Molecular photophysics and spectroscopy / David L. Andrews, Robert H. Lipson.

Format:

Book

Author/Creator:

Andrews, David L., 1952- author.

Lipson, R. H. (Robert Henry), 1955- author.

Contributor:

Institute of Physics (Great Britain), publisher.

Series:

IOP ebooks. 2021 collection.

IOP ebooks. [2021 collection]

Language:

English

Subjects (All):

Molecular spectroscopy.

Photons.

Physical Description:

1 online resource (various pagings) : illustrations (some color).

Edition:

Second edition.

Other Title:

Molecular Photophysics and Spectroscopy

Place of Publication:

Bristol [England] (Temple Circus, Temple Way, Bristol BS1 6HG, UK) : IOP Publishing, [2021]

System Details:

Mode of access: World Wide Web.

System requirements: Adobe Acrobat Reader, EPUB reader, or Kindle reader.

Biography/History:

David Andrews is known for advances in the theory of quantum and nonlinear optics, fundamental photonics, energy transport, and optical vortices. He has published 400 papers and over twenty books, including as author or co-author Lasers in Chemistry, Optical Harmonics in Molecular Systems, Optical Nanomanipulation, and an Introduction to Photon Science and Technology. David has taught extensively at the University of East Anglia and run numerous spectroscopy courses for industry: he has twice been Chair of the Royal Society of Chemistry Molecular Spectroscopy Group. Andrews is a Chartered Chemist and Chartered Physicist, and he is the 2021 President of SPIE, the international society for optics and photonics. Rob Lipson has published extensively in the areas of laser spectroscopy, nanoscience, and novel material for photonics applications. He has taught a wide variety of undergraduate and graduate level physical chemistry courses at Western University and the University of Victoria (UVic). Administratively, he has served as Chair of the Department of Chemistry at Western and two terms as Dean of Science at UVic. In addition to his academic work, he was also a long-serving Senior Editor of the Canadian Journal of Chemistry, and a panel member on numerous funding and research integrity committees for the federal Government of Canada. Lipson is a Fellow of the Chemical Institute of Canada.

Summary:

This new, expanded edition provides a fresh, photon-based description of modern molecular spectroscopy and photophysics, with applications that are drawn from across the breadth of chemistry, biology, physics, and materials science, including recent developments. The focus is on the mechanisms that operate at the fundamental level, on how light absorption and scattering occur in molecules, what happens to the energy which the molecules acquire, and what may be learned from the study of these processes. Mathematics is again kept to a minimum though quantitative understanding is nevertheless put into practice via example calculations throughout the text. With the aid of extensive, purposely devised illustrations, this approach fosters a deeper intuition for the photophysical processes involved in light-matter interaction, aiming to consolidate the principles and to exemplify how widely ranging information can be derived from spectroscopic studies.

Contents:

1. Introduction to molecular spectroscopy and photophysics

1.1. The distinctiveness of molecular interactions with light

1.2. Properties of molecules and their spectra

1.3. The electromagnetic spectrum

1.4. Photon properties : polarisation and spin

2. Atoms and molecules : developing principles of electronic structure

2.1. Review of atomic orbitals, angular momentum and electron spin

2.2. Multielectron atoms

2.3. Diatomic molecules

2.4. Orbitals and bonding in molecules

3. Polyatomic molecules : orbitals, symmetry and group theory

3.1. Symmetry elements

3.2. Point groups and operations : Schoenflies notation

3.3. Matrix representations and character tables

4. Electronic and nuclear energy levels in molecules

4.1. The separation of electronic and nuclear motions

4.2. Types of nuclear motions and degrees of freedom

4.3. How far do the atoms move?

5. Small molecule rotational energy levels and spectra

5.1. Diatomic and linear polyatomic molecules

5.2. Nuclear spin effects

5.3. Interpreting rotational spectra

5.4. Centrifugal distortion

5.5. Non-linear polyatomic molecules

6. Diatomics and triatomics : vibrational energy levels and spectra

6.1. Diatomic molecules : harmonic motion

6.2. Anharmonicity and dissociation

6.3. Vibration-rotation spectra of diatomic molecules

6.4. The vibrations of triatomic molecules

7. Large molecule infrared absorption spectroscopy

7.1. Group frequencies and skeletal modes

7.2. Infrared spectroscopy in the condensed phase

7.3. Near-infrared spectroscopy

8. Raman scattering and spectral interpretation

8.1. Rayleigh scattering

8.2. Vibrational Raman scattering

8.3. Depolarisation ratio

8.4. Resonance Raman spectroscopy

9. Electronic and vibrational states in large molecules

9.1. Electronic states, transitions, and molecular structure

9.2. Vibronic structure in electronic absorption spectra

9.3. Vibronic structure in electronic emission spectra

9.4. Transition metal complexes : vibronic coupling in electronic transitions

10. Electronic transitions, colours, and detection

10.1. The origins of colour

10.2. Photometry and Beer's law

10.3. Organic molecules : conjugation and colour

11. After light is absorbed : photophysics in an excited electronic state

11.1. Interplay of excitation and decay

11.2. States accessible to photoexcitation

11.3. Decay channels

12. Molecular fluorescence

12.1. Quantum yields and fluorescence measurements

12.2. Transition dipole orientations

12.3. Photoselection and fluorescence anisotropy

12.4. Fluorophores and laser-induced fluorescence imaging

12.5. Quantum dots

13. Fluorescence resonance energy transfer

13.1. Mechanism for intermolecular energy transfer

13.2. Spectroscopic shift

13.3. Distance measurements

14. Chiral phenomena and optical activity

14.1. Criteria for chirality in matter and in light

14.2. Circular dichroism

14.3. Optical rotation

15. Multiphoton absorption in molecules

15.1. Two-photon absorption

15.2. Non-resonant two-photon absorption

15.3. Resonant two-photon absorption

15.4. Two-photon spectroscopy

15.5. Higher order processes

15.6. Multiphoton imaging and processing.

Notes:

"Version: 20210207"--Title page verso.

Includes bibliographical references and index.

Title from PDF title page (viewed on August 5, 2021).

ISBN:

0-7503-3682-X

0-7503-3683-8

OCLC:

1262946077