Metallomacrocycles : from structures to applications / edited by Hai-Bo Yang.

Format:

Book

Contributor:

Yang, Hai-Bo, editor.

Series:

Monographs in supramolecular chemistry ; no. 27.

Monographs in supramolecular chemistry, 1368-8642 ; no. 27

Language:

English

Subjects (All):

Supramolecular organometallic chemistry.

Physical Description:

xiii, 289 pages : illustrations (some color) ; 24 cm.

Place of Publication:

London : Royal Society of Chemistry, [2019]

Contents:

Chapter 1 Evolution of Metallomacrocycles From Macrocycles p. 1 / Wei Zheng and Shu-Ting Jiang and Bo Jiang and Hai-Bo Yang

1.1 Macrocycles p. 1

1.2 Coordination-driven Self-assembly p. 3

1.3 Two-dimensional Assembly of Metallomacrocycles p. 6

1.4 Characterization of Metallomacrocycles p. 11

1.4.1 Mass Spectrometry p. 11

1.4.2 X-ray Measurement p. 13

1.5 The Essential Characteristic of Metallomacrocycles p. 14

1.5.1 Charged Systems p. 14

1.5.2 The Dynamic Characteristic of Metallomacrocycles p. 15

Chapter 2 Design Principles of Self-assembled Metallomacrocycles p. 20 / Bo Jiang and Bo Ou and Hai-Bo Yang

2.2 The Directional-bonding Approach p. 21

2.2.1 Molecular Rhomboids p. 23

2.2.2 Molecular Triangles p. 25

2.2.3 Molecular Squares p. 30

2.2.4 Molecular Hexagons p. 35

2.3 The Symmetry-interaction Approach p. 37

2.4 The Weak-link Approach p. 39

Chapter 3 Self-organization in Coordination-driven Self-assembled Metallomacrocyles p. 47 / Xu-Qing Wang and Wei-Jian Li and Hai-Bo Yang

3.2 Two-component Self-organization Systems p. 48

3.3 Three-component Self-organization Systems p. 54

3.4 Multicomponent Self-organization Systems p. 65

Chapter 4 Self-assembled Chiral Metallomacrocycles p. 77 / Li-Jun Chen and Jun-Long Zhu and Hai-Bo Yang

4.2 Synthetic Strategies for Self-assembled Chiral Metallomacrocycles p. 78

4.2.1 Introduction of Chiral Bridging Ligands p. 78

4.2.2 Use of Chiral Metal Auxiliaries that Possess Chiral Capping Groups p. 89

4.2.3 Use of Inherently Chiral Metal Centres Having Specific Coordination Geometries p. 92

4.3 Applications of Self-assembled Chiral Metallomacrocycles p. 95

4.3.1 Chiral Sensing p. 96

4.3.2 Asymmetric Catalysis p. 98

Chapter 5 Half-sandwich Iridium- and Rhodium-based Organometallic Macrocyeles p. 106 / Ying-Feng Han and Guo-Xin Jin

Chapter 6 Supramolecular Transformations of Metallomacrocycles p. 120 / Wei Wang

6.2 Supramolecular Transformations Between Metallomacrocycles and One-dimensional Metallosupramolecular Polymers p. 121

6.3 Supramolecular Transformations Between Metallomacrocycles and Another Two-dimensional Metallomacrocycles p. 124

6.4 Supramolecular Transformations Between Metallomacrocycles and 3D Metallocages p. 142

Chapter 7 Coordination-driven Self-assembly of Functionalized Self-assembled Metallomacrocycles p. 152 / M. R. Crawley and T. R. Cook

7.1.1 Sites of Functionalization p. 155

7.1.2 Pre- versus Post-self-assembly p. 157

7.2 Photophysical Properties p. 159

7.2.2 Covalently Append Dyes p. 159

7.2.3 Sensor Applications p. 162

7.2.4 Effects of Functional Groups on Photophysical Properties p. 164

7.2.5 BODIPY-functionalized Metallomacrocycles p. 164

7.3 Electrochemically Active Materials p. 166

7.3.2 Functionalization with dppf Ligands p. 166

7.3.3 Covalently Tethered Ferrocene p. 167

7.3.4 Fc/Dendrimer Hybrid Materials p. 171

7.4 Dendrimer and Polymer Interfaces p. 173

7.4.2 Functionalized Building Block Approach to Dendrimer-functionalized Metallacycles p. 174

7.4.3 Metallacycles with Polymeric Functionalities p. 177

7.5 Host-Guest Chemistry p. 180

7.5.2 Cation Functionalized for Host-Guest Chemistry p. 181

7.5.3 Pendant Groups for Host-Guest Chemistry p. 181

7.5.4 Host-Guest Sensors p. 184

7.6 Catalytically Active Species p. 184

7.6.2 Synthetic Organic Catalysis p. 185

7.6.3 Small-molecule Activation p. 189

Chapter 8 Higher-order Supramolecular Systems Derived From Self-assembled Metallomacrocycles p. 195 / Li-Jun Chen and Jun-Long Zhu and Hai-Bo Yang

8.2 Hydrophobic/Hydrophilic Effects as Secondary Driving Force p. 197

8.3 Hydrogen Bonding as Secondary Driving Force p. 202

8.4 π-π Stacking and CH-π Interaction Imposed by Dendrimers as Secondary Driving Force p. 206

8.5 Host-Guest Interaction as Secondary Driving Force p. 210

8.6 Electrostatic Interactions as Secondary Driving Force p. 214

8.7 Multiple Secondary Driving Forces p. 216

Chapter 9 Applications of Self-assembled Metallomacrocycles I: Biological Applications p. 226 / Nem Singh and Se Chan Rang and Ki-Whan Chi

9.2 Anticancer Activity of Self-assembled Metallomacrocycles p. 227

9.2.1 Anticancer Activity of Ru-based Metallomacrocycles p. 228

9.2.2 Anticancer Activities of Metallomacrocycles of Other Transition Metals p. 235

9.3 Studies Conducted on Metallomacrocycle Binding with DNA and Proteins p. 237

9.3.1 Metallomacrocycle-DNA Binding p. 237

9.3.2 Metallacyele-Protein Binding p. 240

9.4 Drug Delivery Using Metallomacrocycles p. 241

9.5 Biological Evaluation Experiments p. 243

9.5.1 Human Cell Culture p. 243

9.5.2 In vitro Cytotoxicity Assay p. 244

9.5.3 In vitro Drug Release Kinetics p. 244

9.5.4 In vitro Fluorescence Microscopy of PDTC/DOX-loaded Nanoparticles p. 244

9.5.5 Clonogenic Survival Assay p. 244

9.5.6 Detection of Apoptotic Cells p. 245

Chapter 10 Applications of Self-assembled Metallomacrocycles II: Catalysis and Sensing p. 251 / Lin Xu and Yi-Xiong Hu and Partha Sarathi Mukherjee

10.2 Self-assembled Metallomacrocycles for Catalysis Applications p. 252

10.3 Self-assembled Metallomacrocycles for Sensing p. 260.

Notes:

Includes bibliographical references and index.

ISBN:

9781782628583

1782628584

OCLC:

1036730227