The chemistry of metal-organic frameworks : synthesis, characterization, and applications / edited by Stefan Kaskel.

Format:

Book

Contributor:

Kaskel, Stefan, editor.

Language:

English

Subjects (All):

Organometallic chemistry.

Physical Description:

1 online resource (1,070 pages)

Edition:

1st ed.

Place of Publication:

Weinheim, Germany : Wiley, 2016.

Summary:

Providing vital knowledge on the design and synthesis of specific metal-organic framework (MOF) classes as well as their properties, this ready reference summarizes the state of the art in chemistry. Divided into four parts, the first begins with a basic introduction to typical cluster units or coordination geometries and provides examples of recent and advanced MOF structures and applications typical for the respective class. Part II covers recent progress in linker chemistries, while special MOF classes and morphology design are described in Part III. The fourth part deals with advanced characterization techniques, such as NMR, in situ studies, and modelling. A final unique feature is the inclusion of data sheets of commercially available MOFs in the appendix, enabling experts and newcomers to the field to select the appropriate MOF for a desired application. A must-have reference for chemists, materials scientists, and engineers in academia and industry working in the field of catalysis, gas and water purification, energy storage, separation, and sensors.

Contents:

Intro

Related Titles

Title Page

Copyright

Table of Contents

List of Contributors

Volume 1

Chapter 1: Introduction

Chapter 2: Network Topology

2.1 Introduction

2.2 Crystal Structures and MOFs Regarded as Nets

2.3 Some Introductory Remarks about Graphs, Topology, and Symmetry

2.4 Nomenclature of and Symbols for Nets - or What Does 4.4.4.4.4.4.4.4.4.4.4.4.*.*.* Mean?

2.5 Characterization of Nets in the Spirit of the RCSR

2.6 Derived Nets: Relationships Between Nets

2.7 Simplification of MOFs and Linkers or the Famous Case "4-c versus 2 Times 3-c"

2.8 A Very Short Survey on Common and Not So Common Nets: The Minimal Transitivity Principle

2.9 Summary and Conclusions

Acknowledgment

References

Part I: MOF Chemistry of Metallic Clusters and Other Nodes

Chapter 3: Reticular Chemistry of Metal-Organic Frameworks Composed of Copper and Zinc Metal Oxide Secondary Building Units as Nodes

3.1 Introduction

3.2 Secondary Building Units (SBUs): The Design Principles of MOFs

3.3 Points of Extension

3.4 Concluding Remarks

Chapter 4: Alkaline Earth Metal-Based Metal-Organic Frameworks: Synthesis, Properties, and Applications

4.1 Introduction

4.2 Synthesis

4.3 Structures

4.4 Properties and Applications

4.5 Conclusions and Outlook

Acknowledgments

Chapter 5: Synthesis, Structure, and Selected Properties of Aluminum-, Gallium-, and Indium-Based Metal-Organic Frameworks

5.1 Introduction

5.2 Properties of Al3+, Ga3+, and In3+ ions

5.3 Synthesis and Characterization of G13-MOFs

5.4 Prevalent Framework Structures and Inorganic Building Units in G13-MOFs

5.5 Selected G13-MOFs

5.6 Selected Aspects of G13-MOFs

Chapter 6: Group 4 Metals as Secondary Building Units: Ti, Zr, and Hf-based MOFs.

6.1 Introduction

6.2 Zirconium-Based MOFs

6.3 Summary and Conclusions

Chapter 7: Iron and Groups V- and VI-based MOFs

7.1 Introduction: The Chemistry in Solution

7.2 MOFs Based on Iron, Chromium, or Vanadium

7.3 MOFs Based on Nb, Ru, Mo, and W

7.4 Synthesis at the Nanoscale

7.5 Properties

7.6 Conclusion

Chapter 8: Platinum Group Metal-Organic Frameworks

8.1 Introduction

8.2 Single Node Frameworks

8.3 Metalloligands for the Construction of Mixed Metal-Organic Frameworks (M′MOFs)

8.4 Hofmann-Type MOFs

8.5 Coordination Polymers with Paddle-Wheel Metal Clusters

8.6 Summary and Conclusions

Chapter 9: Group 3 Elements and Lanthanide Metals

9.1 Introduction

9.2 Chemistry and Structures of Group 3 and Lanthanide-Based MOFs

9.3 Electronic and Optical Properties of Group 3 and Lanthanide-Based MOFs

9.4 Summary and Conclusions

Part II: Functional Linkers

Chapter 10: Extended Linkers for Ultrahigh Surface Area Metal-Organic Frameworks

10.1 Introduction

10.2 Brief Introduction of the History of Porous MOFs

10.3 General Synthetic Strategy for Extended Organic Linkers

10.4 Case Studies of Extended Linkers

10.5 Summary and Conclusions

Chapter 11: Porous Metal Azolate Frameworks

11.1 Introduction

11.2 Imidazolate Coordination Modes

11.3 Pyrazolate Coordination Modes

11.4 Triazolate Coordination Modes

11.5 Tetrazolate and Other Coordination Modes

11.6 Summary and Conclusions

Chapter 12: Functional Linkers for Catalysis

12.1 Introduction: MOF in Catalysis

12.2 Self-Assembled Frameworks

12.3 Postsynthetic Modification

12.4 Relevant and Accurate Characterizations as Key for the Design of MOF Catalyst

References.

