Organic coatings : science and technology / Frank N. Jones, Mark E. Nichols, S. Peter Pappas.

Format:

Book

Author/Creator:

Jones, Frank N., 1936- author.

Nichols, Mark E., author.

Pappas, S. Peter, author.

Language:

English

Subjects (All):

Plastic coatings.

Physical Description:

1 online resource (515 pages) : illustrations

Edition:

Fourth edition.

Place of Publication:

Hoboken, New Jersey : Wiley, 2017.

Summary:

The definitive guide to organic coatings, thoroughly revised and updated-now with coverage of a range of topics not covered in previous editions Organic Coatings: Science and Technology, Fourth Edition offers unparalleled coverageof organic coatings technology and its many applications. Written by three leading industry experts (including a new, internationally-recognized coatings scientist) it presents a systematic survey of the field, revises and updates the material from the previous edition, and features new or additional treatment of such topics as superhydrophobic, ice-phobic, antimicrobial, and self-healing coatings; sustainability, artist paints, and exterior architectural primers. making it even more relevant and useful for scientists and engineers in the field, as well as for students in coatings courses. The book incorporates up-to-date coverage of recent developments in the field with detailed discussions of the principles underlying the technology and their applications in the development, production, and uses of organic coatings. All chapters in this new edition have been updated to assure consistency and to enable extensive cross-referencing. The material presented is also applicable to the related areas of printing inks and adhesives, as well as areas within the plastics industry. This new edition * Completely revises outdated chapters to ensure consistency and to enable extensive cross-referencing * Correlates the empirical technology of coatings with the underlying science throughout * Provides expert troubleshooting guidance for coatings scientists and technologists * Features hundreds of illustrative figures and extensive references to the literature * A new, internationally-recognized coatings scientist brings fresh perspective to the content. Providing a broad overview for beginners in the field of organic coatings and a handy reference for seasoned professionals, Organic Coatings: Science and Technology, Fourth Edition, gives you the information and answers you need, when you need them.

Contents:

Intro

Title Page

Copyright Page

Contents

Preface

Chapter 1 Introduction to Coatings

1.1 Definitions and Scope

1.2 Types of Coatings

1.3 Composition of Coatings

1.4 Coating History

1.5 Commercial Considerations

References

Chapter 2 Polymerization and Film Formation

2.1 Polymers

2.1.1 Molecular Weight (MW)

2.1.2 Morphology and Glass Transition Temperature, Tg

2.2 Polymerization

2.2.1 Chain-Growth Polymerization

2.2.2 Step-Growth Polymerization

2.3 Film Formation

2.3.1 Film Formation by Solvent Evaporation from Solutions of Thermoplastic Binders

2.3.2 Film Formation from Solutions of Thermosetting Resins

2.3.3 Film Formation by Coalescence of Polymer Particles

General References

Chapter 3 Flow

3.1 Shear Flow

3.2 Types of Shear Flow

3.3 Determination of Shear Viscosity

3.3.1 Capillary Viscometers

3.3.2 Rheometers

3.3.3 Rotating Disk Viscometers

3.3.4 Bubble Viscometers

3.3.5 Efflux Cups

3.3.6 Paddle Viscometers

3.4 Shear Viscosity of Resin Solutions

3.4.1 Temperature Dependence of Viscosity

3.4.2 Dilute Polymer Solution Viscosity

3.4.3 Concentrated Polymer Solution Viscosity

3.5 Viscosity of Liquids With Dispersed Phases

3.5.1 Thickeners for Latex Coatings

3.6 Other Modes of Flow

3.6.1 Turbulent Flow

3.6.2 Normal Force Flow

3.6.3 Extensional Flow

Chapter 4 Mechanical Properties

4.1 Introduction

4.2 Basic Mechanical Properties

4.2.1 Glass Transition Temperature (Tg)

4.2.2 Viscoelasticity

4.2.3 Dynamic Mechanical Behavior

4.3 Fracture Mechanics

4.4 Abrasion, Scratch, and Mar Resistance

4.4.1 Abrasion Resistance

4.4.2 Scratch and Mar Resistance

4.5 Measurement of Mechanical Properties

4.6 Tests of Coatings on Substrates.

4.6.1 Field Exposure Tests

4.6.2 Laboratory Simulation Tests

4.6.3 Empirical Tests

Chapter 5 Exterior Durability

5.1 Photoinitiated Oxidative Degradation

5.2 Photostabilization

5.2.1 UV Absorbers and Excited State Quenchers

5.2.2 Antioxidants

5.2.3 Hindered Amine Light Stabilizers

5.2.4 Pigmentation Effects

5.3 Degradation of Chlorinated Resins

5.4 Hydrolytic Degradation

5.5 Other Modes of Failure on Exterior Exposure

5.6 Testing For Exterior Durability

5.6.1 Natural Weathering

5.6.2 Accelerated Outdoor Exposure

5.6.3 Accelerated Laboratory Weathering Devices

5.6.4 Analysis of Coating Changes during Weathering

5.7 Service Life Prediction

Chapter 6 Adhesion

6.1 Mechanisms of Adhesion

6.1.1 Surface Mechanical Effects on Adhesion

6.1.2 Relationships between Wetting and Adhesion

6.1.3 Chemical Interactions between Coatings and Surfaces

6.2 Mechanical Stresses and Adhesion

6.3 Adhesion to Metal Surfaces

6.3.1 Conversion Coating and Pretreatment of Metal Substrates

6.4 Characterization of Surfaces

6.5 Organic Chemical Treatment of Substrates to Enhance Adhesion

6.6 Covalent Bonding To Glass and Metal Substrates

6.7 Adhesion to Plastics and to Coatings

6.8 Testing for Adhesion

Chapter 7 Corrosion Protection by Coatings

7.1 Corrosion Basics

7.2 Corrosion of Uncoated Steel

7.3 Corrosion Protection of Metals

7.3.1 Passivation: Anodic Protection

7.3.2 Cathodic Protection

7.3.3 Barrier Protection and Inhibition

7.4 Corrosion Protection by Intact Coatings

7.4.1 Critical Factors

7.4.2 Adhesion for Corrosion Protection

7.4.3 Factors Affecting Oxygen and Water Permeability

7.5 Corrosion Protection by Nonintact Films.

7.5.1 Minimizing Growth of Imperfections: Cathodic Delamination

7.5.2 Primers with Passivating Pigments

7.5.3 Cathodic Protection by Zinc-Rich Primers

7.5.4 Smart Corrosion Control Coatings

7.6 Evaluation and Testing

Chapter 8 Acrylic Resins

8.1 Thermoplastic Acrylic Resins

8.2 Thermosetting Acrylic Resins

8.2.1 Hydroxy-Functional Acrylic Resins

8.2.2 Acrylics Having Other Functional Groups

8.3 Water-Reducible Thermosetting Acrylic Resins

Chapter 9 Latexes

9.1 Emulsion Polymerization

9.1.1 Raw Materials for Emulsion Polymerization

9.1.2 Emulsion Polymerization Variables

9.1.3 Sequential Polymerization

9.2 Acrylic Latexes

9.3 Vinyl Ester Latexes

9.4 Thermosetting Latexes

9.4.1 One-Package Thermosetting Latex Coatings That Require Baking for Cure

9.4.2 Two-Package (2 K) Thermosetting Latex Coatings That Do Not Require Baking

9.4.3 One-Package Thermosetting Latex Coatings That Do Not Require Baking

Chapter 10 Polyester Resins

10.1 Hydroxy-Terminated Polyester Resins for Conventional Solids Coatings

