Novel carbon materials and composites : synthesis, properties and applications / edited by Xin Jiang, Zhenhui Kang, Xiaoning Guo, Hao Zhuang.

Format:

Book

Contributor:

Jiang, Xin, (Chemist), editor.

Kang, Zhenhui, editor.

Guo, Xiaoning, editor.

Zhuang, Hao, editor.

Series:

Nanocarbon chemistry and interfaces

Language:

English

Subjects (All):

Carbon composites.

Physical Description:

xvi, 284 pages ; 26 cm.

Place of Publication:

Hoboken, NJ, USA : John Wiley & Sons, Inc., 2019.

Contents:

1 Cubic Silicon Carbide: Growth, Properties, and Electrochemical Applications p. 1 / Nianjun Yang and Xin Jiang

1.1 General Overview of Silicon Carbide p. 1

1.1.1 SiC Properties p. 1

1.1.2 SiC Applications p. 3

1.2 Synthesis of Silicon Carbide p. 4

1.2.1 Acheson Process p. 4

1.2.2 Physical Vapor Transport p. 5

1.2.3 Chemical Vapor Deposition p. 5

1.3 Properties of Cubic Silicon Carbide p. 9

1.3.1 Surface Morphology p. 9

1.3.2 Electrochemical Properties p. 12

1.3.3 Surface Chemistry p. 16

1.3.3.1 Surface Terminations p. 16

1.3.3.2 Surface Functionalization p. 17

1.4 Electrochemical Applications of Cubic Silicon Carbide Films p. 20

1.4.1 Electrochemical Sensors p. 20

1.4.2 Biosensors p. 20

1.4.3 Energy Storage p. 21

2 Application of Silicon Carbide in Photocatalysis p. 35 / Xiao-Ning Guo and Xi-Li Tong and Xiang-Yun Guo

2.1 Preparation of SiC with High Surface Area p. 36

2.1.1 Carbon Template Method p. 37

2.1.2 Sol-gel Method p. 40

2.1.3 Polycarbosilane Pyrolysis Method p. 42

2.2 Photocatalytic Water-Splitting p. 43

2.3 Photocatalytic Degradation of Pollutants p. 54

2.4 Photocatalytic Selective Organic Transformations p. 57

2.5 Photocatalytic CO₂ Reduction p. 66

3 Application of Silicon Carbide in Electrocatalysis p. 73 / Xiao-Ning Guo and Xi-Li Tong and Xiang-Yun Guo

3.1 Electrochemical Sensors p. 73

3.2 Direct Methanol Fuel Cells p. 76

3.3 Dye-sensitized Solar Cells p. 83

3.4 Lithium-ion Batteries p. 86

3.5 Supercapacitors p. 88

4 Carbon Nitride Fabrication and Its Water-Splitting Applications p. 99 / Yanhong Liu and Baodong Mao and Weidong Shi

4.2 Preparation of Pristine g-C₃N₄ p. 100

4.2.1 Effect of Precursors p. 102

4.2.2 Effect of Reaction Parameters p. 102

4.3 Bandgap Engineering by Doping and Copolymerization p. 104

4.3.1 Doping of g-C₃N₄ p. 104

4.3.1.1 C-doping and N-vacancy p. 104

4.3.1.2 S-doping p. 106

4.3.1.3 P-doping p. 106

4.3.1.4 Metal doping p. 107

4.3.2 Copolymerization of g-C₃N₄ p. 107

4.4 Nanostructure Engineering of g-C₃N₄ p. 109

4.4.1 Ordered Mesoporous Nanostructures of g-C₃N₄ p. 109

4.4.1.1 Hard Templating Methods p. 109

4.4.1.2 Soft Templating Methods p. 110

4.4.1.3 Template-free Methods p. 112

4.4.2 Exfoliation to 2D Nanosheets of g-C₃N₄ p. 113

4.4.3 0D Quantum Dots of g-C₃N₄ p. 115

4.5 g-C₃N₄ Composite Photocatalysts p. 117

4.5.1 Metal/g-C₃N₄ Heterojunctions p. 117

4.5.2 Graphitic Carbon/g-C₃N₄ Heterojunctions p. 120

4.5.3 Semiconductors/g-C₃N₄ Heterojunctions p. 122

4.5.3.1 Type-II Heterojunction p. 123

4.5.3.2 Z-scheme p. 124

4.5.3.3 0D/2D Heterostructures p. 124

4.5.3.4 g-C₃N₄ Homojunctions p. 125

4.5.3.5 Dyes Sensitization p. 126

4.5.4 Deposition of Earth-Abundant Cocatalysts p. 128

5 Carbon Materials for Supercapacitors p. 137 / Yanfang Gao and Zijun Shi and Lijun Li

5.2 Affecting Factors p. 139

5.2.1 Specific Surface Area p. 139

5.2.2 Pore Size p. 139

5.2.3 Surface Functional Groups p. 141

