Advanced electrode materials / edited by Ashutosh Tiwari, Filiz Kuralay and Lokman Uzun.

Format:

Book

Contributor:

Tiwari, Ashutosh, editor.

Kuralay, Filiz, editor.

Uzun, Lokman, editor.

Series:

Advanced materials series (Scrivener Publishing)

Advanced Materials Series

Language:

English

Subjects (All):

Electric batteries--Electrodes--Materials.

Electric batteries.

Electrochemistry.

Nanostructured materials.

Physical Description:

1 online resource (533 pages) : illustrations.

Edition:

1st ed.

Place of Publication:

Beverly, Massachusetts : Scrivener Publishing, [2016]

Summary:

This book covers the recent advances in electrode materials and their novel applications at the cross-section of advanced materials. The book is divided into two sections: State-of-the-art electrode materials; and engineering of applied electrode materials. The chapters deal with electrocatalysis for energy conversion in view of bionanotechnology; surfactant-free materials and polyoxometalates through the concepts of biosensors to renewable energy applications; mesoporous carbon, diamond, conducting polymers and tungsten oxide/conducting polymer-based electrodes and hybrid systems. Numerous approaches are reviewed for lithium batteries, fuel cells, the design and construction of anode for microbial fuel cells including phosphate polyanion electrodes, electrocatalytic materials, fuel cell reactions, conducting polymer based hybrid nanocomposites and advanced nanomaterials.

Contents:

Cover

Title Page

Copyright Page

Contents

Preface

Part 1 State-of-the-Art Electrode Materials

1 Advances in Electrode Materials

1.1 Advanced Electrode Materials for Molecular Electrochemistry

1.1.1 Graphite and Related sp2-Hybridized Carbon Materials

1.1.2 Graphene

1.1.2.1 Graphene Preparation

1.1.2.2 Engineering of Graphene

1.1.3 Carbon Nanotubes

1.1.3.1 Carbon Nanotube Networks for Applications in Flexible Electronics

1.1.4 Surface Structure of Carbon Electrode Materials

1.2 Electrode Materials for Electrochemical Capacitors

1.2.1 Carbon-based Electrodes

1.2.2 Metal Oxide Composite Electrodes

1.2.3 Conductive Polymers-based Electrodes

1.2.4 Nanocomposites-based Electrode Materials for Supercapacitor

1.3 Nanostructure Electrode Materials for Electrochemical Energy Storage and Conversion

1.3.1 Assembly and Properties of Nanoparticles

1.4 Progress and Perspective of Advanced Electrode Materials

Acknowledgments

References

2 Diamond-based Electrodes

2.1 Introduction

2.2 Techniques for Preparation of Diamond Layers

2.2.1 HF-CVD Diamond Synthesis

2.2.2 MW-CVD Diamond Synthesis

2.2.3 RF-CVD Diamond Synthesis

2.3 Why Diamond for Electrodes?

2.4 Diamond Doping

2.4.1 In Situ Diamond Doping

2.4.2 Ion Implantation

2.5 Electrochemical Properties of Doped Diamonds

2.6 Diamond Electrodes Applications

2.6.1 Water Treatment and Disinfection

2.6.2 Electroanalytical Sensors

2.6.3 Energy Technology

2.6.3.1 Supercapacitors

2.6.3.2 Li Ion Batteries

2.6.3.3 Fuel Cells

2.7 Conclusions

3 Recent Advances in Tungsten Oxide/Conducting Polymer Hybrid Assemblies for Electrochromic Applications

3.1 Introduction

3.2 History and Technology of Electrochromics

3.3 Electrochromic Devices

3.3.1 Electrochromic Contrast.

3.3.2 Coloration Efficiency

3.3.3 Switching Speed

3.3.4 Stability

3.3.5 Optical Memory

3.4 Transition Metal Oxides

3.5 Tungsten Oxide

3.6 Conjugated Organic Polymers

3.7 Hybrid Materials

3.8 Electrochromic Tungsten Oxide/Conducting Polymer Hybrids

3.9 Conclusions and Perspectives

4 Advanced Surfactant-free Nanomaterials for Electrochemical Energy Conversion Systems: From Electrocatalysis to Bionanotechnology