10.1.1 Selection of Polyols

10.1.2 Selection of Polyacids

10.2 Polyester Resins for High Solids Coatings

10.3 Carboxylic Acid-Terminated Polyester Resins

10.4 Carbamate-Functional Polyester Resins

10.5 Water-Reducible Polyester Resins

10.6 Polyester Resins for Powder Coatings

Chapter 11 Amino Resins

11.1 Synthesis Of Melamine-Formaldehyde Resins

11.1.1 The Methylolation Reaction

11.1.2 The Etherification Reaction

11.1.3 Self-Condensation Reactions

11.2 Types of Mf Resins

11.3 Mf-Polyol Reactions in Coatings

11.3.1 Catalysis of MF-Polyol Reactions

11.3.2 Kinetics and Mechanism of MF-Polyol Co-condensation

11.3.3 Package Stability Considerations.

11.3.4 MF Resin Reactions with Carboxylic Acids, Urethanes, Carbamates, and Malonate-Blocked Isocyanates

11.4 Other Amino Resins

11.4.1 Urea-Formaldehyde Resins

11.4.2 Benzoguanamine-Formaldehyde Resins

11.4.3 Glycoluril-Formaldehyde Resins

11.4.4 Poly(meth)acrylamide- Formaldehyde Resins

Chapter 12 Polyurethanes and Polyisocyanates

12.1 Reactions of Isocyanates

12.2 Kinetics of Reactions of Isocyanates with Alcohols

12.2.1 Noncatalyzed Reactions

12.2.2 Catalysts

12.2.3 Interrelationships in Catalysis

12.3 Isocyanates Used in Coatings

12.3.1 Aromatic Isocyanates

12.3.2 Aliphatic Isocyanates

12.4 Two-Package (2K) Solventborne Urethane Coatings

12.4.1 2K Polyurea Coatings

12.5 Blocked Isocyanates

12.5.1 Principles of Blocking and Deblocking

12.5.2 Blocking Groups

12.5.3 Catalysis of Blocked Isocyanate Coatings

12.6 Moisture-Curable Urethane Coatings

12.7 Waterborne Polyurethane Coatings

12.7.1 Polyurethane Dispersions

12.7.2 Acrylic/Polyurethane Blends and Hybrid Dispersions

12.7.3 2K Waterborne Urethanes

12.8 Hydroxy-Terminated Polyurethanes

Chapter 13 Epoxy and Phenolic Resins

13.1 Epoxy Resins

13.1.1 Bisphenol A Epoxy Resins

13.1.2 Other Epoxy Resins

13.2 Amine Cross-Linked Epoxy Resins

13.2.1 Pot Life and Cure Time Considerations

13.2.2 Toxicity and Stoichiometric Considerations

13.2.3 Graininess and Blushing

13.2.4 Tg Considerations

13.2.5 Other Formulating Considerations

13.2.6 Waterborne Epoxy-Amine Systems

13.3 Other Cross-Linking Agents for Epoxy Resins

13.3.1 Phenols

13.3.2 Carboxylic Acids and Anhydrides

13.3.3 Hydroxyl Groups

13.3.4 Mercaptans

13.3.5 Homopolymerization

13.4 Water-Reducible Epoxy/Acrylic Graft Copolymers: Epoxy/Acrylic Hybrids

13.5 Epoxy Resin Phosphate Esters.

13.6 Phenolic Resins

13.6.1 Resole Phenolic Resins

13.6.2 Novolac Phenolic Resins

13.6.3 Ether Derivatives of Phenolic Resins

Chapter 14 Drying Oils

14.1 Compositions of Natural Oils

14.2 Autoxidation and Cross-Linking

14.2.1 Nonconjugated Drying Oils

14.2.2 Catalysis of Autoxidation and Cross-Linking

14.2.3 Conjugated Drying Oils

14.3 Synthetic and Modified Drying Oils

14.3.1 Heat Bodied Oils, Blown Oils, and Dimer Acids

14.3.2 Varnishes

14.3.3 Synthetic Conjugated Oils

14.3.4 Esters of Higher Functionality Polyols

14.3.5 Maleated Oils

14.3.6 Vinyl-Modified Oils

Chapter 15 Alkyd Resins

15.1 Oxidizing Alkyds

15.1.1 Monobasic Acid Selection

15.1.2 Polyol Selection

15.1.3 Dibasic Acid Selection

15.2 High Solids Oxidizing Alkyds

15.3 Waterborne Oxidizing Alkyds

15.3.1 Water-Reducible Alkyds

15.3.2 Alkyd Emulsions

15.4 Nonoxidizing Alkyds

15.5 Synthetic Procedures for Alkyd Resins

15.5.1 Synthesis from Oils or Fatty Acids

15.5.2 Process Variations

15.6 Modified Alkyds

15.7 Uralkyds and Other Autoxidizable Urethanes

15.7.1 Uralkyds

15.7.2 Autoxidizable Polyurethane Dispersions

15.8 Epoxy Esters

Chapter 16 Silicon Derivatives

16.1 Silicones

16.1.1 Silicone Rubbers and Resins

16.1.2 Modified Silicone Resins

16.1.3 Silicone-Modified Resins

16.2 Reactive Silanes

16.3 Orthosilicates

16.3.1 Sol-Gel Coatings

Chapter 17 Other Resins and Cross-Linkers

17.1 Halogenated Polymers

17.1.1 Solution-Grade Thermoplastic Vinyl Chloride Copolymers

17.1.2 Vinyl Chloride Dispersion Copolymers

17.1.3 Chlorinated Rubber, Chlorinated Ethylene/Vinyl Acetate Copolymers, and Chlorinated Polyolefins.

17.1.4 Fluorinated Polymers.

Notes:

Includes bibliographical references at the end of each chapters and index.

Description based on print version record.

ISBN:

9781523123711

1523123710

9781119337157

1119337151

9781119337218

1119337216

9781119337201

1119337208

OCLC:

975176535