5.2.4 Electrical Conductivity p. 141

5.3 Electrolyte p. 142

5.3.1 Aqueous Electrolyte p. 142

5.3.2 Organic Electrolyte p. 143

5.3.3 Ionic Liquid Electrolytes p. 143

5.4 Electrode Materials p. 143

5.4.1 Activated Carbons p. 143

5.4.2 Graphene p. 148

5.4.3 Carbon Nanotubes p. 152

5.4.4 Carbide-Derived Carbon p. 157

5.4.5 Carbon Aerogels p. 159

6 Diamond/ß-SiC Composite Films p. 169 / Xin Jiang and Hao Zhuang and Haiyuan Fu

6.2 Deposition Instruments p. 169

6.3 Conditions of the CVD Process p. 170

6.4 Film Quantity (Phase Distribution, Orientation, and Crystallinity) and Characterization p. 172

6.5 Growth Mechanism p. 177

6.6.1 Improvement of the Film Adhesion p. 179

6.6.2 Biosensor Applications p. 181

6.6.3 Preferential Protein Absorption p. 186

6.6.4 Diamond Networks p. 192

6.7 Conclusions and Future Aspects p. 196

7 Diamond/Graphite Nanostructured Film: Synthesis, Properties, and Applications p. 205 / Nan Huang and Zhaofeng Zhai and Yuning Guo and Qingquan Tian and Xin Jiang

7.2 Synthesis of the D/G Nanostructured Film p. 206

7.3 Growth Mechanism of the D/G Nanostructured Film p. 208

7.4 Properties and Applications of the D/G Nanostructured Film p. 210

7.4.1 Mechanical Properties p. 210

7.4.2 Electrochemical Properties p. 212

7.4.3 Hybrid D/G Film Electrode for the Detection of Trace Heavy Metal Ions p. 214

7.4.4 Hybrid D/G Film Electrochemical Biosensor for DNA Detection p. 216

8 Carbon Nanodot Composites: Fabrication, Properties, and Environmental and Energy Applications p. 223 / Hui Huang and Yang Liu and Zhenhui Kang

8.2 Synthesis, Structure, and Properties p. 224

8.2.1 Synthesis of C-dots p. 224

8.2.2 Composition and Structure p. 225

8.2.3.1 Absorption p. 226

8.2.3.2 Photoluminescence p. 227

8.2.3.3 Photoinduced Electron Transfer Property p. 227

8.2.3.4 Electrochemiluminescence p. 227

8.2.3.5 Proton adsorption p. 229

8.2.3.6 Toxicity p. 229

8.3 C-dot-based Functional Nanocomposites p. 229

8.3.1 C-dots in Mesoporous Structures p. 229

8.3.2 C-dots in Polymers p. 232

8.3.3 C-dots as Building Blocks for Mesoporous Structures p. 232

8.4 Catalysis Application p. 235

8.4.1 C-dots as Photocatalysts p. 235

8.4.2 C-dots as Electro catalysts p. 239

8.4.3 Photocatalyst Design Based on C-dots p. 241

8.4.3.1 Metal Nanoparticle/C-dots Complex Photocatalyst p. 241

8.4.3.2 C-dots/Ag/Ag₃PW₁₂O₄₀ Photocatalysts p. 242

8.4.3.3 C-dots/TiO₂ Photocatalysts p. 243

8.4.3.4 CDs/Ag₃PO₄ Photocatalysts p. 244

8.4.3.5 CDs/Cu₂O Photocatalysts p. 244

8.4.3.6 C-dots/C₃N₄ Photocatalysts p. 245

8.4.3.7 C-dots/Enzyme Photocatalysts p. 245

8.4.4 Photoelectrochemical Catalyst Design Based on C-dots p. 246

8.4.5 Modulation of Electron/Energy Transfer States at the TiO₂-C-dots Interface p. 248

8.4.6 Electrocatalyst Design Based on C-dots p. 249

8.4.7 Surface Modifications Towards Catalyst Design p. 252

8.5 C-Dots for Sensing and Detection p. 252

8.5.1 PL Sensors p. 252

8.5.2 Electronic, Electrochemiluminescent and Electrochemical Sensors p. 255

8.5.3 C-dots for Humidity and Temperature Sensing p. 257

8.6 C-dots for Solar Energy p. 257

8.7 Application in Supercapacitors and Lithium-Ion Batteries p. 263

8.8 C-Dots Nanocomposite for Efficient Lubrication p. 264.

Notes:

Includes bibliographical references and index.

Other Format:

Online version: Novel carbon materials and composites

ISBN:

9781119313397

1119313392

OCLC:

1077574173