4.1 Advanced Electrode Materials Design: Preparation and Characterization of Metal Nanoparticles

4.1.1 Current Strategies for Metal Nanoparticles Preparation: General Consideration

4.1.2 Emerged Synthetic Methods without Organic Molecules as Surfactants

4.2 Electrocatalytic Performances Toward Organic Molecules Oxidation

4.2.1 Electrocatalytic Properties of Metal Nanoparticles in Alkaline Medium

4.2.1.1 Electrocatalytic Properties Toward Glycerol Oxidation

4.2.1.2 Electrocatalytic Properties Toward Carbohydrates Oxidation

4.2.2 Spectroelectrochemical Characterization of the Electrode-Electrolyte Interface

4.2.2.1 Spectroelectrochemical Probing of Electrode Materials Surface by CO Stripping

4.2.2.2 Spectroelectrochemical Probing of Glycerol Electrooxidation Reaction

4.2.2.3 Spectroelectrochemical Probing of Glucose Electrooxidation Reaction

4.2.3 Electrochemical Synthesis of Sustainable Chemicals: Electroanalytical Study

4.2.4 Electrochemical Energy Conversion: Direct Carbohydrates Alkaline Fuel Cells

4.3 Metal Nanoparticles at Work in Bionanotechnology

4.3.1 Metal Nanoparticles at Work in Closed-biological Conditions: Toward Implantable Devices

4.3.2 Activation of Implantable Biomedical and Information Processing Devices by Fuel Cells

4.4 Conclusions

Notes

References.

Part 2 Engineering of Applied Electrode Materials

5 Polyoxometalate-based Modified Electrodes for Electrocatalysis: From Molecule Sensing to Renewable Energy-related Applications

5.1 Introduction

5.2 POMs and POMs-based (Nano)Composites

5.2.1 Polyoxometalates

5.2.2 Polyoxometalate-based (Nano)Composites

5.2.3 General Electrochemical Behavior of POMs

5.3 POMs-based Electrocatalysis for Sensing Applications

5.3.1 Reductive Electrocatalysis

5.3.1.1 Nitrite Reduction

5.3.1.2 Bromate Reduction

5.3.1.3 Iodate Reduction

5.3.1.4 Hydrogen Peroxide Reduction Reaction

5.3.2 Oxidative Electrocatalysis

5.3.2.1 Dopamine and Ascorbic Acid Oxidations

5.3.2.2 L-Cysteine Oxidation

5.4 POMs-based Electrocatalysis for Energy Storage and Conversion Applications

5.4.1 Oxygen Evolution Reaction

5.4.2 Hydrogen Evolution Reaction

5.4.3 Oxygen Reduction Reaction

5.5 Concluding Remarks

List of Abbreviations and Acronyms

6 Electrochemical Sensors Based on Ordered Mesoporous Carbons

6.1 Introduction

6.2 Electrochemical Sensors Based on OMCs

6.3 Electrochemical Sensors Based on Redox Mediators/OMCs

6.4 Electrochemical Sensors Based on NPs/OMCs

6.4.1 Electrochemical Sensors Based on Transition Metal NPs/OMCs

6.4.2 Electrochemical Sensors Based on Noble Metal NPs/OMCs

6.5 Conclusions

7 Non-precious Metal Oxide and Metal-free Catalysts for Energy Storage and Conversion

7.1 Metal-Nitrogen-Carbon (M-N-C) Electrocatalysts

7.1.1 Introduction

7.1.2 Catalysts for Hydrogen Evolution Reaction

7.1.3 Catalysts for Oxygen Evolution Reaction

7.1.4 Catalysts for Oxygen Reduction Reaction

7.1.5 None-heat-treated M-N-C Electrocatalysts

7.1.6 Heat-treated M-N-C Electrocatalysts

7.1.7 Conclusion.

7.2 Transition Metal Oxide Electrode Materials for Oxygen Evolution Reaction, Oxygen Reduction Reaction and Bifuctional Purposes (OER/ORR)

