. O3-Na[M,M']O2 (M, M' = transition metals)

1.3.3. Moist air stability of O3-NaMO2 and surface coating

1.4. P2-type layered materials

1.4.1. Practical issues of P2-type materials for Na-ion batteries

1.4.2. P2-Na2/3[Mn,Co,M]O2

1.4.3. P2-Na2/3[Mn,Fe,M]O2

1.4.4. P2-Na2/3[Ni,Mn,M]O2

1.5. Summary and prospects

1.6. Acknowledgments

1.7. References

2. Polyanionic-Type Compounds as Positive Electrodes for Na-ion batteries

2.1. Introduction

2.1.1. Oxides and polyanionic frameworks as positive electrodes for sodium ion-batteries

2.1.2. NASICONs and Na3V2(PO4)2F3

2.2. NASICON structures as model frameworks in sodium-ion battery applications

2.2.1. Compositional diversity from solid electrolytes to electrodes

2.2.2. NASICON-typed materials as electrodes for Na batteries

2.2.3. Na3V2(PO4)3 (NVP)

2.3. Na3V2(PO4)2F3 used as a model framework in sodium-ion battery applications

2.3.1. Structural description and compositional diversity.

2.3.2. Na3V2(PO4)2F3: a promising active material for positive electrodes in NIBs

2.3.3. Oxygen substitution in Na3V2(PO4)2F3 and its effects on the electrochemical performance of substituted phases

2.3.4. Paving the way toward Na3V2(PO4)2F3 with superior performance

2.4. Conclusion and perspectives

2.5. References

3. Hard Carbon for Na-ion Batteries: From Synthesis to Performance and Storage Mechanism

3.1. Introduction

3.2. What is a hard carbon?

3.3. Hard carbon synthesis and microstructure

3.3.1. Synthetic precursors-based hard carbon synthesis

3.3.2. Bio-polymers derived hard carbon synthesis

3.3.3. Biomass-based hard carbon synthesis

3.4. Hard carbon characteristics

3.4.1. Hard carbon structure

3.4.2. Hard carbon porosity

3.4.3. Hard carbon surface chemistry

3.4.4. Hard carbon structural defects

3.5. Electrochemical performance

3.5.1. Materials performance

3.5.2. Full Na-ion system performance

3.5.3. Sodium insertion mechanisms in hard carbon

3.6. Conclusion

3.7. References

4. Non-Carbonaceous Negative Electrodes in Sodium Batteries

4.1. Introduction

4.2. Insertion materials

4.2.1. Insertion anodes based on titanium oxide and titanates

4.2.2. Insertion anodes based on transition metal chalcogenides

4.2.3. Insertion MXene-based anodes

4.2.4. Insertion organic anodes

4.3. Negative electrode materials based on electrochemical alloying with sodium

4.3.1. Silicon and germanium

4.3.2. Tin

4.3.3. Phosphorus

4.3.4. Antimony

4.3.5. Other post-transition metal elements

4.4. Negative electrode materials based on conversion reactions

4.4.1. Reaction mechanisms of CM

4.4.2. Approaches toward efficient anode CM for NIB

4.5. Conclusion

4.6. References

5. Electrolytes for Sodium Batteries

5.1. Introduction.

5.2. Liquid and solid electrolytes for sodium batteries

5.2.1. Organic liquid electrolytes

5.2.2. IL-based electrolytes

5.2.3. Hybrid electrolytes

5.2.4. Effects of additives and impurities

5.2.5. Solid-state electrolytes

5.3. Properties of IL-based electrolytes for Na batteries

5.3.1. Physical properties

5.3.2. Thermal stability

5.3.3. Electrochemical stability

5.4. Modeling IL-based electrolytes

5.5. Conclusion and future perspectives

5.6. Abbreviations

5.7. References

6. Solid Electrolyte Interphase in Na-ion batteries

6.1. Introduction

6.1.1. The solid electrolyte interphase

6.1.2. Characterization of the SEI

6.2. Physical properties of the Na-ion SEI

6.2.1. Electrochemical stability

6.2.2. Mechanical properties

6.2.3. Dissolution of SEI components

6.3. Comparisons of SEI in sodium- and lithium-based electrolytes

6.3.1. Formation and composition

6.3.2. Resistance

6.4. Conclusion

6.5. References

7. Batteries Containing Prussian Blue Analogue Electrodes

7.1. Introduction

7.1.1. Chapter introduction

7.1.2. History of Prussian blue

7.1.3. Physical characteristics: structure, composition and morphology

7.1.4. Synthetic methods

7.2. Electrochemistry of PBAs

7.2.1. Mechanism and resulting characteristics

7.2.2. Reaction potentials

7.2.3. PBA cathodes

7.2.4. PBA anodes

7.3. Prussian blue batteries

7.3.1. Cells containing two PBA electrodes

7.3.2. Cells containing one PBA electrode

7.3.3. Challenges for PBA batteries

7.4. Conclusion and future outlook

7.5. References

8. The Design, Performance and Commercialization of Faradion's Non-aqueous Na-ion Battery Technology

8.1. Introduction

8.2. Experimental

8.2.1. Active materials

8.2.2. Electrode fabrication

8.2.3. Pouch cell fabrication.

8.2.4. Faradion electrolyte

8.3. Cell performance

8.3.1. Half-cell cycling

8.3.2. Full Na-ion cell cycling: curves and stability

8.3.3. Rate capability

8.3.4. Temperature studies

8.3.5. Three-electrode cell studies

8.4. Safety and zero energy storage and transportation

8.5. Scale-up and prototyping

8.6. Demonstrators: stacks and packs

8.7. Business and IP strategy

8.8. Cost analysis

8.9. Future developments

8.10. Conclusion

8.11. Acknowledgments

8.12. References

List of Authors

Index

EULA.

Notes:

Description based on print version record.

ISBN:

9781523143641

1523143649

9781119818045

1119818044

9781119818052

1119818052

OCLC:

1243533485