Main group strategies towards functional organic materials / edited by Thomas Baumgartner, Department of Chemistry, York University, Toronto, Canada, Frieder Jakle, Department fo Chemistry, Rutgers University, Newark, USA.

Format:

Book

Contributor:

Baumgartner, Thomas, 1968- editor.

Jale, Frieder, 1969- editor.

Language:

English

Subjects (All):

Composite materials.

Nanostructured materials.

Polymers.

Physical Description:

1 online resource (786 pages) : illustrations

Edition:

1st ed.

Place of Publication:

Hoboken, New Jersey : Wiley, 2018.

Summary:

Showcases the highly beneficial features arising from the presence of main group elements in organic materials, for the development of more sophisticated, yet simple advanced functional materials Functional organic materials are already a huge area of academic and industrial interest for a host of electronic applications such as Organic Light-Emitting Diodes (OLEDs), Organic Photovoltaics (OPVs), Organic Field-Effect Transistors (OFETs), and more recently Organic Batteries. They are also relevant to a plethora of functional sensory applications. This book provides an in-depth overview of the expanding field of functional hybrid materials, highlighting the incredibly positive aspects of main group centers and strategies that are furthering the creation of better functional materials. Main Group Strategies towards FunctionalHybrid Materials features contributions from top specialists in the field, discussing the molecular, supramolecular and polymeric materials and applications of boron, silicon, phosphorus, sulfur, and their higher homologues. Hypervalent materials based on the heavier main group elements are also covered. The structure of the book allows the reader to compare differences and similarities between related strategies for several groups of elements, and to draw crosslinks between different sections. * The incorporation of main group elements into functional organic materials has emerged as an efficient strategy for tuning materials properties for a wide range of practical applications * Covers molecular, supramolecular and polymeric materials featuring boron, silicon, phosphorus, sulfur, and their higher homologues * Edited by internationally leading researchers in the field, with contributions from top specialists Main Group Strategies towards Functional Hybrid Materials is an essential reference for organo-main group chemists pursuing new advanced functional materials, and for researchers and graduate students working in the fields of organic materials, hybrid materials, main group chemistry, and polymer chemistry.

Contents:

