Solid state chemistry : an introduction / Elaine A. Moore, Lesley E. Smart.

Format:

Book

Author/Creator:

Moore, Elaine (Elaine A.), author.

Smart, Lesley, author.

Language:

English

Subjects (All):

Solid state chemistry.

Physical Description:

xxv, 442 pages : illustrations (some color) ; 25 cm

Edition:

Fifth edition.

Place of Publication:

Boca Raton, FL : CRC Press, 2021.

Summary:

"Building a foundation with a thorough description of crystalline structures, this fifth edition of Solid State Chemistry: An Introduction presents a wide range of the synthetic and physical techniques used to prepare and characterize solids. Going beyond this, this largely nonmathematical introduction to solid state chemistry includes the bonding and electronic, magnetic, electrical and optical properties of solids. Solids of particular interest - porous solids, superconductors and nanostructures are included. Practical examples of applications and modern developments are given. It offers students the opportunity to apply their knowledge in real-life situations and serve them well throughout their degree course"-- Provided by publisher.

Contents:

Machine generated contents note: ch. 1 An Introduction To Crystal Structures

1.1. Introduction

1.2. Lattices and Unit Cells

1.2.1. Lattices

1.2.2. One- and Two-Dimensional Unit Cells

1.3. Symmetry

1.3.1. Symmetry Notation

1.3.2. Axes of Symmetry

1.3.3. Planes of Symmetry

1.3.4. Inversion

1.3.5. Inversion Axes and the Identity Element

1.3.6. Operations

1.4. Symmetry in Crystals

1.4.1. Translational Symmetry Elements

1.5. Three-Dimensional Lattices and Their Unit Cells

1.5.1. Space Group Labels

1.5.2. Packing Diagrams

1.6. Close Packing

1.6.1. Body-Centred and Primitive Structures

1.7. Crystal Planes

Miller Indices

1.7.1. Interplanar Spacings

1.8. Crystalline Solids

1.8.1. Ionic Solids with Formula MX

1.8.2. Solids with General Formula MX

1.8.3. Other Important Crystal Structures

1.8.4. Ionic Radii

1.8.5. Extended Covalent Arrays

1.8.6. Bonding in Crystals

1.8.7. Atomic Radii

1.8.8. Molecular Structures

1.9. Lattice Energy

1.9.1. Born

Haber Cycle

1.9.2. Calculating Lattice Energies

1.9.2.1. Computer Modeling

1.10. Summary

Questions

ch. 2 Physical Methods For Characterizing Solids / Liana Vella-Zarb

2.1. Introduction

2.2. X-Ray Diffraction

2.2.1. Generation of X-Rays

2.2.2. Diffraction of X-Rays

2.3. Single Crystal X-Ray Diffraction

2.3.1. The Importance of Intensities

2.3.2. Solving Single Crystal Structures

2.3.3. High-Energy X-Ray Diffraction

2.4. Powder Diffraction

2.4.1. Powder Diffraction Patterns

2.4.2. Absences Due to Lattice Centring

2.4.3. Systematic Absences Due to Screw Axes and Glide Planes

2.4.4. Uses of Powder X-Ray Diffraction

2.4.4.1. Identification of Unknowns and Phase Purity

2.4.4.2. Crystallite Size

2.4.4.3. Following Reactions and Phase Diagrams

2.4.4.4. Structure Determination and the Rietveld Method

2.5. Neutron Diffraction

2.5.1. Uses of Neutron Diffraction

2.6. X-Ray Microscopy/X-Ray Computed Tomography

2.7. Electron Microscopy

2.7.1. Scanning Electron Microscopy, SEM

2.7.2. Transmission Electron Microscopy, TEM

2.7.3. Cryogenic Electron Microscopy (Cryo EM)

2.7.4. Energy Dispersive X-Ray Analysis, EDX (EDAX)

2.7.5. Scanning Transmission Electron Microscopy, STEM

2.7.6. Electron Energy Loss Spectroscopy, EELS

2.7.7. superSTEM

2.8. Scanning Probe Microscopy, SPM

2.8.1. Scanning Tunnelling Microscopy, STM

2.9. Atomic Force Microscopy, AFM

2.10. X-Ray Absorption Spectroscopy, XAS

