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Framboids / David Rickard.

Oxford Scholarship Online Chemistry Available online

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Format:
Book
Author/Creator:
Rickard, David T. (David Terence), 1943- author.
Language:
English
Subjects (All):
Pyrites.
Ore deposits.
Sediments (Geology).
Texture (Crystallography).
Aggregation (Chemistry).
Genre:
Electronic books.
Physical Description:
1 online resource (xxv, 334 pages) : illustrations (some color)
Place of Publication:
New York, NY : Oxford University Press, [2021]
System Details:
text file
Summary:
"Framboids may be the most astonishing and abundant natural features you have never heard of. These microscopic spherules of golden pyrite consist of thousands of even smaller microcrystals often arranged in stunning geometric arrays. There are probably 1030 on Earth and they are forming at a rate of 1020 every second. This means that there are a billion times more framboids than sand grains on Earth and a million times more framboids than stars in the observable universe. They are all around us: they can be found in rocks of all ages and in present-day sediments, soils and natural waters. The sulfur in the pyrite is mainly produced by bacteria and many framboids contain organic matter. They are formed through burst nucleation of supersaturated solutions of iron and sulfide followed by limited crystal growth in diffusion-dominated stagnant sediments. The framboids self-assemble as surface free energy is minimized and the microcrystals are attracted to each other by surface forces. Self-organization occurs through entropy maximization and the microcrystals rotate into their final positions through Brownian motion. The final shape of the framboids is often actually polygonal or partially facetted rather than spherical, as icosahedral microcrystal packing develops. Their average diameter is around 6 microns and the average microcrystal size is about 0.1 microns. There is no significant change in these dimensions with time: the framboid is an exceptionally stable structure and the oldest may be 2.9 billion years old. This means that they provide samples of the chemistry of ancient environments"-- Provided by publisher.
Contents:
Framboid sizes
Framboid shapes
Microcrystal morphology
Framboid microarchitecture
The crystallography of pyrite framboids
Organic matter in framboids
Framboid mineralogy
Geochemistry of framboids
Pyrite framboid formation chemistry
Nucleation of framboids
Framboid microcrystal growth
Framboid self-assembly and self-organization.
Notes:
Includes bibliographical references and index.
Description based on online resource; title from digital title page (viewed on August 18, 2021).
Other Format:
Print version: Rickard, David T. (David Terence), 1943- Framboids
ISBN:
0197571921
9780190080129
0190080124
9780197571934
019757193X
9780197571927
OCLC:
1236900899
Access Restriction:
Restricted for use by site license.

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