The aqueous chemistry of oxides / Bruce C. Bunker and William H. Casey.

Format:

Book

Author/Creator:

Bunker, Bruce C., author.

Casey, William Howard, author.

Series:

Oxford scholarship online.

Oxford scholarship online

Language:

English

Subjects (All):

Oxides.

Water chemistry.

Hydrolysis.

Physical Description:

1 online resource (645 p.)

Edition:

First edition.

Place of Publication:

New York, NY : Oxford University Press, 2020.

Language Note:

English

Summary:

'The Aqueous Chemistry of Oxides' is a comprehensive reference volume and special topics textbook that explores all of the major chemical reactions that take place between oxides and aqueous solutions.

Contents:

2.4. Oxides Containing Octahedral Cations2.5. Oxides Containing Tetrahedral Cations; 2.6. Oxides Containing Both Octahedral and Tetrahedral Cations; 2.7. Engineered Oxide Nanostructures; PART TWO Fundamental Oxide Reactions in Aqueous Solutions; 3. The Structure and Properties of Water; 4. Solvated Ions in Water; 4.1. Introduction; 4.2. Solvated Anions; 4.3. Solvated Cations; 4.4. The Structure of Solvated Cations; 4.5. The Acid-Base Properties of the First Solvation Shell; 4.6. Using Formal Charge Models to Predict and Rationalize pKa Values; 4.7. An Introduction to Ligand-Exchange Reactions

4.8. The Thermodynamics of Ligand Exchange4.9. The Kinetics of Ligand-Exchange Reactions; 5. The Hydrolysis Products: Soluble Multi-cation Clusters; 5.1. Introduction; 5.2. Structures of the Hydrolysis Products; 5.3. The Occurrence of Hydrolysis Products: Reading Hydrolysis Diagrams; 5.4. Trends in Cation Hydrolysis; 5.5. Hydrolysis Diagrams as Predictors of Oxide Chemistry; 5.6. Speciation Diagrams Involving Foreign Ligands; 5.7. The Acid-Base Chemistry of Multi-Cation Hydrolysis Products; 5.8. Mechanisms for Reversible Condensation Reactions

5.9. Hydrolysis Product Stability: Dimer Reaction Pathways5.10. The Stability of Larger Hydrolysis Products; 5.11. The Polyoxometalates: Covalent Oxide Clusters; 6. The Chemistry of Extended Oxide Surfaces; 6.1. Introduction; 6.2. Ideal Oxide Surfaces in the Absence of Water; 6.3. Interactions between Pristine Surfaces and Water Molecules; 6.4. The Interface between Liquid Water and Oxide Surfaces; 6.5. Acid-Base Reactions on Oxide Surfaces in Liquid Water; 6.6. Ligand-Exchange Reactions Involving Water: Oxide Dissolution; 6.7. Reactions Involving Foreign Ligands

PART THREE The Aqueous Synthesis and Processing of Oxides7. Nucleation and Growth of Solid Oxide and Hydroxide Phases; 7.1. Introduction; 7.2. Classic Nucleation Theory; 7.3. Chemical Control of Oxide Nucleation; 7.4. Classic Growth Theory; 8. The Colloidal Chemistry of Oxides; 8.1. Introduction; 8.2. Fundamental Colloidal Interactions; 8.3. The Chemical Origin of Surface Charge; 8.4. The Impact of Aggregation on the Properties of Colloidal Slurries; 8.5. Ceramic Processing: The Role of Organic Additives; 9. Bio-inspired Synthesis of Oxide Nanostructures; 9.1. Introduction

9.2. Hierarchical Self-Assembly: From Molecules to Template Architectures

Notes:

This edition previously issued in print: 2016.

Includes bibliographical references and index.

Description based on print version record.

ISBN:

0-19-756298-1

1-5231-2130-0

0-19-938426-6