2.10.1. Extended X-Ray Absorption Fine Structure, EXAFS

2.10.2. X-Ray Absorption Near-Edge Structure, XANES, and Near-Edge X-Ray Absorption Fine Structure, NEXAFS

2.11. X-Ray Photoelectron Spectroscopy (XPS)

2.12. Solid-State Nuclear Magnetic Resonance Spectroscopy

2.13. Thermal Analysis

2.13.1. Differential Thermal Analysis, DTA

2.13.2. Thermogravimetric Analysis, TGA

2.13.3. Differential Scanning Calorimetry, DSC

2.13.4. Simultaneous Thermal Analysis, STA, and Coupling with Spectroscopic or Spectrometric Methods

2.14. Temperature Programmed Reduction, TPR

2.15. Other Techniques

2.16. Summary

ch. 3 Synthesis Of Solids

3.1. Introduction

3.2. High-Temperature Ceramic Methods

3.2.1. Direct Heating of Solids

3.2.2. Precursor Methods

3.2.3. Sol

Gel Methods

3.3. Mechanochemical Synthesis

3.4. Microwave Synthesis

3.5. Combustion Synthesis

3.6. High-Pressure Methods

3.6.1. Hydrothermal Methods

3.6.2. Using High-Pressure Gases

3.6.3. Using Hydrostatic Pressures

3.6.4. Using Ultrasound

3.7. Chemical Vapour Deposition

3.7.1. Preparation of Semiconductors

3.7.2. Diamond Films

3.7.3. Optical Fibres

3.7.4. Lithium Niobate

3.8. Preparing Single Crystals

3.8.1. Epitaxy Methods

3.8.2. Chemical Vapour Transport

3.8.3. Melt Methods

3.8.4. Solution Methods

3.9. Intercalation

3.10. Green Chemistry

3.11. Choosing a Method

ch. 4 Solids: Bonding And Electronic Properties / Neil Allan

4.1. Introduction

4.2. Bonding in Solids: Free-Electron Theory

4.2.1. Electronic Conductivity

4.3. Bonding in Solids: Molecular Orbital Theory

4.3.1. Simple Metals

4.4. Diamond, Si, and Ge: Semiconductors

4.4.1. Photoconductivity

4.4.2. Doped Semiconductors

4.4.3. p

n Junction and Field Effect Transistors

4.5. Bands in Compounds: Gallium Arsenide

4.6. Bands in d-Block Compounds: Transition Metal Monoxides

4.7. Summary

ch. 5 Defects And Nonstoichiometry

5.1. Introduction

5.2. Point Defects and Their Concentration

5.2.1. Intrinsic Defects

5.2.2. Concentration of Defects

5.2.3. Extrinsic Defects

5.2.4. Defect Nomenclature

5.3. Nonstoichiometric Compounds

5.3.1. Nonstoichiometry in Wustite (FeO) and MO-Type Oxides

5.3.2. Uranium Dioxide

5.3.3. Titanium Monoxide Structure

5.4. Extended Defects

5.4.1. CS Planes

5.4.2. Planar Intergrowths

5.4.3. Block Structures

5.4.4. Pentagonal Columns

5.4.5. Infinitely Adaptive Structures

5.5. Electronic Properties of Nonstoichiometric Oxides

5.6. Summary

ch. 6 Solid-State Materials For Batteries

6.1. Introduction

6.2. Ionic Conductivity in Solids

6.3. Solid Electrolytes

6.3.1. Silver Ion Conductors

6.3.2. Lithium Ion Conductors

6.3.3. Sodium Ion Conductors

6.4. Lithium-Based Batteries

6.5. Sodium-Based Batteries

6.6. Summary

ch. 7 Microporous And Mesoporous Solids

7.1. Introduction

7.2. Zeolites

7.2.1. Silicates

7.2.2. Composition and Structure of Zeolites

7.2.3. Zeolite Nomenclature

7.2.4. Si/Al Ratios in Zeolites

7.2.5. Exchangeable Cations

7.2.6. Channels and Cavities

7.2.7. Synthesis of Zeolites

7.2.8. Uses of Zeolites

7.2.8.1. Adsorbents

7.2.8.2. Catalysts

7.3. Metal Organic Frameworks

7.3.1. Composition and Structure of MOFs

7.3.2. Synthesis of MOFs

7.3.3. Uses of MOFs

7.3.3.1. Storage and Separation

7.3.3.2. Heterogeneous Catalysis

7.3.3.3. Other Applications

7.3.4. Zeolite-like MOFs

7.4. Covalent Organic Frameworks

7.4.1. Structure of COFs

7.4.2. Synthesis of COFs

7.4.3. Uses of COFs

7.5. Other Porous Solids

7.5.1. Mesoporous Aluminosilicates

7.5.2. Clays

7.5.3. Periodic Mesoporous Organosilicas

7.6. Summary