Chapter 13: Chiral Linker Systems

13.1 Introduction

13.2 Section A: Classes of Chiral Linkers

13.3 Section B: Enantioselective Separation and Chromatography with Chiral MOFs

13.4 Summary and Conclusions

Chapter 14: Functional Linkers for Electron-Conducting MOFs

14.1 Introduction

14.2 Methods for Measuring Electrical Properties

14.3 Linkers

14.4 Conclusion and Perspective

Chapter 15: Linkers with Optical Functionality

15.1 Linker Electronic Structure

15.2 Design Principles

15.3 Linkers for Light Harvesting

15.4 Bioimaging

15.5 Linkers for Chemical Sensing

15.6 Radiation Detection

15.7 Conclusions

Volume 2

Part III: Special MOF Classes and Morphology Design of MOFs

Chapter 16: Nanoparticles

16.1 Introduction

16.2 Nanoparticles

16.3 Synthesis of MOF Nanoparticles

16.4 Engineering MOF Nanoparticles

16.5 Application of MOF Nanoparticles

16.6 Nanotoxicology

16.7 Summary and Conclusions

Chapter 17: SURMOFs: Liquid-Phase Epitaxy of Metal-Organic Frameworks on Surfaces

17.1 Introduction

17.2 Fabrication of Novel MOF Materials by LPE-Based Synthesis

17.3 Heterostructured SURMOFs (Hetero-SURMOFs)

17.4 Postsynthetic Modification of SURMOFs

17.5 SURMOFs as New Investigation Platform to Determine MOF Properties

17.6 Advanced Applications

17.7 Conclusion

Chapter 18: Granulation and Shaping of Metal-Organic Frameworks

18.1 Introduction

18.2 Granulation

18.3 Spray Drying

18.4 Extrusion

18.5 Pressing

18.6 Summary

Part IV: Progress in Advanced Characterization of MOFs

Chapter 19: Adsorption Methodology

19.1 Introduction

19.2 Sample Preparation for Adsorption Measurements.

19.3 Porosity Determination

19.4 Enthalpy of Adsorption and Isosteric Enthalpy of Adsorption

19.5 High Pressure Adsorption: Fundamentals and Practical Aspects

19.6 Summary and Conclusions

Chapter 20: Nuclear Magnetic Resonance of Metal-Organic Frameworks (MOFs)

20.1 Solid-State NMR Spectroscopy: A Brief Introduction

20.2 Applications of Solid-State NMR Spectroscopy to Study the MOF Lattice

20.3 NMR Spectroscopic Studies of Host-Guest Interactions

20.4 Summary and Conclusions

Chapter 21: Electron Paramagnetic Resonance

21.1 Introduction

21.2 EPR Spectroscopy

21.3 Applications of EPR in MOF Science

21.4 Conclusions

Chapter 22: IR and Raman Spectroscopies Probing MOFs Structure, Defectivity, and Reactivity

22.1 Introduction

22.2 Raman and IR Spectroscopy to Check the Synthesis Product

22.3 Spectroscopic Monitoring of Gas Adsorption

22.4 Spectroscopic Monitoring of Catalytic Reactions

22.5 Conclusions

Chapter 23: In Situ X-ray Diffraction and XAS Methods

23.1 Introduction

23.2 In Situ Diffraction Techniques

23.3 In Situ X-ray Absorption Spectroscopy on MOFs

23.4 Summary and Conclusions

Chapter 24: In Situ Studies of the Crystallization of Metal-Organic Frameworks

24.1 Introduction

24.2 In Situ Diffraction

24.3 In Situ Studies Using Scattering and Spectroscopic Methods

24.4 Microscopy and Other Methods

24.5 Summary and Future Directions

Chapter 25: Role of Molecular Simulations in the Field of MOFs

25.1 Introduction

25.2 Structure Solution of MOFs: An Indispensable Interplay Between Characterization and Modeling Tools

25.3 Structure Prediction of Novel MOFs: A Relatively Poor Success of the High-Throughput Computational Approach.

25.4 Adsorption in MOFs: From Prediction Toward Understanding

25.5 Rationalization of the Adsorption Performances of MOFs: A Recent Evolving Field

25.6 Probing the Dynamics of Guests Confined in MOFs Using a Joint Experimental Modeling: A Success Story

25.7 New Computational Challenges

Chapter 26: Defects and Disorder in MOFs

26.1 Introduction

26.2 Defects in MOFs

26.3 Summary and Conclusions

Appendix A: MOF Suppliers

Appendix B: Datasheets

2.1 Aluminum Fumarate (Basolite A520)

2.2 MIL-100(Al) (Material of Institute Lavoisier-100)

2.3 MIL-101(Cr) (Chromium(III) Terephthalate, Material of Institute Lavoisier-101)

2.4 HKUST-1 (Hong Kong University of Science and Technology-1)

2.5 ZIF-8 (Zeolitic Imidazolate Framework-8)

2.6 UiO-66 (Universitetet i Oslo 66, Zirconium Terephthalate)

2.7 DUT-67(Zr) (Dresden University of Technology-67)

Index

End User License Agreement.

Notes:

Includes bibliographical references at the end of each chapters and index.

Description based on online resource; title from PDF title page (ebrary, viewed July 1, 2016).

ISBN:

9781523155828

1523155825

9783527693078

3527693076

9783527693054

352769305X

9783527693085

3527693084

OCLC:

952568569