Advances in organometallic chemistry. Volume 43 / edited by Robert West and Anthony F. Hill.

Format:

Book

Contributor:

Hill, Anthony F.

West, Robert, 1928-

Series:

Advances in organometallic chemistry ; 43.

Advances in organometallic chemistry ; 43

Language:

English

Subjects (All):

Organometallic compounds.

Organic compounds.

Physical Description:

1 online resource (439 p.)

Place of Publication:

New York : Academic Press, 1999.

Language Note:

English

Summary:

This book is an essential reference work for the academic and industrial chemists and will provide up-to-date material at the cutting edge of chemistry research.This widely-acclaimed serial contains authoritative reviews that address all aspects of organometallic chemistry, a field which has expanded enormously since the publication of Volume 1 in 1964. Almost all branches of chemistry and material science now interface with organometallic chemistry--the study of compounds containing carbon-metal bonds. Organometallic compounds range from species which are so reactive that they only ha

Contents:

Front Cover; Advances in Organometallic Chemistry, Volume 43; Copyright Page; Contents; Contributors; Preface; Chapter 1. Silylenes Coordinated to Lewis Bases; I. Introduction; II. Theoretical Studies of Silylene-Lewis Base Complexes; III. Spectroscopic Properties of Silylene-Lewis Base Adducts; IV. Kinetic Studies; V. Donor-Acceptor Interactions of Silylenes in Organometallic Reactions; References; Chapter 2. Chemistry of Ruthenium-Carbide Clusters RU5C(CO)15 and Ru6C(CO)17; I. Introduction; II. Synthesis and Characterization of RU5C(CO)15 and Ru6C(CO)17; III. Electrochemistry

IV. Ligand Reactions of RU5C(CO)15 and RU6C(CO)17V. Dervatives of Ru5C(CO)15 and Ru6 C(CO)17 Prepared from Other Clusters; VI. Origin of the Carbide Atom in Ru6C(CO)17 and Some of Its Dervatives; VII. Reactions of Ru5C(CO)15 and Ru6C(CO)17 That Result in Higher Nucleatity Clusters; VIII. Hereronuclear Derivatives; IX. Stereochemical Nonrigid Behavior; X. Concluding Remarks; References; Chapter 3. Transition Metal Heteroaldehyde and Heteroketone Complexes; I. Introduction; II. Bonding in Heteroaldehydes and Heteroketones; III. Bonding and Structure in Heteroaldehyde and Heteroketone Complexes

IV. Synthesis of Heteroaldehyde and Heteroketone ComplexesV. Reactions of Heteroaldehyde and Heteroketone Complexes; References; Chapter 4. Recent Progress in Transition Metal-Catalyzed Reactions of Silicon, Germanium, and Tin; I. Introduction; II. Formation of E-C Bonds; III. Formation of E-E Bonds; IV. Formation of Si-O Bonds; V. Formation of Si-N Bonds; VI. Conclusions; References; Chapter 5. Organometallic Compounds of the Heavier Alkali Metals; I. Introduction; II. Synthesis; III. Alkyl Derivatives; IV. Aryl Derivatives; V. Cyclopentadienyl and Related Derivatives

VI. Alkene and Alkyne DerivativesVII. Arene Derivatives; VIII. Conclusions; References; Chapter 6.Organometallic Complexes in Nonlinear Optics II: Third-Order Nonlinearities and Optical Limiting Studies; I. Introduction; II. Background; III. Organometallics for Third-Order Nonlinear Optics; IV. Optical Limiting Properties of Organometallic Complexes; V. Concluding Remarks; VI. Appendix: Abbreviations; References; INDEX; CUMULATIVE LIST OF CONTRIBUTORS FOR VOLUMES 1-36; CUMULATIVE INDEX FOR VOLUMES 37-43

Notes:

Description based upon print version of record.

ISBN:

1-281-71182-9

9786611711825

0-08-058044-0

OCLC:

437244197