ch. 8 Optical Properties Of Solids

8.1. Introduction

8.2. Interaction of Light with Atoms

8.2.1. Ruby Laser

8.2.2. Phosphors in LEDs

8.3. Colour Centres

8.4. Absorption and Emission of Radiation in Continuous Solids

8.4.1. Gallium Arsenide Laser

8.4.2. Quantum Wells: Blue Lasers

8.4.3. Light-Emitting Diodes

8.4.4. Photovoltaic (Solar) Cells

8.5. Carbon-Based Conducting Polymers

8.5.1. Discovery of Polyacetylene

8.5.2. Bonding in Polyacetylene and Related Polymers

8.5.3. Organic LEDs and Photovoltaic Cells

8.6. Refraction

8.6.1. Calcite

8.6.2. Optical Fibres

8.7. Photonic Crystals

8.8. Metamaterials

8.9. Summary

ch.

9 Magnetic And Electrical Properties

9.1. Introduction

9.2. Magnetic Susceptibility

9.3. Paramagnetism in Metal Complexes

9.4. Ferromagnetic Metals

9.4.1. Ferromagnetic Domains

9.4.2. Permanent Magnets

9.4.3. Magnetic Shielding

9.5. Ferromagnetic Compounds: Chromium Dioxide

9.6. Antiferromagnetism: Transition Metal Monoxides

9.7. Ferrimagnetism: Ferrites

9.7.1. Magnetic Strips on Swipe Cards

9.8. Spiral Magnetism

9.9. Giant, Tunnelling, and Colossal Magnetoresistance

9.9.1. Giant Magnetoresistance

9.9.2. Tunnelling Magnetoresistance

9.9.3. Hard-Disk Read Heads

9.9.4. Colossal Magnetoresistance: Manganites

9.10. Electrical Polarisation

9.11. Piezoelectric Crystals: A-Quartz

9.12. Ferroelectric Effect

9.12.1. Multilayer Ceramic Capacitors

9.13. Multiferroics

9.13.1. Type I Multiferroics: Bismuth Ferrite

9.13.2. Type II Multiferroics: Terbium Manganite

9.14. Summary

ch. 10 Superconductivity

10.1. Introduction

10.2. Properties of Superconductors

10.2.1. Electrical Conductivity

10.2.2. Magnetic Properties of Superconductors

10.2.3. BCS Theory of Superconductivity

10.3. High-Temperature Superconductors

10.3.1. Cuprate Superconductors

10.3.2. Iron Superconductors

10.3.3. Theory of High-Tc Superconductors

10.4. Uses of High-Temperature Superconductors

10.5. Summary

ch. 11 Nanostructures

11.1. Introduction

11.2. Consequences of the Nanoscale

11.2.1. Nanoparticle Morphology

11.2.2. Electronic Structure

11.2.3. Optical Properties

11.2.4. Magnetic Properties

11.2.5. Mechanical Properties

11.2.6. Melting Temperature

11.3. Nanostructural Carbon

11.3.1. Carbon Black

11.3.2. Graphite

11.3.3. Intercalation Compounds of Graphite

11.3.4. Graphene

11.3.5. Graphene Oxide

11.3.6. Buckminsterfullerene

11.3.7. Carbon Nanotubes

11.4. Noncarbon Nanoparticles

11.4.1. Fumed Silica

11.4.2. Quantum Dots

11.4.3. Metal Nanoparticles

Contents note continued: 11.5. Other Noncarbon Nanostructures

11.6. Synthesis of Nanomaterials

11.6.1. Top-Down Methods

11.6.2. Bottom-Up Methods: Manipulating Atoms and Molecules

11.6.3. Synthesis Using Templates

11.7. Safety

11.8. Summary

ch. 12 Sustainability / Mary Anne White

12.1. Introduction

12.1.1. Definition of Materials Sustainability

12.1.2. Sustainable Materials Chemistry Goals

12.1.3. Materials Dependence in Society

12.1.4. Elemental Abundances

12.1.5. Solid-State Chemistry's Role in Sustainability

12.1.6. Material Life Cycle

12.2. Tools for Sustainable Approaches

12.2.1. Green Chemistry

12.2.2. Herfindahl

Hirschman Index (HHI)

12.2.3. Embodied Energy

12.2.4. Exergy

12.2.5. Life Cycle Assessment

12.3. Case Study: Sustainability of a Smartphone

12.4. Concluding Remarks

Questions.

Notes:

Includes bibliographical references and index.

Other Format:

Online version: Moore, Elaine A, Solid state chemistry

ISBN:

9780367135720

0367135728

9780367135805

0367135809

OCLC:

1145912015

Publisher Number:

99987413457