Organometallic chemistry / editors: Hiroshi Nakazawa, Julian Koe.

Format:

Book

Contributor:

Nakazawa, Hiroshi, 1952- editor.

Koe, Julian (Julian R.), editor.

ProQuest ebook central.

Series:

Coordination chemistry fundamentals.

Coordination chemistry fundamentals

Language:

English

Japanese

Subjects (All):

Organometallic chemistry.

Physical Description:

1 online resource (1 volume).

polychrome

Place of Publication:

Cambridge, UK : Royal Society of Chemistry, 2021.

System Details:

text file

Contents:

Intro

Title

Copyright

Preface

Author Biography

Contents

Section 1: Basics

Chapter 1 What is Organometallic Chemistry

1.1 Organic Chemistry and Inorganic Chemistry

1.2 Coordination Chemistry

1.3 Organometallic Chemistry

References

Chapter 2 Basic Concepts Relating to Organometallic Complexes

2.1 Introduction

2.2 EAN Rule

2.3 Eighteen Electron Rule (18e Rule)

2.4 Electron Counting

2.4.1 Transition Metal

2.4.2 Ligand

2.4.3 Total Charge of the Complex

2.4.4 Importance of Electron Counting

3.3.2 Ligand Field Theory (LFT)

3.3.3 Reason for the Establishment of the 18e Rule

3.4 Reason Why a Four-coordinate d8 Complex Adopts a Square-planar Structure

Chapter 4 Carbonyl, Olefin and Phosphine Complexes

4.1 Introduction

4.2 Carbonyl Complexes

4.3 Olefin Complexes

4.3.1 Change in Oxidation State of the Metal

4.3.2 Substituents on the Olefin

4.3.3 Fluxionality: Olefin Rotational Motion

4.3.4 C C Double Bond Length of the Olefin

4.3.5 Bent Back Angle of the Olefin

4.4 Phosphine Complexes

References

Chapter 5 Carbene Complexes

Complexes with M C Double Bonds

5.1 History of Carbene Complexes

5.2 Properties of Carbene Complexes

5.3 Reactivity of Carbene Complexes

Chapter 6 Basic Reactions of Organometallic Complexes

6.1 Introduction

6.2 Oxidative Addition

6.2.1 Vaska's Complex

6.2.2 C-H Bond Activation

6.2.3 Orthometallation

6.2.4 Ease of Oxidative Addition

6.3 Reductive Elimination

6.3.1 Reductive Elimination in cis-[MR2L2] (L = Phosphine, M = Ni, Pd, Pt)

6.3.2 Ease of Reductive Elimination

Notes:

Electronic reproduction. Ann Arbor, MI Available via World Wide Web.

Print version record.

Other Format:

Print version: ORGANOMETALLIC CHEMISTRY.

ISBN:

9781839164200

1839164204

9781839164217

1839164212

Publisher Number:

40030651803

Access Restriction:

Restricted for use by site license.