7.2.1 Introduction

7.2.2 Oxygen Evolution Reaction

7.2.2.1 Synthesis Methodology

7.2.2.2 OER Properties of Catalyst

7.2.2.3 Morphology or Microstructure Analysis of TM Oxide for OER

7.2.3 Oxygen Reduction Reaction

7.2.3.1 Morphology or Microstructure Analysis

7.2.3.2 ORR Properties of Catalyst

7.2.3.3 Synthesis Methodology

7.2.3.4 Theoretical Analyses of ORR Active Catalysts

7.2.4 Hydrogen Evolution Reaction

7.2.5 Bifunctional Oxide Materials (OER/ORR)

7.2.5.1 Bifunctional Properties of Catalyst

7.2.5.2 Dopant Effects

7.2.5.3 Morphology or Microstructure Analysis

7.2.5.4 Synthesis Methodology

7.2.6 Conclusion

7.3 Transition Metal Chalcogenides, Nitrides, Oxynitrides, and Carbides

7.3.1 Transition Metal Chalcogenides

7.3.2 Transition Metal Nitrides

7.3.3 Transition Metal Oxynitrides

7.3.4 Transition Metal Carbides

7.4 Oxygen Reduction Reaction for Metal-free

7.4.1 Different Doping Synthesis Strategies

7.4.2 ORR Activity in Different Carbon Source

7.4.2.1 1D Carbon Nanotube Doped

7.4.2.2 2D Graphene

7.4.3 Oxygen Evolution Reaction

8 Study of Phosphate Polyanion Electrodes and Their Performance with Glassy Electrolytes: Potential Application in Lithium Ion Solid-state Batteries

8.1 Introduction

8.2 Glass Samples Preparation

8.3 Nanostructured Composites Sample Preparation

8.4 X-ray Powder Diffraction

8.4.1 X-ray Powder Diffraction Patterns of Glassy Materials

8.4.2 X-ray Powder Diffraction Patterns of Composites Materials

8.5 Thermal Analysis

8.5.1 Thermal Analysis of Glassy Systems

8.5.2 Thermal Analysis of Nanocomposites Materials

8.6 Density and Appearance.

8.6.1 Density and Oxygen Packing Density of Glassy Materials

8.6.2 Materials' Appearance

8.6.2.1 Glasses

8.6.2.2 Nanostructured Composites

8.7 Structural Features

8.7.1 Glassy Materials

8.7.1.1 FTIR and Raman Spectroscopy

8.7.2 Nanocomposites Materials

8.8 Electrical Behavior

8.8.1 Glasses Materials

8.8.2 Composite Materials

8.9 All-solid-state Lithium Ion Battery

8.10 Final Remarks

9 Conducting Polymer-based Hybrid Nanocomposites as Promising Electrode Materials for Lithium Batteries

9.1 Introduction

9.2 Electrode Materials of Lithium Batteries Based on Conducting Polymer-based Nanocomposites Prepared by Chemical and Electrochemical Methods

9.2.1 Host-guest Hybrid Nanocomposites

9.2.2 Core-shell Hybrid Nanocomposites

9.3 Mechanochemical Preparation of Conducting Polymer-based Hybrid Nanocomposites as Electrode Materials of Lithium Batteries

9.3.1 Principle of Mechanochemical Synthesis

9.3.2 Mechanochemically Prepared Conducting Polymer-based Hybrid Nanocomposite Materials for Lithium Batteries

9.4 Conclusion

10 Energy Applications: Fuel Cells

10.1 Introduction

10.2 Catalyst Supports for Fuel Cell Electrodes

10.2.1 Commercial Carbon Supports

10.2.2 Carbon Nanotube (CNT) Supports

10.2.3 Graphene Supports

10.2.4 Mesoporous Carbon Supports

10.2.5 Other Carbon Supports

10.2.6 Conducting Polymer Supports

10.2.7 Hybrid Supports

10.2.8 Non-carbon Supports

10.3 Anode and Cathode Catalysts for Fuel Cells

10.3.1 Anode Catalysts

10.3.2 Cathode Catalysts

10.4 Conclusions

11 Novel Photoelectrocatalytic Electrodes Materials for Fuel Cell Reactions

11.1 Introduction

11.2 Basic Understanding on the Improved Catalytic Performance of Photo-responsive Metal/Semiconductor Electrodes.

11.3 Synthetic Methods for Metal/Semiconductor Electrodes.

Notes:

Includes bibliographical references and index.

Includes index.

Description based on print version record.

ISBN:

9781119242857

1119242851

9781119242840

1119242843

9781119242659

1119242657

OCLC:

962451083