Intro

Title Page

Table of Contents

List of Contributors

Preface

1 Incorporation of Boron into π‐Conjugated Scaffolds to Produce Electron‐Accepting π‐Electron Systems

1.1 Introduction

1.2 Boron‐Containing Five‐Membered Rings: Boroles and Dibenzoboroles

1.3 Annulated Boroles

1.4 Boron‐Containing Seven‐Membered Rings: Borepins

1.5 Boron‐Containing Six‐Membered Rings: Diborins

1.6 Planarized Triphenylboranes and Boron‐Doped Nanographenes

1.7 Conclusion and Outlook

References

2 Organoborane Donor-Acceptor Materials

2.1 Organoboranes: Form and Functions

2.2 Linear D‐A Systems

2.3 Non‐conjugated D‐A Organoboranes

2.4 Conjugated Nonlinear D‐A Systems

2.5 Polymeric Systems

2.6 Cyclic D‐A Systems: Macrocycles and Fused‐Rings

2.7 Conclusions and Outlook

3 Photoresponsive Organoboron Systems

3.1 Introduction

3.2 Photoreactivity of (ppy)BMes2 and Related Compounds

3.3 Photoreactivity of BN‐Heterocycles

3.4 New Photochromism of BN‐Heterocycles

3.5 Exciton Driven Elimination (EDE): In situ Fabrication of OLEDs

3.6 Summary and Future Prospects

4 Incorporation of Group 13 Elements into Polymers

4.1 Introduction

4.2 Tricoordinate Boron in Conjugated Polymers

4.3 Tetracoordinate Boron Chelate Complexes in Polymeric Materials

4.4 Polymeric Materials with B‐P and B‐N in the Backbone

4.5 Polymeric Materials Containing Borane and Carborane Clusters

4.6 Polymeric Materials Containing Higher Group 13 Elements

4.7 Conclusions

Acknowledgements

5 Tetracoordinate Boron Materials for Biological Imaging

5.1 Introduction

5.2 Small Molecule Fluorescence Imaging Agents

5.3 Polymer Conjugated Materials

5.4 Conclusion and Future Outlook

6 Advances and Properties of Silanol‐Based Materials.

6.1 Introduction

6.2 Preparation

6.3 Reactivity

6.4 Properties and Application

7 Silole‐Based Materials in Optoelectronics and Sensing

7.1 Introduction

7.2 Basic Aspects of Silole‐Based Materials

7.3 Silole‐Based Electron‐Transporting Materials

7.4 Silole‐Based Host and Hole‐Blocking Materials for OLEDs

7.5 Silole‐Based Light‐Emitting Materials

7.6 Silole‐Based Semiconducting Materials

7.7 Silole‐Based Light‐Harvesting Materials for Solar Cells

7.8 Silole‐Based Sensing Materials

7.9 Conclusion

8 Materials Containing Homocatenated Polysilanes

8.1 Introduction

8.2 Synthesis

8.3 Functional Modification of Polysilanes

8.4 Control of the Stereochemistry of Polysilanes

8.5 Control of the Secondary Structure of Polysilanes

8.6 Polysilanes with 3D Architectures

8.7 Applications

8.8 Summary

9 Catenated Germanium and Tin Oligomers and Polymers

9.1 Introduction

9.2 Oligogermanes and Oligostannanes

9.3 Preparation of Polygermanes

9.4 Preparation of Polystannanes

9.5 Conclusions and Outlook

10 Germanium and Tin in Conjugated Organic Materials

10.1 Introduction

10.2 Germanium and Tin‐Linked Conjugated Polymers

10.3 Germanium‐ and Tin‐Containing Conjugated Cyclic Systems

10.4 Summary and Outlook

11 Phosphorus‐Based Porphyrins

11.1 Introduction

11.2 Porphyrins Bearing Phosphorus‐Based Functional Groups at their Periphery

11.3 Porphyrins and Related Macrocycles Containing Phosphorus Atoms at their Core

11.4 Conclusions

12 Applications of Phosphorus‐Based Materials in Optoelectronics

12.1 Introduction

12.2 Phosphines

12.3 Four‐Membered P‐Heterocyclic Rings

12.4 Five‐Membered P‐Heterocyclic Rings: Phospholes.

12.5 Six‐Membered P‐Heterocyclic Rings

12.6 Conclusion

Abbreviations

13 Main‐Chain, Phosphorus‐Based Polymers

13.1 Introduction

13.2 Polyphosphazenes

13.3 Poly(phosphole)s

13.4 Poly(methylenephosphine)s

13.5 Poly(arylene‐/vinylene‐/ethynylene‐phosphine)s

13.6 Phospha‐PPVs

13.7 Poly(phosphinoborane)s

13.8 Metal‐Containing Phosphorus Polymers

13.9 Additional P‐Containing Polymers

13.10 Summary

14 Synthons for the Development of New Organophosphorus Functional Materials

14.1 General Introduction

14.2 Phosphorus Transfer Reagents as Emerging Synthetic Approaches to Materials

14.3 Carbene‐Stabilized Molecules as Phosphorus Reagents

14.4 Conclusions and Outlook

15 Arsenic‐Containing Oligomers and Polymers

15.1 Introduction

15.2 Chemistry of Organoarsenic Compounds

15.3 Arsenic Homocycles

15.4 Development of C-As Bond Formation for Organoarsenic Compounds

15.5 Properties of Poly(vinylene‐arsine)s

15.6 Properties of 1,4‐Dihydro‐1,4‐diarsinines

15.7 Properties of Arsole Derivatives

15.8 Arsole‐Containing Polymers

15.9 Conclusions

16 Antimony‐ and Bismuth‐Based Materials and Applications

16.1 Introduction

16.2 Anion Binding and Sensing Applications

16.3 Small‐Molecule Binding

16.4 Antimony and Bismuth Chromophores

16.5 Conclusion

17 High Sulfur Content Organic/Inorganic Hybrid Polymeric Materials

17.1 Introduction

17.2 The Chemistry of Liquid Sulfur

17.3 Waterborne Reactions of Polysulfides

17.4 Controlled Polymerization with High Sulfur‐Content Monomers

17.5 Modern Applications of High Sulfur‐Content Copolymers

17.6 Conclusion and Outlook

18 Selenium and Tellurium Containing Conjugated Polymers.

18.1 Introduction

18.2 Selenium‐Containing Conjugated Polymers

18.3 Tellurium‐Containing Conjugated Polymers

18.4 Conclusions and Outlook

19 Hypervalent Iodine Compounds in Polymer Science and Technology

19.1 Introduction

19.2 Applications of Hypervalent Iodine Compounds in Polymer Science and Technology

19.3 Conclusions

Index

End User License Agreement.

Notes:

Includes bibliographical references at the end of each chapters and index.

Description based on print version record.

ISBN:

9781119235965

1119235960

9781119235958

1119235952

9781119235941

1119235944

OCLC:

1017751353