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Angle Resolved Photoemission Spectroscopy of Delafossite Metals / by Veronika Sunko.

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Format:
Book
Author/Creator:
Sunko, Veronika, author.
Contributor:
SpringerLink (Online service)
Series:
Physics and Astronomy (Springer-11651)
Springer Theses, Recognizing Outstanding Ph.D. Research,. 2190-5053
Springer Theses, Recognizing Outstanding Ph.D. Research, 2190-5053
Language:
English
Subjects (All):
Solid state physics.
Spectrum analysis.
Microscopy.
Surfaces (Technology).
Thin films.
Solid State Physics.
Spectroscopy and Microscopy.
Surfaces and Interfaces, Thin Films.
Spectroscopy/Spectrometry.
Local Subjects:
Solid State Physics.
Spectroscopy and Microscopy.
Surfaces and Interfaces, Thin Films.
Spectroscopy/Spectrometry.
Physical Description:
1 online resource (XVII, 198 pages) : 122 illustrations, 104 illustrations in color.
Edition:
First edition 2019.
Contained In:
Springer eBooks
Place of Publication:
Cham : Springer International Publishing : Imprint: Springer, 2019.
System Details:
text file PDF
Summary:
This thesis describes the results of angle resolved photoemission spectroscopy experiments on delafossite oxide metals, and theoretical work explaining these observations. The study was motivated by the extraordinarily high conductivity of the non-magnetic delafossites PdCoO2 and PtCoO2, the measurement of whose electronic structure is reported and discussed. Two unexpected effects were observed in the course of the investigation; each is described and analysed in detail. Firstly, a previously unrecognised type of spectroscopic signal, allowing the non-magnetic probe of photoemission to become sensitive to spin-spin correlations, was observed in the antiferromagnetic PdCrO2. Its origin was identified as the Kondo-like coupling of itinerant and Mott insulating electrons. Furthermore, surface states exhibiting an unusually large Rashba-like spin-splitting were observed on the transition metal terminated surfaces of delafossites. The large inversion symmetry breaking energy scale, a consequence of the unusual structure of the surface layer, is identified as the origin of the effect.
Contents:
Introduction
Angle Resolved Photoemission
Theory and Models
Bulk States in PtCoO2 and PdCoO2
Coupling of Metallic and Mott-insulating states in PdCrO2
Rashba-like Spin-Split Surface States
Conclusions and Outlook
Appendices.
Other Format:
Printed edition:
ISBN:
978-3-030-31087-5
9783030310875
Access Restriction:
Restricted for use by site license.

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