Enantioselective cobalt-catalysed transformations / by Hélène Pellissier.

Format:

Book

Author/Creator:

Pellissier, Hélène, editor.

Series:

RSC catalysis series ; no. 35.

Catalysis series ; no. 35

Language:

English

Subjects (All):

Cobalt catalysts.

Enantioselective catalysis.

Physical Description:

xvi, 223 pages : illustrations ; 24 cm.

Place of Publication:

[London] : Royal Society of Chemistry, [2018]

Contents:

Chapter 1 Enantioselective Cobalt-catalysed [2+1] Cycloadditions p. 1

1.2 Cyclopropanations p. 1

1.2.1 Intermolecular Cyclopropanations p. 1

1.2.2 Intramolecular Cyclopropanations p. 20

1.3 Aziridinations and Epoxidations p. 22

1.3.1 Aziridinations p. 22

1.3.2 Epoxidations p. 26

Chapter 2 Other Enantioselective Cobalt-catalysed Cycloadditions p. 34

2.1 Enantioselective Cobalt-Catalysed (Hetero)-Diels-Alder Cycloadditions p. 34

2.1.1 Diels-Alder Cycloadditions p. 34

2.1.2 Hetero-Diels-Alder Cycloadditions p. 36

2.2 Enantioselective Cobalt-Catalysed 1,3-Dipolar Cycloadditions p. 40

2.3 Enantioselective Cobalt-catalysed [2+2+2] and [2+2+1] Cycloadditions p. 46

2.3.1 [2+2+2] Cycloadditions p. 46

2.3.2 [2+2+1] Cycloadditions p. 50

2.4 Other Enantioselective Cobalt-Catalysed Cycloadditions p. 53

Chapter 3 Enantioselective Cobalt-catalysed Cyclisations Through Domino Reactions p. 62

Chapter 4 Miscellaneous Enantioselective Cobalt-catalysed Cyclisations p. 75

4.1 Using Salen Ligands p. 75

4.2 Using Biphosphine Ligands p. 84

4.3 Using Porphyrin Ligands p. 86

4.4 Using Other Ligands p. 88

Chapter 5 Synthesis of Chiral Acyclic Compounds Through Enantioselective Cobalt-catalysed Reduction Reactions p. 95

5.1 Reductions of Carbonyl Compounds and Derivatives p. 95

5.1.1 Borohydride Reductions p. 95

5.1.2 Hydrosilylations p. 105

5.1.3 Hydrogenations p. 109

5.2 Reductions of Alkenes p. 111

5.2.1 Reductions with Borane Derivatives p. 111

5.2.2 Hydrosilylations p. 119

5.2.3 Hydrogenations p. 120

Chapter 6 Synthesis of Chiral Acyclic Compounds Through Enantioselective Cobalt-catalysed Ring-Opening Reactions p. 129

6.1 Hydrolytic and Alcoholytic Ring-Opening of Epoxides p. 129

6.2 Ring-Opening of Epoxides by Amines and Carbamates p. 140

6.3 Ring-Opening of Epoxides Through (Co)polymerisation p. 143

Chapter 7 Synthesis of Chiral Acyclic Compounds Through Enantioselective Cobalt-catalysed Michael and (Nitro)-Aldol Reactions p. 155

7.1 Michael Reactions p. 155

7.1.1 Michael Additions to α,ß-Unsaturated Carbonyl Compounds and Derivatives p. 155

7.1.2 Michael Additions to Nitroolefins p. 160

7.2 (Nitro)-Aldol Reactions p. 167

Chapter 8 Synthesis of Chiral Acyclic Compounds Through Enantioselective Cobalt-catalysed 1,2-Nucleophilic Additions to Carbonyl Compounds and Derivatives p. 178

Chapter 9 Synthesis of Chiral Acyclic Compounds Through Enantioselective Cobalt-catalysed Cross-coupling Reactions p. 188

Chapter 10 Synthesis of Chiral Acyclic Compounds Through Enantioselective Cobalt-catalysed Hydrovinylation Reactions p. 196

Chapter 11 Synthesis of Chiral Acyclic Compounds Through Miscellaneous Enantioselective Cobalt-catalysed Reactions p. 204

11.1 α-Funationalisations and α-Alkylations of Carbonyl Compounds p. 204

11.2 Carbonyl-ene Reactions p. 207

11.3 Other Reactions p. 209.

Notes:

Includes bibliographical references and index.

ISBN:

1788014626

9781788014625

OCLC:

1030592196